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The original book was published in two volumes. The format is reproduced for this e-text, except that the author’s preface (originally in Volume I) and the combined index (Volume II) are in this introductory file.
See the [end of this file] for notes on scientific terminology, spelling, Plates and chapter numbering.
CONVERSATIONS
ON
CHEMISTRY;
IN WHICH
THE ELEMENTS OF THAT SCIENCE
ARE
FAMILIARLY EXPLAINED
AND
ILLUSTRATED BY EXPERIMENTS.
IN TWO VOLUMES.
The Fifth Edition, revised, corrected, and considerably enlarged.
LONDON:
PRINTED FOR LONGMAN, HURST, REES, ORME, AND BROWN,
PATERNOSTER-ROW.
1817.
Printed by A. Strahan,
Printers-Street, London.
ADVERTISEMENT.
The Author, in this fifth edition, has endeavoured to give an account of the principal discoveries which have been made within the last four years in Chemical Science, and of the various important applications, such as the gas-lights, and the miner’s-lamp, to which they have given rise. But in regard to doctrines or principles, the work has undergone no material alteration.
London, July, 1817.
[PREFACE.]
In venturing to offer to the public, and more particularly to the female sex, an Introduction to Chemistry, the author, herself a woman, conceives that some explanation may be required; and she feels it the more necessary to apologise for the present undertaking, as her knowledge of the subject is but recent, and as she can have no real claims to the title of chemist.
On attending for the first time experimental lectures, the author found it almost impossible to derive any clear or satisfactory information from the rapid demonstrations which are usually, and perhaps necessarily, crowded into popular courses of this kind. But frequent opportunities having afterwards occurred of conversing with a friend on the subject of chemistry, and of repeating a variety of experiments, she became better acquainted with the principles of that science, and began to feel highly interested in its pursuit. It was then that she perceived, in attending the excellent lectures delivered at the Royal Institution, by the present Professor of Chemistry, the great advantage which her previous knowledge of the subject, slight as it was, gave her over others who had not enjoyed the same means of private instruction. Every fact or experiment attracted her attention, and served to explain some theory to which she was not a total stranger; and she had the gratification to find that the numerous and elegant illustrations, for which that school is so much distinguished, seldom failed to produce on her mind the effect for which they were intended.
Hence it was natural to infer, that familiar conversation was, in studies of this kind, a most useful auxiliary source of information; and more especially to the female sex, whose education is seldom calculated to prepare their minds for abstract ideas, or scientific language.
As, however, there are but few women who have access to this mode of instruction; and as the author was not acquainted with any book that could prove a substitute for it, she thought that it might be useful for beginners, as well as satisfactory to herself, to trace the steps by which she had acquired her little stock of chemical knowledge, and to record, in the form of dialogue, those ideas which she had first derived from conversation.
But to do this with sufficient method, and to fix upon a mode of arrangement, was an object of some difficulty. After much hesitation, and a degree of embarrassment, which, probably, the most competent chemical writers have often felt in common with the most superficial, a mode of division was adopted, which, though the most natural, does not always admit of being strictly pursued—it is that of treating first of the simplest bodies, and then gradually rising to the most intricate compounds.
It is not the author’s intention to enter into a minute vindication of this plan. But whatever may be its advantages or inconveniences, the method adopted in this work is such, that a young pupil, who should occasionally recur to it, with a view to procure information on particular subjects, might often find it obscure or unintelligible; for its various parts are so connected with each other as to form an uninterrupted chain of facts and reasonings, which will appear sufficiently clear and consistent to those only who may have patience to go through the whole work, or have previously devoted some attention to the subject.
It will, no doubt, be observed, that in the course of these Conversations, remarks are often introduced, which appear much too acute for the young pupils, by whom they are supposed to be made. Of this fault the author is fully aware. But, in order to avoid it, it would have been necessary either to omit a variety of useful illustrations, or to submit to such minute explanations and frequent repetitions, as would have rendered the work tedious, and therefore less suited to its intended purpose.
In writing these pages, the author was more than once checked in her progress by the apprehension that such an attempt might be considered by some, either as unsuited to the ordinary pursuits of her sex, or ill-justified by her own recent and imperfect knowledge of the subject. But, on the one hand, she felt encouraged by the establishment of those public institutions, open to both sexes, for the dissemination of philosophical knowledge, which clearly prove that the general opinion no longer excludes women from an acquaintance with the elements of science; and, on the other, she flattered herself that whilst the impressions made upon her mind, by the wonders of Nature, studied in this new point of view, were still fresh and strong, she might perhaps succeed the better in communicating to others the sentiments she herself experienced.
