SCIENTIFIC AMERICAN SUPPLEMENT NO. 455
NEW YORK, SEPTEMBER 20, 1884
Scientific American Supplement. Vol. XVIII, No. 455.
Scientific American established 1845
Scientific American Supplement, $5 a year.
Scientific American and Supplement, $7 a year.
THE GIRAFFE.
The spirited view herewith presented, representing the "Fall of the Giraffe" before the rifle of a sportsman, we take from the Illustrated London News. Hunting the giraffe has long been a favorite sport among the more adventurous of British sportsmen, its natural range being all the wooded parts of eastern, central, and southern Africa, though of late years it has been greatly thinned out before the settlements advancing from the Cape of Good Hope.
THE FALL OF THE GIRAFFE.
The characteristics of this singular animal are in some particulars those of the camel, the ox, and the antelope. Its eyes are beautiful, extremely large, and so placed that the animal can see much of what is passing on all sides, and even behind it, so that it is approached with the greatest difficulty. The animal when full grown attains sometimes a height of fifteen to seventeen feet. It feeds on the leaves and twigs of trees principally, its immense length of legs and height at the withers rendering it difficult for the animal to graze on an even surface. It is not easily overtaken except by a swift horse, but when surprised or run down it can defend itself with considerable vigor by kicking, thus, it is said, often tiring out and beating off the lion. It was formerly almost universally believed that the fore legs were longer than the hinder ones, but in fact the hind legs are the longer by about one inch, the error having been caused by the great development and height of the withers, to give a proper base to the long neck and towering head. The color varies a good deal, the head being generally a reddish brown, and the neck, back, and sides marked with tessellated, rust colored spots with narrow white divisions. Many specimens have been brought to this country, the animal being extremely docile in confinement, feeding from the hand, and being very friendly to those who are kind to it.
An experiment has been made in Vienna which proves that even with incandescent lights special precautions must be taken to avoid any risk of fire. A lamp having been enveloped with paper and lighted by a current, the heat generated was sufficient to set fire to the paper, which burnt out and caused the lamp to explode.
THE TEMPERATURE OF THE EARTH AS SHOWN BY DEEP MINES.
At a recent meeting of the American Society of Civil Engineers, observations on the temperature of the earth, as shown by deep mines, were presented by Messrs. Hamilton Smith, Jr., and Edward B Dorsey. Mr. Smith said that the temperature of the earth varies very greatly at different localities and in different geological formations. There are decided exceptions to the general law that the temperature increased with the depth. At the New Almaden quicksilver mine, in California, at a depth of about 600 feet the temperature was very high—some 115 degrees; but in the deepest part of the same mine, 1,800 feet below the surface and 500 feet below sea level, the temperature is very pleasant, probably less than 80 degrees. At the Eureka mines, in California, the air 1,200 feet below the surface appears nearly as cool as 100 feet below the surface. The normal temperature of the earth at a depth of 50 or 60 feet is probably near the mean annual temperature of the air at the particular place. At the Comstock mines, some years since, the miners could remain but a few moments at a time, on account of the heat. Ice water was given them as an experiment; it produced no ill effects, but the men worked to much better advantage; and since that time, ice water is furnished in all these mines, and drunk with apparently no bad results.
Mr. E.B. Dorsey said that the mines on the Comstock vein, Nevada, were exceptionally hot. At depths of from 1,500 to 2,000 feet, the thermometer placed in a freshly drilled hole will show 130 degrees. Very large bodies of water have run for years at 155 degrees, and smaller bodies at 170 degrees. The temperature of the air is kept down to 110 degrees by forcing in fresh air cooled over ice.
Captain Wheeler, U.S. Engineers, estimated the heat extracted annually from the Comstock by means of the water pumped out and cold air forced in, as equal to that generated by the combustion of 55,560 tons of anthracite coal or 97,700 cords of wood. Observations were then given upon temperature at every 100 feet in the Forman shaft of the Overman mine, running from 53 degrees at a depth of 100 feet to 121.2 degrees at a depth of 2,300 feet. The temperature increased:
- 100 to 1,000 feet deep, increase 1 degree in 29 feet.
- 100 to 1,800 feet deep, increase 1 degree in 30.5 feet.
- 100 to 2,300 feet deep, increase 1 degree in 32.3 feet.
A table was presented giving the temperatures of a large number of deep mines, tunnels, and artesian wells. The two coolest mines or tunnels are in limestone, namely, Chanarcillo mines and Mont Cenis tunnel; and the two hottest are in trachyte and the "coal measures," namely, the Comstock mines in trachyte and the South Balgray in the "coal measures." Mr. Dorsey considered that experience showed that limestone was the coolest formation.
GALLISIN, AN UNFERMENTABLE SUBSTANCE IN STARCH SUGAR.
C. Schmitt and A. Coblenzl have made a careful investigation of the unfermentable substances found in commercial starch sugars, and have succeeded in isolating a definite compound, to which they give the name gallisin. The method of separation and purification which they made use of is as follows: 5 kilogrammes of commercial starch sugar were allowed to ferment. At a temperature of 18-20° C. and with a solution containing 20 per cent. the fermentation was complete in five to six days. It was filtered; the perfectly clear, almost colorless, liquid evaporated as far as possible on the water-bath, and the sirup while still warm brought into a good-sized flask. The sirup was then well shaken with a large excess of absolute alcohol, when it became viscous, but did not mix with the alcohol. The latter was poured off, replaced by fresh alcohol, and again shaken. When this shaking with alcohol has been repeated several times, the sirup is finally changed to a yellowish-gray mass. This is now brought into a large mortar, and rubbed up under a mixture of alcohol and ether. After some time the whole mass is transformed into a gray powder. It is quickly filtered off with the aid of an aspirator, washed with alcohol and then with ether, and brought under a desiccator with concentrated sulphuric acid. In order to purify the substance, it is dissolved in water and treated with bone-black. The solution is then evaporated to a sirup, and this poured into a mixture of equal parts of anhydrous alcohol and ether. In this way the new compound is obtained as a very fine, pure white powder which rapidly settles. It has much the appearance of starch. Under the microscope it is perfectly amorphous. In the air it deliquesces much more rapidly than ignited calcium chloride.
Treated with dilute mineral acids or oxalic acid on the water-bath gallisin is transformed into dextrose. It does not ferment when treated in water solution with fresh yeast. The analyses led to the formula C12H24O10. When treated under pressure with three times its weight of acetic anhydride at 130-140° it dissolves perfectly. From the solution a product was separated which on analysis gave results agreeing with the formula C12H18O10(C2H3O) 6. The substance appears therefore to be hexacetylgallisin.
Physiological experiments on lower animals and human beings demonstrated clearly that gallisin has neither directly nor indirectly any injurious effect on the health.—Berichte der Deutschen Chemischen Gesellschaft, 17, 1000; Amer. Chem. Jour.
THE COMBINING WEIGHTS, VOLUMES, AND SPECIFIC GRAVITIES OF ELEMENTS AND COMPOUNDS.
Under the title of "Figures Worth Studying," Mr. William Farmer, of New York, read a paper before a recent meeting of the Society of Gas Lighting, from which the American Gas Light Journal gives the following:
I have prepared the following table, which contains some of the elements and compounds, with their combining weights, volumes, and specific gravities. When the combining weight of any of these elements and compounds is taken in pounds, then the gas or vapor therefrom will always occupy about 377.07 cubic feet of space, at 60° Fahr. and 30 inches barometer. If we divide this constant 377.07 by the combining weight of any of the substances, then the quotient will be the number of cubic feet per pound of the same. If we divide the combining weight of any of the substances given in the table by 2, then the quotient will give the density of the same, as compared with hydrogen. If we divide the combining weight of any of the substances by the constant 28.87, then the quotient will be the specific gravity of the gas or vapor therefrom, as compared with air. All the calculations are based on the atomic weights which are now generally adopted by the majority of chemists.
| Combining Weight. | Cub. Ft. per Pound. | Cub. Ft. per Combining Weight. | Specific Gravity, Air = 1. | |
|---|---|---|---|---|
| Hydrogen (H2) | 2.00 | 188.53 | 377.07 | 0.0692 |
| Carbon vapour (C2) | 23.94 | 15.75 | 377.07 | 0.8292 |
| Nitrogen (N2) | 28.06 | 13.43 | 377.07 | 0.9719 |
| Oxygen (O2) | 31.92 | 11.81 | 377.07 | 1.1056 |
| Chlorine (Cl2) | 71.00 | 5.31 | 377.07 | 2.4593 |
| Bromine (Br2) | 160.00 | 2.35 | 377.07 | 5.5420 |
| Flourine (F2) | 38.00 | 9.92 | 377.07 | 1.3162 |
| Iodine (I2) | 253.20 | 1.48 | 377.07 | 8.7703 |
| Sulphur (S2) | 63.96 | 5.89 | 377.07 | 2.2154 |
| Phosphorus (P4) | 123.84 | 3.04 | 377.07 | 4.2895 |
| Carbonic oxide (CO) | 27.03 | 13.50 | 377.07 | 0.9674 |
| Carbonic acid (CO2) | 48.89 | 8.59 | 377.07 | 1.5202 |
| Water vapour (H2O) | 17.06 | 20.99 | 377.07 | 0.6221 |
| Hydrogen sulphide (H2S) | 33.08 | 11.09 | 377.07 | 1.1770 |
| Ammonia (H2N) | 17.03 | 22.14 | 377.07 | 0.5898 |
| Sulphurous oxide (SO2) | 63.90 | 5.90 | 377.07 | 2.2133 |
| Sulphuric oxide (SO3) | 79.86 | 4.72 | 377.07 | 2.7662 |
| Cyanogen (C2N2) | 52.00 | 7.25 | 377.07 | 1.8011 |
| Bisulphide of carbon (CS2) | 75.93 | 4.96 | 377.07 | 2.6300 |
| Ethyl alcohol (C2H6O) | 45.90 | 8.21 | 377.07 | 1.5898 |
| Ethyl ether (C4H10O) | 73.84 | 5.10 | 377.07 | 2.5576 |
| Methyl alcohol (CH4O) | 31.93 | 11.81 | 377.07 | 1.1059 |
| Methyl chloride (CH3Cl) | 50.47 | 7.47 | 377.07 | 1.7482 |
| Carbonyl chloride (COCl2) | 98.93 | 3.81 | 377.07 | 3.4267 |
| Phosphine gas (PH3) | 33.96 | 11.10 | 377.07 | 1.1769 |
| Hydrochloric acid (HCl) | 36.50 | 10.33 | 377.07 | 1.2642 |
| Methane (CH4) | 15.98 | 26.61 | 377.07 | 0.5531 |
| Ethane (C2H6) | 29.94 | 12.50 | 377.07 | 1.0370 |
| Propane (C3H8) | 43.91 | 8.58 | 377.07 | 1.5209 |
| Butane (C4H10) | 57.88 | 6.51 | 377.07 | 2.0048 |
| Ethene (C2H4) | 27.94 | 13.49 | 377.07 | 0.9677 |
| Propene (C3H6) | 41.91 | 8.99 | 377.07 | 1.4516 |
| Butene (C4H8) | 55.88 | 6.74 | 377.07 | 1.9355 |
| Ethine (C2H2) | 25.94 | 14.53 | 377.07 | 0.8985 |
| Propine (C3H4) | 39.91 | 9.44 | 377.07 | 1.3824 |
| Butine (C4H6) | 53.88 | 6.98 | 377.07 | 1.8662 |
| Quintone (C5H6) | 65.85 | 5.72 | 377.07 | 2.2809 |
| Benzene (C6H6) | 77.82 | 4.84 | 377.07 | 2.6955 |
| Styrolene (C8H8) | 103.75 | 3.63 | 377.07 | 3.5936 |
| Naphtalene (C10H8) | 127.70 | 2.95 | 377.07 | 4.4232 |
| Turpentine (C10H16) | 135.70 | 2.77 | 377.07 | 4.7003 |
| Dry air | 28.87 | 13.06 | — | 1.0000 |
EMERALD-GREEN: ITS PROPERTIES AND MANUFACTURE.[[1]]
By ROBERT GALLOWAY, M.R.I.A.