The reader will soon perceive, in perusing this work, that he is often supposed to have previously acquired some slight knowledge of natural philosophy, a circumstance, indeed, which appears very desirable. The author’s original intention was to commence this work by a small tract, explaining, on a plan analogous to this, the most essential rudiments of that science. This idea she has since abandoned; but the manuscript was ready, and might, perhaps, have been printed at some future period, had not an elementary work of a similar description, under the tide of “Scientific Dialogues,” been pointed out to her, which, on a rapid perusal, she thought very ingenious, and well calculated to answer its intended object.
[ CONTENTS]
Page numbers have been retained to give an idea of the relative length of each Conversation.
| [a] CONVERSATION I.] | |
| ON THE GENERAL PRINCIPLES OF CHEMISTRY. | Page 1 |
| [a] CONVERSATION II.] | |
| ON LIGHT AND HEAT. | 26 |
| [a] CONVERSATION III.] | |
| CONTINUATION OF THE SUBJECT. | 70 |
| [a] CONVERSATION IV.] | |
| ON COMBINED CALORIC, COMPREHENDING SPECIFIC HEAT AND LATENT HEAT. | 122 |
| [a] CONVERSATION V.] | |
| ON THE CHEMICAL AGENCIES OF ELECTRICITY. | 160 |
| [a] CONVERSATION VI.] | |
| ON OXYGEN AND NITROGEN. | 181 |
| [a] CONVERSATION VII.] | |
| ON HYDROGEN. | 214 |
| [a] CONVERSATION VIII.] | |
| ON SULPHUR AND PHOSPHORUS. | 256 |
| [a] CONVERSATION IX.] | |
| ON CARBON. | 282 |
| [a] CONVERSATION X.] | |
| ON METALS. | 314 |
| [a] CONVERSATION XIII.] | |
| ON THE ATTRACTION OF COMPOSITION. | 1 |
| [a] CONVERSATION XIV.] | |
| ON ALKALIES. | 19 |
| [a] CONVERSATION XV.] | |
| ON EARTHS. | 44 |
| [a] CONVERSATION XVI.] | |
| ON ACIDS. | 69 |
| [a] CONVERSATION XVII.] | |
| OF THE SULPHURIC AND PHOSPHORIC ACIDS: OR, THE COMBINATIONS OF OXYGEN WITH SULPHUR AND WITH PHOSPHORUS; AND OF THE SULPHATS AND PHOSPHATS. | 80 |
| [a] CONVERSATION XVIII.] | |
| OF THE NITRIC AND CARBONIC ACIDS: OR THE COMBINATION OF OXYGEN WITH NITROGEN AND WITH CARBON; AND OF THE NITRATS AND CARBONATS. | 100 |
| [a] CONVERSATION XIX.] | |
| ON THE BORACIC, FLUORIC, MURIATIC, AND OXYGENATED MURIATIC ACIDS; AND ON MURIATS. | 131 |
| [a] CONVERSATION XX.] | |
| ON THE NATURE AND COMPOSITION OF VEGETABLES. | 162 |
| [a] CONVERSATION XXI.] | |
| ON THE DECOMPOSITION OF VEGETABLES. | 202 |
| [a] CONVERSATION XXII.] | |
| HISTORY OF VEGETATION. | 243 |
| [a] CONVERSATION XXIII.] | |
| ON THE COMPOSITION OF ANIMALS. | 276 |
| [a] CONVERSATION XXIV.] | |
| ON THE ANIMAL ECONOMY. | 297 |
| [a] CONVERSATION XXV.] | |
| ON ANIMALISATION, NUTRITION, AND RESPIRATION. | 314 |
| [a] CONVERSATION XXVI.] | |
| ON ANIMAL HEAT; AND OF VARIOUS ANIMAL PRODUCTS. | 336 |
ERRATA.
| Vol. I. page 56. | last line but one, for “caloric,” read “calorific.” |
| 179. | Note, for “Plate XII.” r. “Plate XIII.” |
CONVERSATIONS
ON
CHEMISTRY;
IN WHICH
THE ELEMENTS OF THAT SCIENCE
ARE
FAMILIARLY EXPLAINED
AND
ILLUSTRATED BY EXPERIMENTS.
IN TWO VOLUMES.
The Fifth Edition, revised, corrected, and considerably enlarged.
VOL. I.
ON SIMPLE BODIES.
LONDON:
PRINTED FOR LONGMAN, HURST, REES, ORME, AND BROWN,
PATERNOSTER-ROW.
1817.
[ CONTENTS]
OF
THE FIRST VOLUME.
ON SIMPLE BODIES.
| [ CONVERSATION I.] | |
| ON THE GENERAL PRINCIPLES OF CHEMISTRY. | Page 1 |
| Connexion between Chemistry and Natural Philosophy.—Improved State of modern Chemistry.—Its use in the Arts.—The general Objects of Chemistry.—Definition of Elementary Bodies.—Definition of Decomposition.—Integrant and Constituent Particles.—Distinction between Simple and Compound Bodies.—Classification of Simple Bodies.—Of Chemical Affinity, or Attraction of Composition.—Examples of Composition and Decomposition. | |
| [ CONVERSATION II.] | |
| ON LIGHT AND HEAT. | 26 |
| Light and Heat capable of being separated.—Dr. Herschel’s Experiments.—Phosphorescence.—Of Caloric.—Its two Modifications.—Free Caloric.—Of the three different States of Bodies, solid, fluid, and aeriform.—Dilatation of solid Bodies.—Pyrometer.—Dilatation of Fluids.—Thermometer.—Dilatation of Elastic Fluids.—Air Thermometer.—Equal Diffusion of Caloric.—Cold a Negative Quality.—Professor Prevost’s Theory of the Radiation of Heat.—Professor Pictet’s Experiments on the Reflexion of Heat.—Mr. Leslie’s Experiments on the Radiation of Heat. | |
| [ CONVERSATION III.] | |
| CONTINUATION OF THE SUBJECT. | 70 |
| Of the different Power of Bodies to conduct Heat.—Attempt to account for this Power.—Count Rumford’s Theory of the non-conducting Power of Fluids.—Phenomena of Boiling.—Of Solution in general.—Solvent Power of Water.—Difference between Solution and Mixture.—Solvent Power of Caloric.—Of Clouds, Rain, Dr. Wells’ theory of Dew, Evaporation, &c.—Influence of Atmospherical Pressure on Evaporation.—Ignition. | |
| [ CONVERSATION IV.] | |
| ON COMBINED CALORIC, COMPREHENDING SPECIFIC HEAT AND LATENT HEAT. | 122 |
| Of Specific Heat.—Of the different Capacities of Bodies for Heat.—Specific Heat not perceptible by the Senses.—How to be ascertained.—Of Latent Heat.—Distinction between Latent and Specific Heat.—Phenomena attending the Melting of Ice and the Formation of Vapour.—Phenomena attending the Formation of Ice, and the Condensation of Elastic Fluids.—Instances of Condensation, and consequent Disengagement of Heat, produced by Mixtures, by the Slaking of Lime.—General Remarks on Latent Heat.—Explanation of the Phenomena of Ether boiling, and Water freezing, at the same Temperature.—Of the Production of Cold by Evaporation.—Calorimeter.—Meteorological Remarks. | |
| [ CONVERSATION V.] | |
| ON THE CHEMICAL AGENCIES OF ELECTRICITY. | 160 |
| Of Positive and Negative Electricity.—Galvani’s Discoveries.—Voltaic Battery.—Electrical Machine.—Theory of Voltaic Excitement. | |
| [ CONVERSATION VI.] | |
| ON OXYGEN AND NITROGEN. | 181 |
| The Atmosphere composed of Oxygen and Nitrogen in the State of Gas.—Definition of Gas.—Distinction between Gas and Vapour.—Oxygen essential to Combustion and Respiration.—Decomposition of the Atmosphere by Combustion.—Nitrogen Gas obtained by this Process.—Of Oxygenation in general.—Of the Oxydation of Metals.—Oxygen Gas obtained from Oxyd of Manganese.—Description of a Water-Bath for collecting and preserving Gases.—Combustion of Iron Wire in Oxygen Gas.—Fixed and volatile Products of Combustion.—Patent Lamps.—Decomposition of the Atmosphere by Respiration.—Recomposition of the Atmosphere. | |
| [ CONVERSATION VII.] | |
| ON HYDROGEN. | 214 |
| Of Hydrogen.—Of the Formation of Water by the Combustion of Hydrogen.—Of the Decomposition of Water. —Detonation of Hydrogen Gas.—Description of Lavoisier’s Apparatus for the formation of Water.—Hydrogen Gas essential to the Production of Flame.—Musical Tones produced by the Combustion of Hydrogen Gas within a Glass Tube.—Combustion of Candles explained.—Gas lights.—Detonation of Hydrogen Gas in Soap Bubbles.—Air Balloons.—Meteorological Phenomena ascribed to Hydrogen Gas.—Miner’s Lamp. The final two pages of the Table of Contents for Volume I were missing from the available text; everything after “Decomposition of Water” was supplied from earlier and later editions, compared against the body text. The section marked “Diamond” (Conv. IX) was called “Diamond is Carbon(e) in a state of perfect purity” in the 4th edn., “Diamond” alone in later editions. | |
| [ CONVERSATION VIII.] | |
| ON SULPHUR AND PHOSPHORUS. | 256 |
| Natural History of Sulphur.—Sublimation.—Alembic.—Combustion of Sulphur in Atmospheric Air.—Of Acidification in general.—Nomenclature of the Acids.—Combustion of Sulphur in Oxygen Gas.—Sulphuric Acid.—Sulphurous Acid.—Decomposition of Sulphur.—Sulphurated Hydrogen Gas.—Harrogate, or Hydro-sulphurated Waters.—Phosphorus.—History of its Discovery.—Its Combustion in Oxygen Gas.—Phosphoric Acid.—Phosphorus Acid.—Eudiometer.—Combination of Phosphorus with Sulphur.—Phosphorated Hydrogen Gas.—Nomenclature of Binary Compounds.—Phosphoret of Lime burning under Water. | |
| [ CONVERSATION IX.] | |
| ON CARBON. | 282 |