The poisonous effects of wall-paper stained with emerald-green (aceto-arsenite of copper) appears to be a very favorite topic in many journals; it is continually reappearing in one form or another in different publications, especially medical ones; there has recently appeared a short reference to it under the title, "The Poisonous Effect of Wall-paper." As some years ago I became practically acquainted with its properties and manufacture, a few observations on these subjects may not be without interest.
In the paragraph referred to, it is stated that the poisonous effect of this pigment cannot be entirely due to its mere mechanical detachment from the paper. This writer therefore attributes the poisonous effects to the formation of the hydrogen compound of arsenic, viz., arseniureted hydrogen (AsH3); the hydrogen, for the formation of this compound, being generated, the writer thinks probable, "by the joint action of moisture and organic matters, viz., of substances used in fixing to walls papers impregnated with arsenic." In some of our chemical manuals, Dr. Kolbe's "Inorganic Chemistry," for example, it is also stated that arseniureted hydrogen is formed by the fermentation of the starch-paste employed for fastening the paper to the walls. It is perfectly obvious that the fermentation of the starch-paste must cease after a time, and therefore the poisonous effects of the paper must likewise cease if its injurious effects are caused by the fermentation. I do not think that arseniureted hydrogen could be formed under the conditions, for the oxygen compound of arsenic is in a state of combination, and the compound is in a dry solid state and not in solution and the affinities of the two elements—arsenic and hydrogen—for each other are so exceedingly weak that they cannot be made to unite directly except they are both set free at the same moment in presence of each other. Further, for the formation of this hydrogen compound by the fermentation of the starch, or by the growth of minute fungi, the entire compound must be broken up, and therefore the pigment would become discolored; but aceto-arsenite of copper
(3CuAs2O4+Cu(C2H3O 2)2)
is a very stable compound, not readily undergoing decomposition, and is consequently a very permanent color. It has also been not unfrequently stated that the injurious effects of this pigment are due to the arsenious oxide volatilizing from the other constituents of the compound. This volatilization would likewise cause a breaking up of the entire compound, and would consequently cause a discoloration of the paper; but the volatilization of this arsenic compound is in every respect most improbable.
The injurious effects, if any, of this pigment must therefore be due to its mechanical detachment from the paper; but has it ever been conclusively proved that persons who inhabit rooms the wall-paper of which is stained with emerald-green suffer from arsenical poisoning? If it does occur, then the effects of what may be termed homœopathic doses of this substance are totally different from the effects which arise from larger doses. During the packing of this substance in its dry state in the factory, clouds of its dust ascend in the air, and during the time I had to do with its manufacture I never heard that any of the factory hands suffered, nor did I suffer, from arsenical poisoning. If there is any abrasion of the skin the dust produces a sore, and also the delicate lining of the nostrils is apt to be affected. It is in this way it acts in large doses; I am therefore very skeptical as to its supposed poisonous effects when wall-paper is stained with it.
Different methods are given in works on chemistry for the manufacture of this pigment, but as they do not agree in every respect with the method which was followed in English color factories some years ago, it will be as well, for the full elucidation of the manufacture of this substance, to briefly recite some of these methods before describing the one that was, and probably is still, in use; and I will afterward describe a method which I invented, and which is practically superior to any other, both in the rapidity with which the color can be formed, and for producing it at a less cost.
It is stated in Watts' "Dictionary of Chemistry" that it is "prepared on a large scale by mixing arsenious acid with cupric acetate and water. Five parts of verdigris are made up to a thin paste, and added to a boiling solution of 4 parts or rather more of arsenious acid in 50 parts of water. The boiling must be well kept up, otherwise the precipitate assumes a yellow-green color, from the formation of copper arsenite; in that case acetic acid must be added, and the boiling continued a few minutes longer. The precipitate then becomes crystalline, and acquires the fine green color peculiar to the aceto-arsenite." I do not know from personal knowledge, but I have always understood that the copper salt employed in its manufacture in France is the acetate. This would account, in my opinion, for the larger crystalline flakes in which it is obtained in France than can be produced by the English method of manufacturing it. Cupric acetate is never employed, I believe, in England—the much cheaper copper salt, the sulphate, being always employed.
In "Miller's Chemistry" it is stated it "may be obtained by boiling solutions of arsenious anhydride and cupric acetate, and adding to the mixture an equal bulk of cold water." Why it should be recommended to add cold water, I am at a loss to understand.
In Drs. Roscoe and Schorlemmer's large work on "Chemistry," and in the English edition of "Wagner's Handbook of Chemical Technology," edited by Mr. Crookes, the process as described by Dr. Ehrmann in the "Ann. Pharm.," xii., 92, is given. It is thus stated in Wagner's work: "This pigment is prepared by first separately dissolving equal parts by weight of arsenious acid and neutral acetate of copper in boiling water, and next mixing these solutions while boiling. There is immediately formed a flocculent olive-green colored precipitate of arsenite of copper, while the supernatant liquid contains free acetic acid. After a while the precipitate becomes gradually crystalline, at the same time forming a beautiful green pigment, which is separated from the liquid by filtration, and after washing and carefully drying is ready for use. The mode of preparing this pigment on a large scale was originally devised by M. Braconnot, as follows: 15 kilos. of sulphate of copper are dissolved in the smallest quantity of boiling water, and mixed with a boiling and concentrated solution of arsenite of soda or potassa, so prepared as to contain 20 kilos. of arsenious acid. There is immediately formed a dirty greenish-colored precipitate which is converted into Schweinfurt green by the addition of some 15 liters of concentrated wood-vinegar. This having been done, the precipitate is immediately filtered off and washed."
As I have already stated, the copper salt used in the manufacture of this pigment in England is the sulphate, and it is carried out pretty much according to Braconnot's method as described by Dr Ehrmann; but any one would infer, from reading his description of the manufacturing process, that the compound, aceto-arsenite of copper, was formed almost immediately after the addition of the acetic acid, a higher or lower atmospheric temperature having no effect in hastening or retarding the formation. Furthermore, it is not stated whether the compound forms more readily in an acid or neutral solution, or whether it can or cannot be formed in a neutral one; now both these points are important to notice in describing its manufacture. As regards the former I shall notice it presently, and, as far as my knowledge extends, the pigment will not form when the solution is neutral.
The operation is conducted in the following manner in the factory: The requisite quantity of sulphate of copper is placed in a large wooden vat, and hot water added to dissolve it; the requisite quantity of arsenic (arsenious anhydride) and carbonate of soda, the latter not in quantity quite sufficient to neutralize the whole of the sulphuric acid set free from the sulphate of copper on the precipitation of the copper as arsenite, are placed in another wooden vessel; water is then added, and the formation of the arsenite of soda and its solution are aided by the introduction of steam into the liquid. When complete solution has been effected the arsenic solution is run off into the vat containing the solution of the sulphate of copper, arsenite of copper being at once precipitated. The necessary quantity of acetic acid is afterward added. In warm weather the formation of the aceto-arsenite soon commences after the addition of the vinegar; but, even in that case, it takes a week or more to have the whole of a big batch of arsenite converted into the aceto-arsenite; and perfect conversion is necessary, as the presence of a very minute quantity of unchanged arsenite lowers very much the price of the emerald pigment, and a by no means large quantity renders the pigment unsalable, owing to its dirty yellowish-green color. In cold weather a much longer time is required for its complete conversion; even at the end of a fortnight or three weeks there frequently remains sufficient unconverted arsenite to affect seriously the selling price of the color; when this occurs the manufacturer generally removes these last traces by a most wasteful method viz, by adding a quantity of free sulphuric acid. The acid of course dissolves the arsenite, but it dissolves in very much larger quantities the aceto-arsenite; and this costly solution is not utilized, but is run into the factory sewer.
By my method of manufacturing it, it can be produced in winter as well as in summer in one or two hours, and the quantity of free acid required for its formation is reduced to the lowest amount. I proceed as follows: After having dissolved in hot water the requisite quantity of cupric sulphate, I decompose one-fourth of this salt by adding just sufficient of a solution of carbonate of soda to precipitate the copper, in that quantity of the sulphate, as carbonate. I then add just sufficient acetic acid to convert the carbonate into acetate. I have now got in solution—
3CuSO4 + Cu(C2H3O2)2,
and I have to transform it into—
3CuAs2O4 + Cu(C2H3O2)2.
It is at once seen that I have got the requisite quantity of acetate formed. I next dissolve the requisite quantity of arsenious anhydride in an amount of carbonate of soda rather less than is sufficient to neutralize the acid in the remaining cupric sulphate, and I then bring the solution to or near the boiling-point by introducing steam into it; the arsenic is dissolved not in the same vessel as the copper salt, but in a separate one. When the arsenic solution is fully heated, a small current of it is allowed to flow into the vat containing the copper salts, and brisk stirring is kept up in the vat. The emerald green is at once formed; but if there should be the slightest formation of any arsenite, the flow of the arsenic solution is at once stopped until every trace of the arsenite has been converted; the arsenic solution is then allowed to flow in again, with the same precautions as before; in this way a large batch of emerald-green can he formed in one or two hours, without containing the slightest trace of the arsenite. I keep the arsenic solution near the boiling-point during the whole of the time it is flowing into the other vessel. By varying the proportions of water I could either make it coarse or fine, as I wished, which is an important matter to have complete control over in its manufacture.
Two points of interest occurred to me during the time I was occupied with the research, which I had not time to complete; one was whether the aceto-arsenite can be formed, adopting the old method for its formation, if there is more than a certain quantity of water; from some experiments I made in this direction I was inclined to the opinion it could not. I have already stated that emerald-green is soluble to a certain extent in acids, and that it is formed in a more or less acid solution; consequently a varying amount of the pigment is always lost by being dissolved in the supernatant liquid. To prevent to a certain extent this loss I precipitated the copper from it as arsenite; but I was not successful in the few experiments I had time to make on this part of the subject of reconverting the copper arsenite thus obtained into the aceto-arsenite by the addition of acetic acid.—Jour. of Science.
This substance is also known by the name Schweinfurt green.
ANALYSIS OF ZINC ASH AND CALCINED PYRITES BY MEANS OF AMMONIUM CARBONATE.
In a recent issue of the Chemiker Zeitung Dr. Kosmann has reported an analytical method for the examination of zinciferous products; according to this report, the ash and flue dust produced by the extraction of zinc from its ore comprise:
- Zinc dust, from the distillation of zinc,
- Flue dust, condensed in chambers of zinc furnaces with Kleemann's receivers,
- Zinc ash, of various assortments, from iron blast furnaces.
Of these, zinc dust is the only ready product which is, as color or reducing agent, employed in analytical and technical processes. Its value, when serving the latter purpose, is determined by the percentage of finely divided metallic zinc and cadmium contained therein; of equal reducing power is cadmium, generally associating zinc; injurious, and therefore uneffective, are zinc oxide and oxides of other metals, also metallic lead.
Flue dust, condensed in chambers of zinc furnaces with Kleemann's receivers, is employed with zinc ores in the extraction of zinc, and in small quantities as substitute for zinc white; its commercial value is similarly estimated as that of zinc ores.
The various modifications of zinciferous flue ashes from blast furnaces are an object for continual demand, being both a valuable material for the production of zinc and, in its superior qualities, a desirable pigment. In the regeneration of zinc the presence of foreign substances is of some concern; detrimental are lead, sulphur, and sulphuric acid in form of lead, zinc, and lime sulphate.