| Method of obtaining pure Charcoal.—Method of making common Charcoal.—Pure Carbon not to be obtained by Art.—Diamond.—Properties of Carbon.—Combustion of Carbon.—Production of Carbonic Acid Gas.—Carbon susceptible of only one Degree of Acidification.—Gaseous Oxyd of Carbon.—Of Seltzer Water and other Mineral Waters.—Effervescence.—Decomposition of Water by Carbon.—Of Fixed and Essential Oils.—Of the Combustion of Lamps and Candles.—Vegetable Acids.—Of the Power of Carbon to revive Metals. | |
| [ CONVERSATION X.] | |
| ON METALS. | 314 |
| Natural History of Metals.—Of Roasting, Smelting, &c.—Oxydation of metals by the Atmosphere.—Change of Colours produced by different degrees of Oxydation.—Combustion of Metals.—Perfect Metals burnt by Electricity only.—Some Metals revived by Carbon and other Combustibles.—Perfect Metals revived by Heat alone.—Of the Oxydation of certain Metals by the Decomposition of Water. Power of Acids to promote this Effect.—Oxydation of Metals by Acids.—Metallic Neutral Salts.—Previous oxydation of the Metal requisite.—Crystallisation.—Solution distinguished from Dissolution.—Five metals susceptible of acidification.—Meteoric Stones.—Alloys, Soldering, Plating, &c.—Of Arsenic, and of the caustic Effects of Oxygen.—Of Verdigris, Sympathetic Ink, &c.—Of the new Metals discovered by Sir H. Davy. |
CONVERSATIONS
ON
CHEMISTRY.
[CONVERSATION I.]
ON THE GENERAL PRINCIPLES OF CHEMISTRY.
MRS. B.
AS you have now acquired some elementary notions of Natural Philosophy, I am going to propose to you another branch of science, to which I am particularly anxious that you should devote a share of your attention. This is Chemistry, which is so closely connected with Natural Philosophy, that the study of the one must be incomplete without some knowledge of the other; for, it is obvious that we can derive but a very imperfect idea of bodies from the study of the general laws by which they are governed, if we remain totally ignorant of their intimate nature.
CAROLINE.
To confess the truth, Mrs. B., I am not disposed to form a very favourable idea of chemistry, nor do I expect to derive much entertainment from it. I prefer the sciences which exhibit nature on a grand scale, to those that are confined to the minutiæ of petty details. Can the studies which we have lately pursued, the general properties of matter, or the revolutions of the heavenly bodies, be compared to the mixing up of a few insignificant drugs? I grant, however, there may be entertaining experiments in chemistry, and should not dislike to try some of them: the distilling, for instance, of lavender, or rose water . . . . . .
MRS. B.
I rather imagine, my dear Caroline, that your want of taste for chemistry proceeds from the very limited idea you entertain of its object. You confine the chemist’s laboratory to the narrow precincts of the apothecary’s and perfumer’s shops, whilst it is subservient to an immense variety of other useful purposes. Besides, my dear, chemistry is by no means confined to works of art. Nature also has her laboratory, which is the universe, and there she is incessantly employed in chemical operations. You are surprised, Caroline, but I assure you that the most wonderful and the most interesting phenomena of nature are almost all of them produced by chemical powers. What Bergman, in the introduction to his history of chemistry, has said of this science, will give you a more just and enlarged idea of it. The knowledge of nature may be divided, he observes, into three periods. The first was that in which the attention of men was occupied in learning the external forms and characters of objects, and this is called Natural History. In the second, they considered the effects of bodies acting on each other by their mechanical power, as their weight and motion, and this constitutes the science of Natural Philosophy. The third period is that in which the properties and mutual action of the elementary parts of bodies was investigated. This last is the science of Chemistry, and I have no doubt you will soon agree with me in thinking it the most interesting.
You may easily conceive, therefore, that without entering into the minute details of practical chemistry, a woman may obtain such a knowledge of the science as will not only throw an interest on the common occurrences of life, but will enlarge the sphere of her ideas, and render the contemplation of nature a source of delightful instruction.
CAROLINE.
If this is the case, I have certainly been much mistaken in the notion I had formed of chemistry. I own that I thought it was chiefly confined to the knowledge and preparation of medicines.
MRS. B.
That is only a branch of chemistry which is called Pharmacy; and, though the study of it is certainly of great importance to the world at large, it belongs exclusively to professional men, and is therefore the last that I should advise you to pursue.
EMILY.
But, did not the chemists formerly employ themselves in search of the philosopher’s stone, or the secret of making gold?