The chemico-technical analysis of these products has until recently been confined to the volumetric determination of zinc by means of sodium sulphide (Schaffner's method). But as a remnant of sulphur, as sulphuric acid, in roasted blende causes a material loss during distillation, and otherwise being induced to produce a zinc free of lead, the estimation of sulphur, sulphuric acid, and lead became necessary. These impurities are determined by well-known methods; sulphur is oxidized and precipitated with barium chloride, lead by sulphuric acid and alcohol. The examination of zinc dust, when used for the regeneration of metal, determines the quantity of zinc resident therein, and employed as reducing agent, the quantity of metal which causes the generation of hydrogen. Cadmium, showing the same deportment, must also be considered as well as lead and arsenic.
A most complete and rapidly working method for the examination of zinciferous products has originated with the application of neutral ammonium carbonate as solvent. A solution of this preparation is made, according to H. Rose, by dissolving 230 grm. commercial ammon carbonate in 180 c.c. ammoniacal liquor of 0.92 s.g., and, by addition of water, augmenting it to one liter.
This solution dissolves the metallic components, their oxides, and basic zinc sulphate, and transfers cadmium and lead oxide, also lead, magnesium, and lime sulphate, into insoluble carbonates. Iron and manganese, when present as protoxide, are dissolved; of iron sesquioxide but traces, and of cadmium oxide in statu nascendi a small portion enter into solution. The solution of ammonium carbonate contains in each 10 c.c. 1 grm. ammonia, which dissolves 1.5 grm. zinc.
The sample for examination is moistened with water and mixed with an adequate volume of the solvent, is digested at 50-60° C. until complete decomposition is effected. The heating of the liquid prevents the solution of iron, manganese, and cadmium. The content, sediment and liquid, is thrown on a filter and washed with hot water to which a small quantity of the solvent has been added. When the solution contains iron and manganese, it is separated by decantation from the sediment and oxidized with bromine (according to the method of Nic-Wolff) until a flocculent precipitate of iron sesquioxide and manganese dioxide becomes visible; it is united with the original residue and filtered.
The filtrate is diluted till it appears cloudy, boiled to expel ammonia, tested with sodium sulphide upon the presence of zinc, and, when freed of all zinc, decanted. The precipitate of zinc carbonate is filtered, exhausted with water, transferred into zinc oxide by ignition, and weighed. The gravimetric method can be substituted by the volumetric by introducing a solution of sodium sulphide of known strength into the ammoniacal filtrate. On dividing the filtered liquid into various equal portions other substances, arsenic and sulphuric acid, can be determined from the same sample. For this purpose the filtrate is concentrated; divided into two equal portions, one of which is acidified and treated with hydrogen sulphide for the determination of arsenic, the other is acidified and used for the estimation of sulphuric acid by means of barium chloride. The original residue is dissolved in muriatic or acetic acid and filtered. The lead of the filtered liquid is thrown down by sulphuric acid, and alcohol, and cadmium, after dissipation of alcohol into gas, precipitated by hydrogen sulphide. Iron, manganese, alumina, and other substances present in the solution are determined by known methods.
It is manifest that the determination of substances—zinc, lead, and sulphuric acid—which are of importance in technical analysis of zinc ash, can be executed by this method within a comparatively short time. The application of ammonium carbonate as solvent has the advantage, over the application of ammonia, that it is a far better solvent, that it decomposes insoluble basic sulphates, and that the remaining carbonates are readily dissolved by acids.
The decomposition of zinc dust is accompanied by a lively evolution of gas; it is therefore necessary to continue the digestion of the sample till no more hydrogen is given off. Zinc dust contains both metals and their oxides, and methods which, from the volume of hydrogen generated, determine indirectly the percentage of metallic zinc do not give the real composition of the zinc dust. For the determination of the metallic components the material is digested with a solution of copper sulphate, which dissolves zinc and cadmium; the liquid is filtered, acidified, and decomposed with hydrogen sulphide, or treated with a solution of ammonium carbonate. The use of cupric chloride is not advisable, as it corrodes lead, and gives rise to the formation of soluble chloride of lead, which complicates the separation of zinc from cadmium. The best mode of operation is the following: Both copper sulphate and zinc dust are weighed separately, the former is dissolved in water and the latter introduced into the solution of copper sulphate in small portions until it appears colorless. During the operation the vessel is freely shaken, lumps are comminuted with a glass rod, and a few drops of the liquid are ultimately tested with hydrogen sulphide or ammonia. The remainder of zinc dust is then weighed, and its value deducted from the original weight. Zinc and cadmium of the filtrate are determined as above. On repeating this method several times most satisfactory results are obtained.
Another mode of operating is to employ an excess of copper sulphate and to determine the copper dissolved in the filtrate. The separation of copper from cadmium being difficult and laborious, and the volumetric estimation with potassium cyanide not practicable, it is not prudent to apply this method.
When calcined zinciferous pyrites have to be examined, the estimation of zinc is similar to that employed in the analysis of zinc ore. The sample is exhausted with water, filtered, and, to eliminate calcium sulphate and basic iron sulphate, evaporated to dryness. It is then dissolved in a small quantity of alcohol and water, refiltered, and the filtrate decomposed with ammonium carbonate. The original residue is treated with a solution of ammonium carbonate, which dissolves arsenious acid and basic zinc sulphate, filtered, and united with the first filtrate. When iron and manganese are present, the filtrates are treated with bromine. The united filtrates are boiled or examined volumetrically with sodium sulphide.
PETROLEUM AS FUEL IN LOCOMOTIVE ENGINES.[[2]]
By Mr. THOMAS URQUHART.
Comparing naphtha refuse and anthracite, the former has a theoretical evaporative power of 16.2 lb. of water per lb. of fuel, and the latter of 12.2 lb., at a pressure of 8 atm. or 120 lb. per square inch; hence petroleum has, weight for weight, 33 per cent. higher evaporative value than anthracite. Now in locomotive practice a mean evaporation of from 7 lb. to 7½ lb. of water per lb. of anthracite is about what is generally obtained, thus giving about 60 per cent. efficiency, while 40 per cent. of the heating power is unavoidably lost. But with petroleum an evaporation of 12.25 lb. is practically obtained, giving 12.25/16.2 = 75 per cent. efficiency. Thus in the first place petroleum is theoretically 33 per cent. superior to anthracite in evaporative power; and secondly, its useful effect is 25 per cent. greater, being 75 percent. instead of 60 percent.; while, thirdly, weight for weight, the practical evaporative value of petroleum must be reckoned as at least from (12.25 - 7.50)/7.50 = 63 per cent. to (12.25 - 7.00)/7.00 = 75 per cent. higher than that of anthracite.
Spray injector.—Steam not superheated, being the most convenient for injecting the spray of liquid fuel into the furnace, it remains to be proved how far superheated steam or compressed air is really superior to ordinary saturated steam, taken from the highest point inside the boiler by a special internal pipe. In using several systems of spray injectors for locomotives, the author invariably noticed the impossibility of preventing leakage of tubes, accumulation of soot, and inequality of heating of the fire box. The work of a locomotive boiler is very different from that of a marine or stationary boiler, owing to the frequent changes of gradient on the line, and the frequent stoppages at stations. These conditions render firing with petroleum very difficult; and were it not for the part played by properly arranged brickwork inside the fire box, the spray jet alone would be quite inadequate. Hitherto the efforts of engineers have been mainly directed toward arriving at the best kind of "spray injector," for so minutely subdividing a jet of petroleum into a fine spray, by the aid of steam or compressed air, as to render it inflammable and of easy ignition. For this object nearly all the known spray injectors have very long and narrow orifices for petroleum as well as for steam; the width of the orifices does not exceed from ½ mm. to 2 mm. or 0.02 in. to 0.08 in., and in many instances is capable of adjustment. With such narrow orifices it is clear that any small solid particles which may find their way into the spray injector along with the petroleum will foul the nozzle and check the fire. Hence in many of the steamboats on the Caspian Sea, although a single spray injector suffices for one furnace, two are used, in order that when one gets fouled the other may still work; but, of course, the fouled orifices require incessant cleaning out.
Locomotives.—In arranging a locomotive for burning petroleum, several details are required to be added in order to render the application convenient. In the first place, for getting up steam to begin with, a gas pipe of 1 inch internal diameter is fixed along the outside of the boiler, and at about the middle of its length it is fitted with a three-way cock having a screw nipple and cap. The front end of the longitudinal pipe is connected to the blower in the chimney, and the back end is attached to the spray injector. Then by connecting to the nipple a pipe from a shunting locomotive under steam, the spray jet is immediately started by the borrowed steam, by which at the same time a draught is also maintained in the chimney. In a fully equipped engine shed the borrowed steam would be obtained from a fixed boiler conveniently placed and specially arranged for the purpose of raising steam. In practice steam can be raised from cold water to 3 atm. pressure—45 lb. per square inch—in twenty minutes. The use of auxiliary steam is then dispensed with, and the spray jet is worked by steam from its own boiler; a pressure of 8 atm.—120 lb.—is thus obtained in fifty to fifty-five minutes from the time the spray jet was first started. In daily practice, when it is only necessary to raise steam in boilers already full of hot water, the full pressure of 7 to 8 atm. is obtained in from twenty to twenty-five minutes. While experimenting with liquid fuel for locomotives, a separate tank was placed on the tender for carrying the petroleum, having a capacity of about 3 tons. But to have a separate tank on the tender, even though fixed in place, would be a source of danger from the possibility of its moving forward in case of collision. It was therefore decided, as soon as petroleum firing was permanently introduced, to place the tank for fuel in the tender between the two side compartments of the water tank, utilizing the original coal space. For a six-wheeled locomotive the capacity of the tank is 3½ tons of oil—a quantity sufficient for 250 miles, with a train of 480 tons gross exclusive of engine and tender. In charging the tender tank with petroleum, it is of great importance to have strainers of wire cloth in the manhole of two different meshes, the outer one having openings, say, of ¼ in., the inner, say ⅛ in.; these strainers are occasionally taken out and cleaned. If care be taken to prevent any solid particles from entering with the petroleum, no fouling of the spray injector is likely to occur; and even if an obstruction should arise, the obstacle being of small size can easily be blown through by screwing back the steam cone in the spray injector far enough to let the solid particles pass and be blown out into the fire-box by the steam. This expedient is easily resorted to even when running; and no more inconvenience arises than an extra puff of dense smoke for a moment, in consequence of the sudden admission of too much fuel. Besides the two strainers in the manhole of the petroleum tank on the tender, there should be another strainer at the outlet valve inside the tank, having a mesh of ⅓ in. holes.
Driving locomotives.—In lighting up, certain precise rules have to be followed, in order to prevent explosion of any gas that may have accumulated in the fire box. Such explosions do often take place through negligence; but they amount simply to a puff of gas, driving smoke out through the ash-pan dampers, without any disagreeably loud report. This is all prevented by adhering to the following simple rules: First clear the spray nozzle of water by letting a small quantity of steam blow through, with the ash-pan doors open; at the same time start the blower in the chimney for a few seconds, and the gas, if any, will be immediately drawn up the chimney. Next place on the bottom of the combustion chamber a piece of cotton waste, or a handful of shavings saturated with petroleum and burning with a flame. Then by opening first the steam valve of the spray injector, and next the petroleum valve gently, the very first spray of oil coming on the flaming waste immediately ignites without any explosion whatever; after which the quantity of fuel can be increased at pleasure. By looking at the top of the chimney, the supply of petroleum can be regulated by observing the smoke. The general rule is to allow a transparent light smoke to escape, thus showing that neither too much air is being admitted nor too little. The combustion is quite under the control of the driver, and the regulation can be so effected as to prevent smoke altogether. While running, it is indispensable that the driver and fireman should act together, the latter having at his side of the engine the four handles for regulating the fire, namely, the steam wheel and the petroleum wheel for the spray injector, and the two ash-pan door handles in which there are notches for regulating the air admission. Each alteration in the position of the reversing lever or screw, as well as in the degree of opening of the steam regulator or the blast pipe, requires a corresponding alteration of the fire. Generally the driver generally passes the word when he intends shutting off steam, so that the alteration in the firing can be effected before the steam is actually shut off; and in this way the regulation of the fire and that of the steam are virtually done together. All this care is necessary to prevent smoke, which is nothing less than a waste of fuel. When, for instance, the train arrives at the top of a bank, which it has to go down with the brakes on, exactly at the moment of the driver shutting off the steam and shifting the reversing lever into full forward gear, the petroleum and steam are shut off from the spray injector, the ash-pan doors are closed, and if the incline be a long one, the revolving iron damper over the chimney top is moved into position, closing the chimney, though not hermetically. The accumulated heat is thereby retained in the fire-box; and the steam even rises in pressure, from the action of the accumulated heat alone. As soon as the train reaches the bottom of the incline and steam is again required, the first thing done is to uncover the chimney top; then the steam is turned on to the spray injector, and next a small quantity of petroleum is admitted, but without opening the ash-pan doors, a small fire being rendered possible by the entrance of air around the spray injector, as well as by possible leakage past the ash-pan doors. The spray immediately coming in contact with the hot chamber ignites without any audible explosion; and the ash-pan doors are finally opened, when considerable power is required, or when the air otherwise admitted is not sufficient to support complete combustion. By looking at the fire through the sight hole it can always be seen at night whether the fire is white or dusky; in fact, with altogether inexperienced men it was found that after a few trips they could become quite expert in firing with petroleum. The better men contrive to burn less fuel than others, simply by greater care in attending to all the points essential to success. At present seventy-two locomotives are running with petroleum firing; ten of them are passenger engines, seventeen are eight-wheel coupled goods engines, and forty-five are six-wheel coupled. As might be expected, several points have arisen which must be dealt with in order to insure success. For instance, the distance ring between the plates around the firing door is apt to leak, in consequence of the intense heat driven against it, and the absence of water circulation; it is therefore either protected by having the brick arch built up against it, or, better still, it is taken out altogether when the engines are in for repairs, and a flange joint is substituted, similar to what is now used in the engines of the London and Northwestern Railway. This arrangement gives better results, and occasions no trouble whatever.
Storage of petroleum.—The length of line now worked with petroleum is from Tsaritsin to Burnack, 291 miles. There is a main iron reservoir for petroleum at each of the four engine sheds, namely at Tsaritsin, Archeda, Filonoff, and Borisoglebsk. Each reservoir is 66 ft. internal diameter and 24 ft. high, and when full holds about 2,050 tons. The method of charging the reservoir, which stands a good way from the line, and is situated at a convenient distance from all dwelling houses and buildings, is as follows: On a siding specially prepared for the purpose are placed ten cistern cars full of oil, the capacity of each being about ten tons. From each of these cars a connection is made by a flexible India rubber pipe to one of ten stand pipes which project 1 ft. above the ground line. Parallel with the rails is laid a main pipe, with which the ten stand pipes are all connected, thus forming one general suction main. About the middle of the length of the main, which is laid underground and covered with sawdust or other non-conducting material, is fixed a Blake steam pump. As soon as all the ten connections are made with the cistern cars, the pump is set to work, and in about one hour the whole of the cars are discharged into the main reservoir, the time depending of course upon the capacity of the pump. All the pipes used are of malleable iron, lap-welded, and of 5 in. internal diameter, having screwed coupling muffs for making the connections. At each engine shed, in addition to the main storage reservoir, there is a smaller distributing tank, which is erected at a sufficient height to supply the tenders, and very much resembles the ordinary water tanks. These distributing tanks are circular, about 8½ ft. diameter and 6 ft. high, and of ¼ in. plates; their inside mean area is calculated exactly, and a scale graduated in inches stands in the middle of the tank; a glass with scale is used outside in summer time. Each inch in height on the scale is converted into cubic feet, and then by means of a table is converted into Russian poods, according to the specific gravity at various temperatures. As it would be superfluous to graduate the table for each separate degree of temperature, the columns in the table show the weights for every 8 degrees Reaumur, which is quite sufficient: namely, from 24 deg. to 17 deg., from 16 deg. to 9 deg., and so on, down to -24 deg.; the equivalent Fahrenheit range being from 86 deg. down to -22 deg. Suppose the filling of a tender tank draws off a height of 27 in. from the distributing tank, at a temperature of say -20 deg. R., these figures are shown by the table to correspond with 200.61 poods = 7,245 lb., or 3.23 tons, of petroleum. This arrangement does very well in practice; both the quantity and the temperature are entered on the driver's fuel bill at the time of his taking in his supply.
Engines.—The engines used in the trials were built by Borsig, of Berlin, Schneider, of Creusot, and the Russian Mechanical and Mining Company, of St. Petersburg. Their main dimensions and weights were about the same, as follows, all of them having six wheels coupled, and 36 tons adhesive weight; as originally constructed they had ordinary fire boxes for burning anthracite or wood; cylinders 18⅛ in. diameter and 24 in. stroke; slide valves, outside lap 1-1/16 in., inside lap 3/32 in., maximum travel, 4-9/16 in.; Stephenson link motion; boiler pressure, 120 lb. per square inch; six wheels, all coupled, 4 ft. 3 in. in diameter; distance between centers of leading and middle wheels, 6 ft. 2¾ in.; between middle and trailing, 4 ft. 9¼ in.; total length of wheel base, 11 ft.; weight empty, on leading wheels, 12.041 tons; middle, 10.782 tons; trailing, 10.685 tons; total weight, 33.508 tons empty; weight in running order, on leading wheels, 12.563 tons; middle, 11.885 tons; trailing 12.790 tons; total weight, 37.238 tons in running order. Tubes number 151; outside diameter, 2⅛ in.; length between tube plates, 13 ft. 10⅛ in.; outside heating surface, 1,166 square feet; fire box heating surface, 82 square feet; total heating surface, 1,248 square feet; fire grate area, 17 square feet;tractive power = 65 per cent. of boiler pressure × (cyl. diam.)² × stroke / diameter of wheels = 0.65 × 120 × (18.125)² × 24 / 51 = 5.383 tons. Ratio of tractive power to adhesion weight = 5.383 / 37.238 = 1 / 6.9.
Tender.—Contents: water, 310 cubic feet, or 1,933 gallons, or 8½ tons; anthracite, 600 poods, or 10 tons; or wood, 1½ cubic sajene, or 514 cubic feet; weight empty, 13.477 tons; weight in running order, 28.665 tons; six wheels.
Petroleum Refuse—Comparative Trials with Petroleum, Anthracite, Bituminous Coal, and Wood, between Archeda and Tsaritsin on Grazi and Tsaritsin Railway, in Winter Time.
-----+----+-----+------+---+-----+------+-----------+-------------+------+------------
| L | | | | | | | |
| o | | Train | | | | Consumption | |
| c | | alone. | | | | Including | |
Date.| o | | | | | | Lighting up.| |
1883.| m | |----+-----| | | | | Cost |
| o |Train|Num-| | Dis-| Car | | | of |Atmospheric
| t | |ber |Gross|tance|miles.| Fuel. |-------+-----| fuel |temperature
| i | | of |load.| run.| | | | Per | per | and
| v | |Loa-| | | | | Total |train| train| weather.
| e | |ded | | | | | |mile.| mile.|
| . | |cars| | | | | | | |
-----+----+-----+----+-----+-----+------+-----------+-------+-----+------+------------
| | | No.| Tons|Miles| | | | |Pence.|
-----+----+-----+----+-----+-----+------+-----------+-------+-----+------+------------
| 8 |32-23| 25 | 400 | 388 | 9,700|Anthracite.| 31799 |81.90|11.957|-17° to -18°
| |32-23| | | | | | lb. | lb. | | Reau.,
Feb.| | | | | | | | | | | equiv. to
8 | |24-21| | | | | | | | |-6° to -8½°
| 14 |24-21| 25 | 400 | 388 | 9,700|Bituminous |37557.5|96.53|14.093| Fah.
| | | | | | | Coal. | lb. | lb. | |
| 7 |26-29| 25 | 400 | 194 | 4,830|Petroleum | 9462 |48.77| 5.487| Strong
| | | | | | refuse. | lb. | lb. | | side wind.
-----+----+-----+----+-----+-----+------+-----------+-------+-----+------+------------
| 24 |32-23| 25 | 400 | 194 | 4,850|Anthracite.|12639.5|65.15| 9.512|-5° to -9°
March| | | | | | | | lb. | lb. | | Reau.,
6 | 21 |24-21| 25 | 400 | 194 | 4,850|Wood, in | 1071.8| 5.52| 8.5 | equiv. to
| | | | | | | billets. | c. ft.|c. ft| | 21° to 12°
| | | | | | | | | Fah.
| 23 |26-27| 25 | 400 | 194 | 4,850|Petroleum | 7228 |37.28| 4.188| Light
| | | | | | refuse. | lb. | lb. | | side wind.
-----+----+-----+----+-----+-----+------+-----------+-------+-----+------+-----------
Prices of fuel:
Petroleum refuse, 21s. per ton; Anthracite and bituminous coal, 27s. 3d. per ton;
Wood, in billets, 42s. per cubic sajene = 343 cubic feet;
equivalent to 1.47d. per cubic foot.
Dimensions of locomotives:
Cylinders, 18 ⅛ in. diam. and 24 in. stroke; Wheels, 4 feet 3 in. diam.;
Total heating surface, 1,248 sq. feet: Total adhesion weight, 36 tons;
Boiler pressure, 8 to 9 atm.
The preceding table shows the results of comparative trials made in winter with different sorts of fuel, under exactly similar conditions as to type of engine, profile of line, and load of train. Two sets of comparative trials were made, both of them in winter. The three engines used were some of those built by Schneider. In comparison with anthracite, the economy in favor of petroleum refuse was 41 per cent. in weight, and 55 per cent. in cost. With bituminous coal there was a difference of 49 per cent. in favor of petroleum as to weight and 61 per cent. as to cost. As compared with wood petroleum was 50 per cent. cheaper. At a speed of fourteen miles an hour up an incline of 1 in 125 the steam pressure was easily kept up at 9 to 9½ atm. with a No. 9 injector feeding the boiler all the time.
Up to the present time the author has altered seventy-two locomotives to burn petroleum; and from his own personal observations made on the foot plate with considerable frost he is satisfied that no other fuel can compare with petroleum either for locomotives or for other purposes. In illustration of its safety in case of accident, a photograph was exhibited of an accident that occurred on the author's line on 30th December, 1883, when a locomotive fired with petroleum ran down the side of an embankment, taking the train after it; no explosion or conflagration of any kind took place under such trying circumstances, thus affording some proof of the safety of the petroleum refuse in this mode of firing. Although it is scarcely possible that petroleum firing will ever be of use for locomotives on the ordinary railways of coal-bearing England, yet the author is convinced chat, even in such a country, its employment would be an enormous boon on underground lines.
Abstract of paper read before the Institution of Mechanical Engineers.
CHARCOAL KILNS.
KILN FOR BURNING CHARCOAL.