MRS. B.
These were a particular set of misguided philosophers, who dignified themselves with the name of Alchemists, to distinguish their pursuits from those of the common chemists, whose studies were confined to the knowledge of medicines.
But, since that period, chemistry has undergone so complete a revolution, that, from an obscure and mysterious art, it is now become a regular and beautiful science, to which art is entirely subservient. It is true, however, that we are indebted to the alchemists for many very useful discoveries, which sprung from their fruitless attempts to make gold, and which, undoubtedly, have proved of infinitely greater advantage to mankind than all their chimerical pursuits.
The modern chemists, instead of directing their ambition to the vain attempt of producing any of the original substances in nature, rather aim at analysing and imitating her operations, and have sometimes succeeded in forming combinations, or effecting decompositions, no instances of which occur in the chemistry of Nature. They have little reason to regret their inability to make gold, whilst, by their innumerable inventions and discoveries, they have so greatly stimulated industry and facilitated labour, as prodigiously to increase the luxuries as well as the necessaries of life.
EMILY.
But, I do not understand by what means chemistry can facilitate labour; is not that rather the province of the mechanic?
MRS. B.
There are many ways by which labour may be rendered more easy, independently of mechanics; but even the machine, the most wonderful in its effects, the Steam-engine, cannot be understood without the assistance of chemistry. In agriculture, a chemical knowledge of the nature of soils, and of vegetation, is highly useful; and, in those arts which relate to the comforts and conveniences of life, it would be endless to enumerate the advantages which result from the study of this science.
CAROLINE.
But, pray, tell us more precisely in what manner the discoveries of chemists have proved so beneficial to society?
MRS. B.
That would be an injudicious anticipation; for you would not comprehend the nature of such discoveries and useful applications, as well as you will do hereafter. Without a due regard to method, we cannot expect to make any progress in chemistry. I wish to direct your observations chiefly to the chemical operations of Nature; but those of Art are certainly of too high importance to pass unnoticed. We shall therefore allow them also some share of our attention.
EMILY.
Well, then, let us now set to work regularly. I am very anxious to begin.
MRS. B.
The object of chemistry is to obtain a knowledge of the intimate nature of bodies, and of their mutual action on each other. You find therefore, Caroline, that this is no narrow or confined science, which comprehends every thing material within our sphere.
CAROLINE.
On the contrary, it must be inexhaustible; and I am a loss to conceive how any proficiency can be made in a science whose objects are so numerous.
MRS. B.
If every individual substance were formed of different materials, the study of chemistry would, indeed, be endless; but you must observe that the various bodies in nature are composed of certain elementary principles, which are not very numerous.
CAROLINE.
Yes; I know that all bodies are composed of fire, air, earth, and water; I learnt that many years ago.
MRS. B.
But you must now endeavour to forget it. I have already informed you what a great change chemistry has undergone since it has become a regular science. Within these thirty years especially, it has experienced an entire revolution, and it is now proved, that neither fire, air, earth, nor water, can be called elementary bodies. For an elementary body is one that has never been decomposed, that is to say, separated into other substances; and fire, air, earth, and water, are all of them susceptible of decomposition.
EMILY.
I thought that decomposing a body was dividing it into its minutest parts. And if so, I do not understand why an elementary substance is not capable of being decomposed, as well as any other.
MRS. B.
You have misconceived the idea of decomposition; it is very different from mere division. The latter simply reduces a body into parts, but the former separates it into the various ingredients, or materials, of which it is composed. If we were to take a loaf of bread, and separate the several ingredients of which it is made, the flour, the yeast, the salt, and the water, it would be very different from cutting or crumbling the loaf into pieces.
EMILY.
I understand you now very well. To decompose a body is to separate from each other the various elementary substances of which it consists.
CAROLINE.
But flour, water, and other materials of bread, according to our definition, are not elementary substances?
MRS. B.
No, my dear; I mentioned bread rather as a familiar comparison, to illustrate the idea, than as an example.
The elementary substances of which a body is composed are called the constituent parts of that body; in decomposing it, therefore, we separate its constituent parts. If, on the contrary, we divide a body by chopping it to pieces, or even by grinding or pounding it to the finest powder, each of these small particles will still consist of a portion of the several constituent parts of the whole body: these are called the integrant parts; do you understand the difference?
EMILY.
Yes, I think, perfectly. We decompose a body into its constituent parts; and divide it into its integrant parts.
MRS. B.
Exactly so. If therefore a body consists of only one kind of substance, though it may be divided into its integrant parts, it is not possible to decompose it. Such bodies are therefore called simple or elementary, as they are the elements of which all other bodies are composed. Compound bodies are such as consist of more than one of these elementary principles.
CAROLINE.
But do not fire, air, earth, and water, consist, each of them, but of one kind of substance?
MRS. B.
No, my dear; they are every one of them susceptible of being separated into various simple bodies. Instead of four, chemists now reckon upwards of forty elementary substances. The existence of most of these is established by the clearest experiments; but, in regard to a few of them, particularly the most subtle agents of nature, heat, light, and electricity, there is yet much uncertainty, and I can only give you the opinion which seems most probably deduced from the latest discoveries. After I have given you a list of the elementary bodies, classed according to their properties, we shall proceed to examine each of them separately, and then consider them in their combinations with each other.
Excepting the more general agents of nature, heat, light, and electricity, it would seem that the simple form of bodies is that of a metal.
CAROLINE.
You astonish me! I thought the metals were only one class of minerals, and that there were besides, earths, stones, rocks, acids, alkalies, vapours, fluids, and the whole of the animal and vegetable kingdoms.
MRS. B.
You have made a tolerably good enumeration, though I fear not arranged in the most scientific order. All these bodies, however, it is now strongly believed, may be ultimately resolved into metallic substances. Your surprise at this circumstance is not singular, as the decomposition of some of them, which has been but lately accomplished, has excited the wonder of the whole philosophical world.
But to return to the list of simple bodies—these being usually found in combination with oxygen, I shall class them according to their properties when so combined. This will, I think, facilitate their future investigation.
EMILY.
Pray what is oxygen?
MRS. B.
A simple body; at least one that is supposed to be so, as it has never been decomposed. It is always found united with the negative electricity. It will be one of the first of the elementary bodies whose properties I shall explain to you, and, as you will soon perceive, it is one of the most important in nature; but it would be irrelevant to enter upon this subject at present. We must now confine our attention to the enumeration and classification of the simple bodies in general. They may be arranged as follows:
CLASS I.
Comprehending the imponderable agents, viz.
HEAT or CALORIC,
LIGHT,
ELECTRICITY.
CLASS II.
Comprehending agents capable of uniting with inflammable bodies, and in most instances of effecting their combustion.
OXYGEN,
CHLORINE,
IODINE.[*]
CLASS III.
Comprehending bodies capable of uniting with oxygen, and, forming with it various compounds. This class may be divided as follows:
DIVISION 1.
HYDROGEN, forming water.
DIVISION 2.
Bodies forming acids.
| NITROGEN, | forming nitric acid. |
| SULPHUR, | forming sulphuric acid. |
| PHOSPHORUS, | forming phosphoric acid. |
| CARBON, | forming carbonic acid. |
| BORACIUM, | forming boracic acid. |
| FLUORIUM, | forming fluoric acid. |
| MURIATIUM, | forming muriatic acid. |
DIVISION 3.
Metallic bodies forming alkalies.
| POTASSIUM, | forming potash. |
| SODIUM, | forming soda. |
| AMMONIUM, | forming ammonia. |
DIVISION 4.
Metallic bodies forming earths.
| CALCIUM, | or metal forming lime. |
| MAGNIUM, | forming magnesia. |
| BARIUM, | forming barytes. |
| STRONTIUM, | forming strontites. |
| SILICIUM, | forming silex. |
| ALUMIUM, | forming alumine. |
| YTTRIUM, | forming yttria. |
| GLUCIUM, | forming glucina. |
| ZIRCONIUM, | forming zirconi.[*] |
DIVISION 5.
Metals, either naturally metallic, or yielding their oxygen to carbon or to heat alone.
Subdivision 1.
Malleable Metals.
GOLD,
PLATINA,
PALLADIUM,
SILVER[*]
MERCURY[†]
TIN,
COPPER,
IRON,
LEAD,
NICKEL,
ZINC.
Subdiv. 2.
Brittle Metals.
ARSENIC,
BISMUTH,
ANTIMONY,
MANGANESE,
TELLURIUM,
COBALT,
TUNGSTEN,
MOLYBDENUM,
TITANIUM,
CHROME,
URANIUM,
COLUMBIUM or TANTALIUM,
IRIDIUM,
OSMIUM,
RHODIUM.[*]
CAROLINE.
Oh, what a formidable list! You will have much to do to explain it, Mrs. B.; for I assure you it is perfectly unintelligible to me, and I think rather perplexes than assists me.
MRS. B.
Do not let that alarm you, my dear; I hope that hereafter this classification will appear quite clear, and, so far from perplexing you, will assist you in arranging your ideas. It would be in vain to attempt forming a division that would appear perfectly clear to a beginner: for you may easily conceive that a chemical division being necessarily founded on properties with which you are almost wholly unacquainted, it is impossible that you should at once be able to understand its meaning or appreciate its utility.
But, before we proceed further, it will be necessary to give you some idea of chemical attraction, a power on which the whole science depends.
Chemical Attraction, or the Attraction of Composition, consists in the peculiar tendency which bodies of a different nature have to unite with each other. It is by this force that all the compositions, and decompositions, are effected.
EMILY.
What is the difference between chemical attraction, and the attraction of cohesion, or of aggregation, which you often mentioned to us, in former conversations?