In answer to the inquiry of a correspondent about charcoal making, we offer two illustrations that show a method of manufacture differing from that usually adopted, which is that of burning on the bare ground, and covering with soil or sods to exclude the air. These kilns are made of brick, one course being sufficient, bands of iron or timber framework being added to strengthen the brickwork with greater economy. The usual style is conical, and the size is 24 feet in diameter, with an equal height, holding about 40 cords of wood. The difference in price is 1⅛ d. per bushel in favor of these kilns as compared with the usual mounds, the burner being furnished with the use of the kilns, and the timber standing, the kiln burning costing 2⅛ d., and the other 3¼ d. The kilns must be lined to about halfway up with fire-brick, the cost of which will vary with the locality, but will be about £200, and as 40 to 50 bushels of coal have been made per cord the extra yield on good charcoal and the lessening of the cost of making soon covers any extra outlay on the cost of the kilns. The wall of the kiln is carried up nearly straight for 6 feet, when it is drawn in, so as to become bluntly conical. Upon the top a plate of iron is fastened in the manner of the keystone of an arch, and bands of iron are passed round the kiln and drawn tight with screw bolts and nuts to strengthen it. Double doors of sheet-iron are made at the bottom and near the tops, by which it is either filled or emptied, and a few air-holes (B), which may be stopped with loose bricks, left in the bottom. The second figure shows a kiln of another shape made to burn 3,000 bushels of charcoal, or about 80 cords of wood. The shape is a parallelogram, having an arched roof, and it is strengthened by a framework of timber 10 inches square. As the pressure of the gas is sometimes very great, the walls must be built a brick and a half thick to prevent their bursting. The usual size is 16 feet wide and high, and 40 feet in length, outside measure. The time occupied in filling, burning, and emptying a small cone is about three weeks, and four weeks is required for the larger ones.—The Gardeners' Chronicle.
KILN FOR BURNING CHARCOAL.
ENTRANCE, TIDDINGTON HOUSE, OXON.
Our illustration is a view of the entrance facade to Tiddington House, Oxfordshire, the residence of the Rev. Joshua Bennett. The house is an old building of the Georgian period, and though originally plain and unpretentious, its bold coved cornices under the eaves, its rubbed and shaped arches, moulded strings, and thick sash bars, made it of considerable interest to the admirers of the "Queen Anne" school of architecture, and led to the adoption of that style in the alterations and additions made last year, of which the work shown in our illustration formed a small part. Between the "entrance facade" and the wall of the house there is a space of some twenty feet in length, which is inclosed by a substantially built conservatory-like erection of Queen Anne design, forming an outer hall.
ENTRANCE TIDDINGTON HOUSE OXON.—Morris & Stallwood—Architects.
The works were executed by Messrs. Holly & Butler, of Nettlebed. The brick carving was beautifully done by the late Mr. Finlay; and the architects were Messrs. Morris & Stallwood, of Reading.—The Architect.
NEW ARRANGEMENT OF THE BICHROMATE OF POTASH PILE.
Since Poggendorff in 1842 thought of substituting in the Bunsen battery a solution of bichromate of potash and sulphuric acid for nitric acid, and of thus making a single liquid pile of it, in suppressing the porous vessel, his idea has been taken up a considerable number of times. Some rediscovered it simply, while others, who were better posted in regard to the work of their predecessors, took Poggendorff's pile as he conceived it, and, considering the future that was in store for it, thought only of modifying it in order to render it better. Among these, Mr. Grenet was one of the first to present the bichromate of potash pile under a truly practical form. As long ago as 1856, in fact, he gave it the form that is still in use, and that is known as the bottle pile. Thus constructed, this pile, as is well known, presents a feeble internal resistance, and a greater electro-motive power than the Bunsen element. Unfortunately, its energy rapidly decreases, and the alteration of the liquid, as well as the large deposit of oxide of chromium that occurs on the positive electrode, prevents its being employed in experiments of quite long duration. Mr. Grenet, it is true, obviated these two defects by first renewing the liquid slowly and continuously, and causing a current of air to bubble up in the pile so as to detach the oxide of chromium in measure as the deposit formed. Thus improved, the bichromate pile was employed on a large scale in the lighting of the Comptoir d'Escompte. In an extensive application like this latter, the use of compressed air for renewing the liquid can be easily adapted to the bichromate pile, as the number of elements is great enough to allow of the putting in of all the piping necessary; but when it is only desired to use this pile for laboratory purposes, and when there is need of but a small number of elements, it is impossible to adopt Mr. Grenet's elements in the form required by an electric lighting installation. It becomes absolutely necessary, then, to come back to a simpler form, and attempt at the same time to obviate the defects which are inherent to its very principle. In accordance with this idea, it will be well to point out the arrangement adopted by Mr. Courtot for his bichromate of potash piles—an arrangement that is very simple, but, sufficiently well worked out to render the use of it convenient in a laboratory.
Fig. 1.—COURTOT'S ARRANGEMENT OF THE BICHROMATE PILE.
Fig. 1 gives the most elementary form. It consists of an earthen vessel into which dip four carbon plates connected with each other by a copper ring which carries one of the terminals. In the center there is a cylindrical porous vessel that contains a very dilute and feebly acidulated solution of bichromate of potash into which dips a prism of zinc, which may be lifted by means of a rod when the pile ceases to operate. It is true that the presence of the porous vessel in the bichromate of potash element increases the internal resistance, but, as an offset, although it decreases the discharge, it secures constancy and quite a long duration for it.
Fig. 2.—COURTOT'S ARRANGEMENT OF THE BICHROMATE PILE.
The elements thus constituted may be grouped, to the number of six, in a frame analogous to that shown in the engraving, and, sum total, form a small sized battery adapted to the current experiments of the laboratory, and capable of supplying two small four volt lamps for ten or twelve hours. We have had occasion to make use of these elements for the graduation of galvanometers, and, after ascertaining the constancy of the discharge, have found that the internal resistance of each couple is nearly 0.175 ohm, with an electro-motive force of two volts. As may be seen, these elements should, in general, all be mounted for tension, as they are in the figure, inasmuch as the mobility of the zincs permits, according to circumstances, of employing a variable number of them without changing anything. Moreover, with zincs amalgamated in a special manner, the attack is imperceptible, and the work in open circuit need scarcely to be taken into consideration.
Yet, despite the qualities inherent to the arrangement that we have just described, that defect common to all bichromate of potash piles—the deposit of oxide of chromium upon the carbon—is not here avoided. It occurs quite slowly, to be sure, but it does occur, and, from this point of view, the arrangement shown in Fig. 2 is preferable. The elements here are composed of prismatic porcelain vessels containing, as before, the solution and porous vessel.
Fig. 3.—COURTOT'S ARRANGEMENT OF THE BICHROMATE PILE.
The whole is covered with a sheet of ebonite connected with the zinc and the two carbon plates in such a way that when the pile is not in operation the whole can be lifted from the liquid. Under such circumstances the deposit of oxide is notably diminished, and the duration of the discharge is consequently greatly increased.
Fig. 3 shows the details of a windlass that permits of lifting, according to circumstances, all the elements of the same trough or only a part of them. To effect this, the drum around which the chain winds that carries the carbons is mounted upon a sleeve fixed upon the axle. This latter is actuated by a winch; and a ratchet wheel, R, joined to a click which is actuated by a spiral spring, prevents the ebonite plates from falling back when it is desired to place the bolt under the button, B, of the spring.
When it is desired to put an element out of the circuit, it is only necessary to act with the finger upon the extremity of the lever, D. Under the action of the latter, the piece, s, which carries a groove for the passage of the screws that fix it to the upper cross-piece, takes on a longitudinal motion and consequently gears with the drum through the toothed sleeve, E. When an experiment is finished the zinc may thus be lifted from the liquid, and the deposit of oxide be prevented from forming upon the carbon. As may be seen, the arrangements which we have just described exhibit nothing that is particularly original. The windlasses used for removing the elements from a pile when the circuit is open have been employed for a long time; the bichromate pile is itself old, and, as we said in the beginning, it has been modified in its details a number of times. In spite of this, we have thought it well to point out the mode of construction adopted by Mr. Courtot, since, owing to the simplicity of the arrangements, it renders convenient and easily manageable a pile of very great constancy that may be utilized for supplying incandescent lamps, as well as for the most varied experiments of the laboratory.—La Lumiere Electrique.
THE DISTRIBUTION OF ELECTRICITY BY INDUCTION.
There has been much said in recent times about the distribution of electricity by means of induction coils, and the use of this process has given rise to several systems that differ but little from one another in principle.
The following are a few details in regard to a system due to a Dutch engineer:
In the month of December, 1881, a patent relating to the distribution of electricity was taken out in Germany and other countries by Mr. B. Haitzema Enuma, whose system is based upon a series of successive inductions. The primary current developed by a dynamo-electric machine gives rise to secondary, tertiary, etc., currents. The principal line runs through the streets parallel with their axes, and, when the arrangement of the places is adapted thereto, it is closed upon the generator itself. In those frequent cases where it is necessary to cause the line to return over a path that it has already traversed, it is more advantageous to effect the return through the earth or to utilize the street water mains or gas pipes as conductors. This return arrangement may likewise be applied to the lines of secondary, tertiary, etc., order, as may easily be seen.
The induction is effected by the aid of bobbins whose interior consists of a bundle of soft iron. The wire of the inducting current is wound directly around this core. The wire of the induced current is superposed upon the first and presents a large number of spirals. It is useless to say that these wires must be perfectly insulated from each other, as well as from the soft iron core. We shall call primary bobbins those which are interposed in the principal line, and secondary bobbins those in which the inducting current is a secondary one, and so on.
It will be at once seen that this arrangement permits of continuing the distribution of electricity to the interior of buildings by the simple adjunction of one or several bobbins. Each electric apparatus, whether it be a lamp or other mechanism, is furnished with a special current. If the number of these apparatus be increased, it is only necessary to increase the number of bobbins in the same ratio, on condition, be it understood, that the intensity of the currents remain sufficient to secure a proper working of the apparatus in question. When such intensity diminishes to too great a degree, the bobbin must be replaced by a stronger one.
DISTRIBUTION OF ELECTRICITY BY INDUCTION.
It results from what precedes that each apparatus must be put in in such a way as to permit, of the opening and closing of the corresponding circuit. This arrangement, moreover, has no need of being dependent upon the apparatus, and may just as well be transferred to any part of this same circuit. As regards lighting, it is preferable to employ alternating current dynamo machines; yet there is nothing to prevent the use of continuous current ones, provided that there is an arrangement that permits of constantly opening and closing this same circuit. That portion of the line which is placed under ground is insulated in the ordinary way at the places where it is necessary. As for the underground circuit and the induction coils connected therewith, these are protected against all external influence, and are at the same time insulated very economically by covering them with a coat of very fine silicious sand mixed with asphalt.
It is only necessary to inspect the annexed figure to get an accurate idea of this system of distribution. C represents the building in which the generator of electricity, D, is placed; B, the public street, and Q the house of a subscriber. The principal line, E, starts from the terminals, a, b, of the machine, passes through the primary bobbins, G, and is closed through the earth at F. It will be seen that the primary current communicates through d and c with the internal winding of the bobbins, G, while the secondary currents, H, are connected through e and fwith the external winding. The same arrangement is repeated for the tertiary currents, M, and the quaternary ones, o, p. In the annexed example all the lines that run parallel with the axis of the streets are closed through the earth, while those that have a direction perpendicular thereto enter the houses of subscribers and form a closed circuit. In the interior of these houses the wires, as well as the induction coils, are insulated and applied to the walls. At Q is represented the arrangement that would have to be adopted in the case of a structure consisting of a vestibule, r, and two rooms, s, lighted by two electric lamps, R. In the portion of the figure situated to the left it is easy to see the process employed for insulating the line. A commencement is made by digging a ditch in the street and paving the bottom of it with bricks. Upon these latter there is laid a mixture of sand and asphalt, and then the wires and bobbins are put in, and the whole is finally covered with a new insulating layer.