MRS. B.
The attraction of cohesion exists only between particles of the same nature, whether simple or compound; thus it unites the particles of a piece of metal which is a simple substance, and likewise the particles of a loaf of bread which is a compound. The attraction of composition, on the contrary, unites and maintains, in a state of combination, particles of a dissimilar nature; it is this power that forms each of the compound particles of which bread consists; and it is by the attraction of cohesion that all these particles are connected into a single mass.
EMILY.
The attraction of cohesion, then, is the power which unites the integrant particles of a body: the attraction of composition that which combines the constituent particles. Is it not so?
MRS. B.
Precisely: and observe that the attraction of cohesion unites particles of a similar nature, without changing their original properties; the result of such an union, therefore, is a body of the same kind as the particles of which it is formed; whilst the attraction of composition, by combining particles of a dissimilar nature, produces compound bodies, quite different from any of their constituents. If, for instance, I pour on the piece of copper, contained in this glass, some of this liquid (which is called nitric acid), for which it has a strong attraction, every particle of the copper will combine with a particle of acid, and together they will form a new body, totally different from either the copper or the acid.
Do you observe the internal commotion that already begins to take place? It is produced by the combination of these two substances; and yet the acid has in this case to overcome not only the resistance which the strong cohesion of the particles of copper opposes to their combination with it, but also to overcome the weight of the copper, which makes it sink to the bottom of the glass, and prevents the acid from having such free access to it as it would if the metal were suspended in the liquid.
EMILY.
The acid seems, however, to overcome both these obstacles without difficulty, and appears to be very rapidly dissolving the copper.
MRS. B.
By this means it reduces the copper into more minute parts than could possibly be done by any mechanical power. But as the acid can act only on the surface of the metal, it will be some time before the union of these two bodies will be completed.
You may, however, already see how totally different this compound is from either of its ingredients. It is neither colourless, like the acid, nor hard, heavy, and yellow like the copper. If you tasted it, you would no longer perceive the sourness of the acid. It has at present the appearance of a blue liquid; but when the union is completed, and the water with which the acid is diluted is evaporated, the compound will assume the form of regular crystals, of a fine blue colour, and perfectly transparent[*]. Of these I can shew you a specimen, as I have prepared some for that purpose.
CAROLINE.
How very beautiful they are, in colour, form, and transparency!
EMILY.
Nothing can be more striking than this example of chemical attraction.
MRS. B.
The term attraction has been lately introduced into chemistry as a substitute for the word affinity, to which some chemists have objected, because it originated in the vague notion that chemical combinations depended upon a certain resemblance, or relationship, between particles that are disposed to unite; and this idea is not only imperfect, but erroneous, as it is generally particles of the most dissimilar nature, that have the greatest tendency to combine.
CAROLINE.
Besides, there seems to be no advantage in using a variety of terms to express the same meaning; on the contrary it creates confusion; and as we are well acquainted with the term Attraction in natural philosophy, we had better adopt it in chemistry likewise.
MRS. B.
If you have a clear idea of the meaning, I shall leave you at liberty to express it in the terms you prefer. For myself, I confess that I think the word Attraction best suited to the general law that unites the integrant particles of bodies; and Affinity better adapted to that which combines the constituent particles, as it may convey an idea of the preference which some bodies have for others, which the term attraction of composition does not so well express.
EMILY.
So I think; for though that preference may not result from any relationship, or similitude, between the particles (as you say was once supposed), yet, as it really exists, it ought to be expressed.
MRS. B.
Well, let it be agreed that you may use the terms affinity, chemical attraction and attraction of composition, indifferently, provided you recollect that they have all the same meaning.
EMILY.
I do not conceive how bodies can be decomposed by chemical attraction. That this power should be the means of composing them, is very obvious; but that it should, at the same time, produce exactly the contrary effect, appears to me very singular.
MRS. B.
To decompose a body is, you know, to separate its constituent parts, which, as we have just observed, cannot be done by mechanical means.
EMILY.
No: because mechanical means separate only the integrant particles; they act merely against the attraction of cohesion, and only divide a compound into smaller parts.
MRS. B.
The decomposition of a body is performed by chemical powers. If you present to a body composed of two principles, a third, which has a greater affinity for one of them than the two first have for each other, it will be decomposed, that is, its two principles will be separated by means of the third body. Let us call two ingredients, of which the body is composed, A and B. If we present to it another ingredient C, which has a greater affinity for B than that which unites A and B, it necessarily follows that B will quit A to combine with C. The new ingredient, therefore, has effected a decomposition of the original body A B; A has been left alone, and a new compound, B C, has been formed.
EMILY.
We might, I think, use the comparison of two friends, who were very happy in each other’s society, till a third disunited them by the preference which one of them gave to the new-comer.
MRS. B.
Very well. I shall now show you how this takes place in chemistry.