It is a simple statement that we make here, and it is therefore not for us to discuss the advantages and disadvantages of the system. If we are to believe Mr. Enuma, the advantages are very numerous, to wit: (1) The cables have no need of being of large size; (2) the intensity is the same through the entire extent of the primary circuit, secondary one, etc.; (3) the resistance is invariable in all portions of the line; (4) the apparatus are independent of each other, and consequently there may be a disturbance in one or several of them without the others suffering therefrom; (5) either a strong or weak luminous intensity may be produced, since, that depends only upon the size of the coil employed; (6) there is no style of lamp that may not be used, since each lamp is mounted upon a special circuit; (7) any number of lamps may be lighted or extinguished without the others being influenced thereby; (8) when a fire or other accident happens in a house, it in no wise interferes with the service in the rest of the line; (9) the system could, were it required, be connected with any other kind of existing line; and (10) the cost of installation is infinitely less than that of a system of gas pipes embracing the same extent of ground.—La Lumiere Electrique.
ELECTRICITY APPLIED TO THE STUDY OF SEISMIC MOVEMENTS.
Italy, with her volcanic nature, has very naturally made a specialty of movements of the ground, or seismic perturbations. So the larger part of the apparatus designed for such study are due to Italians. Several of these instruments have already been, described in this journal, and on the present occasion we shall make known a few others that will serve to give an idea of the methods employed.
For the observation of the vertical and horizontal motions of the ground, different apparatus are required. The following is a description of those constructed for each of such purposes by the Brassart Brothers.
FIG. 1.—APPARATUS FOR THE STUDY OF HORIZONTAL SEISMIC MOVEMENTS.
Apparatus for Studying Horizontal Movements.—A lever, (Fig. 1), movable about a horizontal axis, carries a corrugated funnel, i, at one of its extremities. At the other extremity it is provided with a counterpoise which permits of its being exactly balanced, while not interfering with its sensitiveness.
FIGS. 2 AND 3.—DETAILS OF THE APPARATUS.
The opening of the funnel passes freely around a column, v (Fig. 2), upon which is placed in equilibrium a rod that terminates in a weight, P. The corrugations of the funnel carry letters indicating the four cardinal points, and the funnel itself is capable of revolving in such a way that the marked indications shall always correspond to the real position of the cardinal points. When a horizontal shock occurs, the weight, P, falls in a direction opposite thereto, and into one of the corrugations, where it rests, so that the direction of the shock is indicated. But, in falling, it causes the lever, F, to tilt, and this brings about an electric contact between the screw, h, and the column, n, which sends a current into the electro, E, so that the armature of the latter is attracted. In its position of rest this armature holds a series of parts, S, A, L, which have the effect of stopping the pendulum of a clock placed upon the same apparatus. At the moment, then, that the armature is attracted the pendulum is set free and the clockwork is started. As the current, at the same time, sets a bell ringing, the observer comes and arranges the apparatus again to await a new shock. Knowing the hour at which the hand of the clock was stopped, he sees how long it has been in motion again and deduces therefrom the precise moment of the shock.
The small rod, f, which is seen at the extremity of F, is for the purpose of allowing electricity to be dispensed with, if need be. In this case the screw, h, is so regulated that F descends farther, and that f may depress the armature of the magnet just as the current would have done.
FIG. 4.—APPARATUS FOR THE STUDY OF VERTICAL MOVEMENTS.
Apparatus for the Study of Vertical Movements.—In this apparatus (Fig. 4), the contact is formed between a mercury cup, T, and a weight, D. The cup is capable of being raised and lowered by means of a screw, so that the two parts approach each other very closely without touching. At the moment of a vertical shock a contact occurs between the mercury and weight, and there results a current which, acting upon the electro, E, frees the pendulum of the clock as in the preceding apparatus. In this case, in order that the contact may be continuous and that the bell may be rung, the piece, A, upon falling, sets up a permanent contact with the part, a (Fig. 3).
FIG. 5.—BRASSART'S SEISMIC CLOCK.
Brassart's Seismic Clock.—This apparatus is designed for being put in connection at a distance with an indicator like the ones just described. It is a simple clock to which a few special devices have been added. Seismic clocks may be classed in two categories, according as they are stopped by the effect of a shock or are set running at the very instant one occurs. The Messrs. Brassart have always given preference to those of the second category, because there is no need of watching them during a seismic calm, and because they are much more easily constructed. It is to this class, then, that their seismic clock belongs. It is capable of being used for domestic purposes in place of any other clock, and of becoming a seismoscopic clock as soon as it is put in electric communication with the seismic telltales.
To the cross-piece that holds the axle of the drums the inventors have added (Fig. 5) a support formed of a strip of brass, S, with whose extremity is jointed (at the lower part) a double lever, A. This latter is held in a horizontal position by a small counterpoise, i, so that the finger at the opposite extremity shall prevent the pendulum, P, from swinging. To keep the latter in a position of rest a bent lever, n n', is jointed to the upper part of the support, S. The longer arm, n', of this lever is bent forward at right angles, so that it may come into contact with and repel the small rod of the pendulum as soon as the lever has been lifted by means of a small cord which is connected with the larger arm, n, and runs up to a small hook, from whence it descends and makes its exit under the clock-case.
In order to stop the clock, then, it is only necessary to pull on this cord slightly, when, by moving the pendulum to the left, it will thrust it against the inclined plane of the finger of the lever arm, A. It is clear that the extremity of the pendulum, upon striking against the finger, will depress it slightly and go beyond the projection against which it remains fixed owing to the counterpoise, i. The fever, n n', is brought back to its position of rest by means of a small counterpoise at the extremity of the arm, n. When the lever, A, is depressed, the pendulum escapes and sets the clock running. This depression is effected by means of an electro-magnet, E, whose armature, which is connected with the rod, t, t, lifts the arm, i, of the lever, and depresses A. The wires of the two bobbins of the electro-magnet end in two clamps, 1 and 2. The second of these latter is insulated from the clock-case. Both communicate with the extremities of the circuit in which is interposed the seismic telltale that brings about a closing of the current. Having noted the position of the hands on the dial when the clock was running, one can deduce therefrom the moment at which the shock occurred that set the clock in motion.
In addition to the parts that we have described, there are other accessory ones, R Rr, and a third clamp, 3, which constitute a sort of rheotome that is designed to keep the circuit closed after the momentary closing that is produced by the telltale has occurred. This little mechanism is indispensable when the disturbed telltale has also to act upon an electric bell. This rheotome, which is very simple, is constructed as follows: A small brass rod, R, which is screwed to the support, S, carries at its left extremity a brass axis, X, which is insulated from the rod, R, by means of an ivory piece. Toward the center of this small rod, the bent lever, r, carries a small arm that is bent forward, and against which abuts the axis of the pendulum, thus causing it to be thrust toward the left when the pendulum is arrested by the projection of the finger, A. As soon as the pendulum is set free, the lever, r, redescends and places itself against the axis, X. This latter communicates with clamp 3, which is insulated, while the rod, R, communicates with clamp 1. The external communications are so arranged that the circuit in which the bell is interposed remains definitely closed when the lever, r, is in contact with the rod, X.
FIG. 6.—ROSSI'S TREMITOSCOPE.
Rossi's Tremitoscope.—This instrument (Fig. 6) unites, upon the same stone base, three different arrangements for showing evidences of trepidations of the earth. On one side we find (protected by a glass tube) a weight suspended over a mercury cup by a spring, and designed to show vertical motions. The two other parts of the apparatus are designed for registering horizontal motions. The first is a pendulum which causes a contact with four distinct springs, and whose movements are watched with a spy-glass. The second is a steel spring which carries at its upper part a heavy ball that vibrates at the least shock. This ball is provided with a point which is movable within a second ball, so that its motion produces a contact. All these different contacts are signaled or registered electrically.
FIG. 7.—SCATENI'S SEISMOGRAPH.
Scateni's Registering Seismograph.—This apparatus, which is shown in Figs. 7 and 8, consists of two parts—of a transmitter and of a registering device.
FIG. 8.—REGISTERING APPARATUS.
The transmitter consists of a glass vessel supported upon a steel point and provided beneath with a platinum circle connected with a pile. All around this circle are four strips of platinum, against one of which abuts the circle at every movement of the glass. Each strip of platinum communicates, through a special wire, with one of the electro-magnets of the registering device (Fig. 8). This latter consists of an ordinary clock that carries three concentric dials—one for minutes, one for hours, and one for seconds. In a direction with the radii of these dials there are four superposed levers, each of which is actuated by one of the electros. On another hand, each dial is divided into four zones that correspond to the four cardinal points. When a shock coming from the north, for example, produces a contact, the corresponding electro is affected, and its lever falls and marks upon each of the dials a point in its north zone. We thus obtain the exact hour of the shock, as well as its direction. As may be seen, the apparatus, as regards principle, is one of the simplest of its kind.—La Lumiere Electrique.
NEW ACCUMULATORS.
FIG. 1.—ARNOULD & TAMINE'S ACCUMULATOR.
In Messrs. Arnould and Tamine's accumulators, shown in Fig. 1, the formation is effected directly by the current, as in the Planté pile, but the plates are formed of wires connected horizontally at their extremities by soldering. These plates are held apart either by setting them into paraffined wooden grooves at the ends of the trough or by interposing between them pieces of paraffined wood.
FIG. 2.—BARRIER & TOURVIELLE'S ELECTRODOCK.
In Messrs. Barrier and Tourville's Electrodock (Fig. 2) the plates are formed of concentric leaden tubes fixed into a wooden cover. These tubes are threaded internally and externally, and the grooves thus produced are filled with a peculiar cement composed of litharge, powdered charcoal, and permanganate of potash, triturated together, sifted, and then mixed with glucose or sugar sirup so as to make a paste of them. This mixture forms a cement that is very adhesive after, as well as before, the electrolytic action.
FIG. 3.—KORNBLUH'S ACCUMULATOR.
In Kornbluh's accumulators the plates consist of ribbed leaden gratings between which is compressed red lead prepared in a peculiar manner, and constituting, 48 hours after formation, a compact mass with the lead. The tangs of the plates are widened so as to touch one another while leaving a proper distance between the plates themselves, and are hollowed out for the reception of a rod provided at its extremities with a winged nut and jam nut for passing them up close to one another. The plates, properly so called, are held apart by rubber bauds. The glass vessels are placed in osier baskets.—La Lumiere Electrique.
INDUSTRIAL MODEL OF THE REYNIER ZINC ACCUMULATOR.
The three models of a secondary battery that I recently made known to the readers of this journal have been the object of continuous experiment. Conformably to the provisions of theory, the zinc accumulator has shown itself practically superior to the two others, and I have therefore chosen this type for getting up an industrial model, which is shown in the annexed cut. The accumulator contains four Planté positives, having a wide surface, and three negatives constructed of smooth sheets of lead covered with zinc by the electrolysis of the acidulated solution of zinc sulphate in which the couple is immersed. Accidental contact with the interior of the pile is prevented by glass tubes fixed to the negatives by means of leaden bands. The seven electrodes are carried by as many distinct crosspieces of paraffined wood, which rest upon the edges of the trough and hold the plates at a certain distance from the bottom. These various crosspieces, which touch one another, take the place of a cover. Each plate is provided with a terminal. The four positive terminals are all on the same side, and the three negatives are on the opposite side. Two brass rods ending in a wire-clamp connect the respective terminals of the same name. The trough consists of two oblong wooden receptacles, one within the other, and having a play of several millimeters. This space is lined with a tight, elastic, insulating cement having tar for a base.
REYNIER'S ZINC ACCUMULATOR. (One-fifth actual size.)