Let us suppose that we wish to decompose the compound we have just formed by the combination of the two ingredients, copper and nitric acid; we may do this by presenting to it a piece of iron, for which the acid has a stronger attraction than for copper; the acid will, consequently, quit the copper to combine with the iron, and the copper will be what the chemists call precipitated, that is to say, it will be thrown down in its separate state, and reappear in its simple form.
In order to produce this effect, I shall dip the blade of this knife into the fluid, and, when I take it out, you will observe, that, instead of being wetted with a bluish liquid, like that contained in the glass, it will be covered with a thin coat of copper.
CAROLINE.
So it is really! but then is it not the copper, instead of the acid, that has combined with the iron blade?
MRS. B.
No; you are deceived by appearances: it is the acid which combines with the iron, and, in so doing, deposits or precipitates the copper on the surface of the blade.
EMILY.
But, cannot three or more substances combine together, without any of them being precipitated?
MRS. B.
That is sometimes the case; but, in general, the stronger affinity destroys the weaker; and it seldom happens that the attraction of several substances for each other is so equally balanced as to produce such complicated compounds.
CAROLINE.
But, pray, Mrs. B., what is the cause of the chemical attraction of bodies for each other? It appears to me more extraordinary or unnatural, if I may use the expression, than the attraction of cohesion, which unites particles of a similar nature.
MRS. B.
Chemical attraction may, like that of cohesion or gravitation, be one of the powers inherent in matter which, in our present state of knowledge, admits of no other satisfactory explanation than an immediate reference to a divine cause. Sir H. Davy, however, whose important discoveries have opened such improved views in chemistry, has suggested an hypothesis which may throw great light upon that science. He supposes that there are two kinds of electricity, with one or other of which all bodies are united. These we distinguish by the names of positive and negative electricity; those bodies are disposed to combine, which possess opposite electricities, as they are brought together by the attraction which these electricities have for each other. But, whether this hypothesis be altogether founded on truth or not, it is impossible to question the great influence of electricity in chemical combinations.
EMILY.
So, that we must suppose that the two electricities always attract each other, and thus compel the bodies in which they exist to combine?
CAROLINE.
And may not this be also the cause of the attraction of cohesion?
MRS. B.
No, for in particles of the same nature the same electricities must prevail, and it is only the different or opposite electric fluids that attract each other.
CAROLINE.
These electricities seem to me to be a kind of chemical spirit, which animates the particles of bodies, and draws them together.
EMILY.
If it is known, then, with which of the electricities bodies are united, it can be inferred which will, and which will not, combine together?
MRS. B.
Certainly.—I should not omit to mention, that some doubts have been entertained whether electricity be really a material agent, or whether it might not be a power inherent in bodies, similar to, or, perhaps identical with, attraction.
EMILY.
But what then would be the electric spark which is visible, and must therefore be really material?
MRS. B.
What we call the electric spark, may, Sir H. Davy says, be merely the heat and light, or fire produced by the chemical combinations with which these phenomena are always connected. We will not, however, enter more fully on this important subject at present, but reserve the principal facts which relate to it to a future conversation.
Before we part, however, I must recommend you to fix in your memory the names of the simple bodies, against our next interview.
[*] It has been questioned by some eminent chemists, whether these two last agents should not be classed among the inflammable bodies, as they are capable of combining with oxygen, as well as with inflammable bodies. But they seem to be more distinctly characterised by their property of supporting combustion than by any other quality.
[*] Of all these earths, three or four only have as yet been distinctly decomposed.
[*] These first four metals have commonly been distinguished by the appellation of perfect or noble metals, on account of their possessing the characteristic properties of ductility, malleability, inalterability, and great specific gravity, in an eminent degree.
[†] Mercury, in its liquid state, cannot, of course, be called a malleable metal. But when frozen, it possesses a considerable degree of malleability.
[*] These last four or five metallic bodies are placed under this class for the sake of arrangement, though some of their properties have not been yet fully investigated.
[*] These crystals are more easily obtained from a mixture of sulphuric with a little nitric acid.
[CONVERSATION II.]
ON LIGHT AND HEAT OR CALORIC.
CAROLINE.
We have learned by heart the names of all the simple bodies which you have enumerated, and we are now ready to enter on the examination of each of them successively. You will begin, I suppose, with LIGHT?
MRS. B.
Respecting the nature of light we have little more than conjectures. It is considered by most philosophers as a real substance, immediately emanating from the sun, and from all luminous bodies, from which it is projected in right lines with prodigious velocity. Light, however, being imponderable, it cannot be confined and examined by itself; and therefore it is to the effects it produces on other bodies, rather than to its immediate nature, that we must direct our attention.
The connection between light and heat is very obvious; indeed, it is such, that it is extremely difficult to examine the one independently of the other.
EMILY.
But, is it possible to separate light from heat; I thought they were only different degrees of the same thing, fire?
MRS. B.