The careful insulation of the trough and all parts of the apparatus, and the purity of the metal and its amalgamation, reduce the local attack of the zinc to almost nothing. So the coefficient of restitution is now comparable with that of accumulators of the Planté type.
The following are the principal numerical data of the new zinc accumulator.
| PHYSICAL DATA. | ||
|---|---|---|
| E. | Electromotive force. | 2.36 volts. |
| R. | Mean resistance. | 0.02 ohm. |
| I. | Normal intensity of the discharge current. | 25 amperes. |
| i. | Intensity of the charge current. | 5 to 10 amperes. |
| Q. | Capacity of accumulation after 200 hours'formation. | 550,000 couples. |
| DATA CONCERNING CONSTRUCTION. | ||
|---|---|---|
| Efficient surface of the 4 positiveelectrodes. | 200 square dec. | |
| Efficient surface of the 3 negativeelectrodes. | 15 square dec. | |
| Weight of the positive electrodes. | 8.2 kilogrammes. | |
| Weight of the negative electrodes. | 1.4 kilogrammes. | |
| Weight of the trough. | 2.7 kilogrammes. | |
| Weight of the liquid. | 4.4 kilogrammes. | |
| Weight of the attachments. | 0.46 kilogrammes. | |
| Weight, total. | 17.16 kilogrammes. | |
The total electric work stored up is 130,000 kilogrammeters, or 7,600 kilogrammeters per kilogramme of accumulator. Theory indicates that a zinc accumulator might store up as much as 15,600 kilogrammeters per kilogramme. If the present model gives half less, it is because I have purposely exaggerated the solidity of the trough and the mass of the electrodes.
It should be remarked that this capacity of 7,600 kilogrammeters per kilogramme is much greater than that of any other accumulator constructed in France. The new model possesses, then, despite the size of the positives and the box, a relative lightness that will permit it to take a place upon electric locomotives as well as in fixed installations.
Independently of their use as accumulators, secondary zinc batteries may be utilized as regulating voltameters in lighting by incandescence, for deadening piston strokes, attenuating the irregularities in speed, and covering accidental stoppages.—E. Reynier, in La Nature.
THE HISTORY OF A LIGHTNING FLASH.
By W. SLINGO.
Lately we have all felt, I doubt not, a considerable amount of interest in the various phenomena attending this summer's unusually heavy thunderstorms, accompanied, as they have been, by vivid lightning discharges of a more or less hurtful nature. The list of disasters published in Knowledge, No. 143, might be very materially augmented were we to record such damage as has been wrought since that list was compiled.
There is not, I suppose, in the mind of any intelligent man at the present day a doubt as to the electrical origin of a lightning flash. The questions to be considered are rather whence comes the electricity, and in what way is the thunderstorm brought about. In attempting to answer these questions, sight must not be lost of the fact that the very nature of electricity is in itself almost sufficient to baffle any effort put forth to ascertain from lightning, as such, its whence and its whither.
It is possible, however, with the aid of our knowledge of static electricity, to arrive at hypotheses of a more than chimerical nature. In the first place, that our sphere is a more or less electrified body is generally admitted. More than this, it is demonstrated that the different parts of the earth's surface and its enveloping atmosphere are variously charged. As a consequence of these varying charges, there is a constant series of currents flowing through the various parts of the earth, which show themselves in such telegraph wires as may lie in the direction followed by the currents. Such currents are known as earth currents, and present phenomena of a highly interesting nature. But, apart from these electrical manifestations, there is generally a difference of electrical condition between the various parts of the earth's surface and those portions of the atmosphere adjacent to or above them. Inasmuch as air is one of the very best insulators, this difference of condition (or potential) in any particular region is in most cases incapable of being neutralized or equilibrated by an electric flow. Consequently the air remains more or less continually charged. With these points admitted as facts, the question arises, Whence this electricity? There have been very many and various opinions expressed as to the cause of terrestrial electricity, but far the greater portion of such theories lack fundamental probability, and indicate causes which cannot be regarded as sufficiently extensive or operative to produce such tremendous effects as are occasionally witnessed. I take it that we may safely regard the evolution of electricity as one of the ways in which force exhibits itself, that, in other words, when work is performed electricity may result. When two bodies are rubbed together, electricity is produced, so also is it when two connected metals are immersed in water and one of them is dissolved, or when one of the junctions of two metals is raised to a higher temperature than the other junction. I will go further than this, so far, in fact, as to maintain that there is a reasonable ground for supposing that every movement, whether it be of the mass or among the constituent particles, is attended by a change of electrical distribution; and if this is true, it may easily be conceived that inasmuch as motion is the rule of the universe, there must be a constant series of electrical changes. Now, these changes do not all operate in one direction, nor are they all of similar character, whence it is that not only are there earth currents of feeble electro-motive force, but that this E.M.F. is constantly varying, and that, furthermore, electricity of high E.M.F. is to be met with in various parts of the atmosphere.
With earth currents we have here very little to do. The rotation of the earth is in itself sufficient to generate small currents, and the fact that they vary in strength at regular periods of the day and of the year enforces the suggestion that the sun exerts considerable electrical influence on the earth. Letting it be granted, however, that the earth is variously charged, how comes it that the air is also charged, and with electricity of greater tension than that of the earth itself? It was pointed out by Sir W. Grove that if the extremities of a piece of platinum wire be placed in a candle flame, one at the bottom and the other near the top, an electric current will flow through the wire, indicating the presence of electricity. If an electrified body be heated, the electricity escapes more rapidly as the temperature rises. If a vessel of water be electrified, and the water then converted into steam, the electric charge will be rapidly dissipated. If a vessel containing water be electrified, and the water allowed to escape drop by drop, electricity will escape with each drop, and the vessel will soon be discharged.
We regard it as an established fact that the earth has always a greater or less charge; whence it is safe to assume that in the process of evaporation which is going on all over the surface of the globe, more particularly in equatorial regions, every particle of water, as it rises into the air, carries with it its portion, however minute that portion may be, of the earth's electric charge. This small charge distributes itself over the surface of the aqueous particle, and the vapor rises higher and higher until it reaches that point above which the air is too rare to support it. It then flows away laterally, and as it approaches colder regions gets denser, sinking lower and nearer to the earth's surface. The aqueous particles becoming reduced in size, the extent of their surfaces is proportionately reduced. It follows that as the particles and their surfaces are reduced, the charge is confined to a smaller surface, and attains, therefore, a greater "surface density," or in simpler language, a greater amount of electricity per unit of surface.
Electricity, as above set forth, is in what is known as the "static" condition (to distinguish it from electricity which is being transferred in the form of a current), when it has the property of "repelling itself" to the utmost limits of any conductor upon which it may be confined. This will account for the charge finding its way to the surface of the water particles, and will furthermore account for the greater density of the charge as the particle gets smaller and has the extent of its surface rapidly diminished. It may be mentioned that the surface of a sphere varies as the cube of its radius.
Returning to the discussion of the state of affairs existing when the particles have reached their highest position in the atmosphere, we may imagine that they set themselves off on journeys toward either the north or the south pole. As they pass from the hotter to the colder regions, a number of particles coalesce; these again combine with others on the road until the vapor becomes visible as cloud. The increased density implies increased weight, and the cloud particles, as they sail poleward, descend toward the surface of the earth. Assuming that a spherical form is maintained throughout, the condensation of a number of particles implies a considerable reduction of surface. Thus, the contents of two spheres vary as the cubes of their radii, or eight (the cube of 2) drops on combining will form a drop twice the radius of one of the original drops. We may safely conceive hundreds and thousands of such combinations to take place until a cloud mass is formed, in which the constituent parts are more or less in contact, and, therefore, behave electrically as a single conductor of irregular surface, upon which is accumulated all the electricity that was previously distributed over the surfaces of the millions of particles that now compose it.
The tendency of an electric charge upon the surface of a conductor is to take upon itself a position in which it may approach nearest to an equal and opposite charge; or, if possible, to attain neutrality. If, then, a cloud has a charge, and there is no other cloud above or near it, the charge induces on the adjacent earth surface electricity of the opposite kind. Thus, assuming the cloud to be charged with positive electricity, the subjacent earth will be in the negative state. The two electricities[[3]] exert a strong tendency to combine or to produce neutrality, whence there is a species of stress applied to the intervening air. Possibly the cloud will be drawn bodily toward the earth more or less rapidly, according as the charge is great or small. Or, on the other hand, the cloud may roll on for leagues, carrying its influence with it, so that the various portions of the earth underneath become successively charged and discharged as the cloud progresses on its journey.
Should the cloud be near the earth, or should it be very highly charged, the tension of the two electricities may be so great as to overcome the resistance of the intervening air; and if this resistance should prove too weak, what happens? How does the discharge show itself? It takes place in the form of a lightning flash, and passing from the one surface to the other—or, maybe, simultaneously from both—produces neutrality more or less complete.
There has recently been a little discussion in these pages on the subject of lightning, some having stated that they discerned the discharge to take place upward—that is, from the earth toward the cloud. I will not venture so far as to say whether or not the direction of the discharge is discernible; possibly the flash may sometimes be long enough to enable one to tell; but I have never so seen it, and have always looked upon the eye as a deceitful member—very. "The lightning flash itself never lasts more than 1/100000 of a second." It is, however, just as likely that a discharge may travel upward as downward. What controls the discharge? Does the quality of the charge?—that is to say, is the positive or the negative more prone to break disruptively through the insulating medium? Investigations with Geissler's and other tubes containing highly rarefied gases have made it tolerably clear that there is a greater "tearing away" influence at the negative than at the positive pole, and if two equal balls, containing one a positive and the other a negative charge, be equally heated, the negative is more readily dissipated than the positive. But, so far as we at present know, this question enters into the discussion scarcely, if at all. Our knowledge seems rather to point to the substances upon which the charges are collected. The self-repellent nature of electricity compels it to manifest itself at the more prominent parts of the surface, the level being forsaken for the point. The tension of the charge, or its tendency to fly off, is proportionately increased. And if at a given moment the tension attains a certain intensity, the discharge follows, emanating from the surface which offers the greatest facilities for escape. The earth is generally flatter than the cloud, whence, in all probability, the discharge more frequently originates with the cloud.
Should a lightning flash strike the earth and produce direct neutrality, it is possible that no damage will result, although this again is not always certain, because when the cloud charge acts inductively on the earth it produces the opposite (say negative) charge on the nearer parts, the similar (or positive) state is also produced at some place more or less distant. Sometimes this "freed" positive (which, by the way, accumulates gradually and physiologically imperceptibly) is collected at some portion of the earth's surface. When the negative is neutralized by the discharge, the freed positive is no longer confined to a particular region, but tends to dissipate itself, and a shock may be felt more or less severely by any person within the region. Or, again, a similar shock may be experienced by a person standing within the negative zone on the neutralization of the charge.
I may take the opportunity here to mention a highly interesting and instructive incident observed on local telegraph circuits during a thunderstorm. The storm may be taking place at some distance from the point of observation. The electrified cloud induces the opposite charge beneath it, the similar charge being repelled. It is noticeable that the needle of a galvanometer, starting from the middle position, goes gradually over to one side, eventually indicating a considerable deflection. Suddenly, owing apparently to a lightning discharge some distance away, the force which caused the deflection is withdrawn, and the needle rebounds with great violence to the opposite side. In a short time, the cloud becoming again charged on its under surface, and recommencing its inductive effect upon the adjacent earth, the needle starts again, and goes through the same series of movements, a violent counterthrow following every flash of lightning.
If we can so far control our imagination, we may conceive the earth to be one large insulated conductor, susceptible to every influence around it. If then the earth, as a mass of matter, behaves as above indicated, there is no plausible reason for declining to regard any other large conducting mass in a similar light, and as a body capable of being subjected more or less completely to the various impulses affecting the earth. In other words, a large mass of conducting material, partially or perfectly insulated, is, during a thunderstorm, in considerable danger. With this portion of the subject I shall, however, deal more fully when discussing the merits of lightning protectors.
Lightning discharges do not take place between cloud and earth only, but also, and perhaps more frequently, between too oppositely charged clouds. We then get atmospheric lightning, the flash often extending for miles. This form of lightning is harmless, and in all probability what we see is only a reflection of the discharge. The oft-told tale of the lightning flying in at the window, across the room, and out of the door, or up the chimney, is all moonshine, and before dealing with lightning protectors I intend to expose some of the fallacies concerning lightning. Were the discharge to pass through a house, it would infallibly leave more decided traces and do more damage than simply scaring a superstitious old lady now and again. Many people are often and unnecessarily frightened during a thunderstorm, but it may be safely predicted that a person under a roof is infinitely safer than one who is standing alone on level ground, and making himself a prominence inviting a discharge. Rain almost invariably accompanies the discharge, and the roof and sides of the house being wet, they form a more or less perfect channel of escape should a flash strike the building.—Knowledge.
We may speak of two electricities or two electric states without necessarily implying adherence either to the single or the double "fluid" theory. Whether electricity be of two kinds or no, the fact remains that there are two conditions, and all the features of this paper may be explained with equal facility by the supporters of either hypothesis.
RESEARCHES ON MAGNETISM.
By M. DUTER.
If we place a thin plate of steel in a uniform magnetic field, so that the lines of force of the field may be normal to the surface of the plate, we have a very flat magnet, the two faces of which are the two polar surfaces. The magnetic distribution thus obtained seems to disappear when the plate is no longer in the field. The following experiments show that this disappearance is not complete. I made use of plates of tempered steel of 1 millimeter in thickness, and varying in diameter from 0.040 to 0.005 meter. With these plates I formed cylindrical batteries. In some of these batteries the plates are directly in contact, and in others they were separated by leaves of pasteboard, the thickness of which varied from that of the thinnest paper to 0.001 meter. The batteries were placed in the central portion of a very powerful magnetic field, and after they have been taken out they formed perfectly regular permanent magnets. The supporting power of these magnets was the greater the nearer its constituent plates were to each other. In a battery of 100 plates, touching each other directly, and strongly pressed into a brass cylinder, the portative force at each extremity rose to 30 grammes. This first result having been obtained, I dismounted the batteries, plate by plate, taking care to mark the upper and under side of each. I found then that each plate retained only an excessively slight magnetism. Yet each of them still constituted a flat magnet, of which the two faces are the polar surfaces; for on rebuilding the battery it gave again a perfectly regular magnet, though weaker than it was at first. The separation of the magnet into its constituent plates, and its reconstruction, maybe repeated indefinitely.—Comptes Rendus.
Dr. T. Tommasi (Cosmos les Mondes) notes that the thermic constant of thallium is exactly the mean of the thermic constants of potassium and lead, the two metals which it most resembles in its chemical character.
IMPROVED GAS LIGHT BUOY.
GAS LIGHT BUOY.
The accompanying engravings represent a light buoy made by the Pintsch's Patent Lighting Company for the river Humber. The chief dimensions of the buoy are given in the engraving, which also shows that the gas holder is placed within the boat in such a way as to be protected from blows likely to cause any leakage. The buoy has a special form to meet its requirements as a lightship, and the conditions of its employment is the fast tidal current of the river. It was designed by Mr. C. Berthon, of Westminster, and is intended to carry a six months' supply of gas, the burner, regulator, and lamp being on the well known Pintsch system. The hull is formed of ⅜ inch plate, 24 feet 3 inches total length, and 9 feet beam at the line of flotation. The laps of the plates are 4 inches wide, and riveted with ¾ inch rivets, spaced 2¼ inch apart center to center. The keel and stem are both in one piece, as shown, and to this the garboard strake is to be fastened. The bilge pieces are riveted on to the bilge, and made of 9 inches by 4½ inches by 9/16 inch T-iron. A wooden fender, 4 inches by 4 inches wood, is fitted on both sides of hull, running from stern to stern, by 3 inches by 3½ inches by 7/16 inch L-iron top and bottom with the sheer as shown. The hull from water line falls in as shown, so as to describe at midships an arc of 4 feet 6 inches, and a circular deck of ⅛ inch plate is riveted on the hull. There are two man-holes, each 16 inches diameter in the clear, placed in end plates of the circular deck as shown, and provided with covers ⅜ inch thick, secured by twenty screws ¾ inch diameter. The edge of each manhole is stiffened by a welded iron ring. The surface of the mooring link that comes in contact with the shackle and mooring chain is steeled. The gas holder rests upon a plate bent up on each side, and riveted to the keelson, and is prevented from rolling by four gusset plates, with two short pieces of angle iron riveted thereto at the ends and coming in contact with the holder, and at the ends by angular plates, and angle iron riveted on each side and riveted to the keelson. The superstructure consists of four legs of angle iron 2½ inches by 2½ inches by 5/16 inch, the upper ends of the legs being attached to a square flanged plate for supporting the lighting apparatus. Four wooden battens of pitch pine, 4 inches by 1½ inches, and bolted on to each cant of the angle iron superstructure, with ⅞ inch galvanized iron bolts and nuts.
GAS LIGHT BUOY.
PROJECT FOR A ROADSTEAD AT HAVRE.
The present port of Havre is absolutely insufficient to answer the ever increasing requirements of commerce. Its entrance, which is too narrow and not deep enough, does not permit steamers to go in, come out, and perform their evolutions with the rapidity required by our epoch. So they are gradually abandoning our port, and going to load and unload at Anvers and elsewhere. A large number of wise heads, who are anxious about the future of this port and our national interests, have devoted themselves to finding a means of enlarging it, not by dredging new basins, which would prove ruinous to the budget and useless in twenty years, but by installing a true roadstead at the entrance to the present basins.
FIG 1.—PLAN OF THE PROJECTED ROADSTEAD AT HAVRE.
Upon the maps of the hydrographic service may be seen, under the name of the Little Roadstead, a vast extent of sea nearly two kilometers wide by three to four in length, bounded upon one side by the heights of Heve and St. Adresse, and upon the other by the rocky line of Eclat and of the heights of the roadstead (Fig. 1). This Little Roadstead, so called, in order to become a genuine one, would have to be protected against the great waves of the open sea. To thus protect it, to close it as quickly and as cheaply as possible—that is the problem.
In 1838, Charles de Massas presented a project (the first in order of date), which consisted in constructing upon the Eclat reef a semi-lunate dike, and a breakwater at Cape Heve. Moreover, upon the emergent parts of the Eclat reef and heights of the roadstead he proposed to erect two forts.
FIG. 2.—LEWIS' FLOATING BREAKWATER.
The defense of the port of Havre is a very important question, and one that appears to be completely abandoned. Since Engineer Degaulle in 1808 advised the erection of a fort upon the Eclat, and requests have periodically been made and projects drawn. The requests are forgotten, but the drawings are in the Ministers' portfolios, and if France should to-morrow have a war with a maritime power our great northern port might be destroyed and burned by the smallest squadron.
Some years after Massas' project, two officers, Deloffre and Bleve, and an engineer named Renaud, received a commission to search for a means of closing a portion of Seine Bay. These gentlemen advised the erection of two dikes, one on the Eclat shoal in the very axis of this reef, and the other at Heve. Between these two masonry dikes was to be placed a floating breakwater. This project, which was submitted to Admiral de Hell in 1845, had a favorable reception, and the Admiral especially applauded the trial of breakwaters, "which were much talked of in England, although the effects that they might produce were not well known." Deloffre, Bleve, and Renauds' project comprised two forts—one to the north and the other to the south of the roadstead. For a long time nothing more was said about it, and it is only during recent years, when the peril has become imminent for Havre (threatened as it is of being abandoned even by the French transatlantics), that the question has again became the order of the day.
FIG. 3.—FROIDEVILLE'S FLOATING BREAKWATER.—END VIEW.
Mr. Bert, a merchant, would protect the Little Roadstead by means of two jetties, 1,000 and 1,600 meters in length, built, one of them upon the Eclat and the other upon the eminences of the roadstead. These would be constructed by forming a foundation of loose rocks, and using earth and brick above the level of the water. Mr. Vial has likewise proposed a rockwork of 2,000 meters in length, to form a dike 10 meters in height and width, whose platform would be on a level with the highest tides.
Next comes the more recent project of Mr. Coulon. Seeing that it is the deposits of the ocean and not those of the Seine that accumulate upon the estuary, Mr. Coulon advises the construction of a dike about 2,000 meters in length, starting from the Havre jetty, and ending at the southwest extremity of the shoals at the roadstead heights, and a second one returning toward the northwest, of from 500 to 1,000 meters. A third and very long one of not less than 8 kilometers would be built from Honfleur to the Ratier shoals.
This latter one, in contracting the bay, would contribute to increase the force of the current, which, throwing back at the ocean its mud and pebbles, would give us the depths of 15 and 20 meters indicated on the map of Beautemps-Beaupre.
This year, again, two projects have arisen; one of them due to Mr. Thuillard-Froideville, and the other to Mr. Hersent.
According to Mr. Hersent, it would be necessary to surround the Little Roadstead with an insubmersible dike built upon the rocky shoals, which would begin at Cape Heve (which it would consolidate) and end opposite the entrance to the port at 1,600 meters from the jetties. Through it there would be five passages. Afterward another dike would be constructed, starting from the shore and running to meet the jetty designed to inclose the Little Roadstead. On turning the angle at which it met the jetty it would be continued as far as to Berville. Finally, a third dike, running from Honfleur to Berville, would complete the system.
Mr. Hersent's project, which is one of the most remarkable of those that have been proposed, has one fault, and that is that it would require twelve years of work, and cost 158 million francs.
Mr. Thuillard-Froideville, completely renouncing masonry dikes as being too costly and taking too long to construct, proposes to inclose the Havre roadstead by means of floating breakwaters. As we have already seen, the use of these between Cape Heve and the Eclat shoals had already been proposed in 1845. As the project was abandoned, the models of these breakwaters are rare.
In Bouniceau's "Marine Constructions" we find a curious figure, a sort of open framework of clumsy form anchored in a singular manner, and surmounted by rooms for watchmen, semaphores, posts for the shipwrecked, etc. It is, indeed, the most complicated and most impracticable type that could be imagined.
Mr. Lewis' model, which was exhibited last year at the International Fisheries Exhibition, was, on the contrary, one of the simplest. It consisted of a strong piece of wood of nearly triangular section, the sharpest angle of which, being turned oceanward, was designed to cut the waves and cause them to break over it (Fig. 2). If, by favor of divine Providence, this breakwater, which presents absolutely plane surfaces to the shock and pressure of the waves, is not broken to fragments in the first tempest, it will certainly acquit itself of the role for which the inventor destined it. When we have a system of resistance to the sea, anchored and facing a certain direction, and consequently not being able to revolve around its axis as vessels do, care must be taken not to give it entire surfaces.
FIG. 4.—FROIDEVILLE'S BREAKWATER.—MODE OF JOINING THE PARTS.
Mr. Froideville's breakwater consists of a framework 25 meters in length, and 9 in height and width, and having the form of an irregular 5-sided prism (Fig. 3). The smallest side of the prism is designed to serve as a flat keel. The axis is formed of a metallic float, from whence start radii that form the skeleton of the framework, and that are designed for connecting the center with five long spruce beams that form the angles of the prism. To these beams are affixed the cross pieces that form the openwork sides. Five long pieces of wood parallel with the beams, but not so strong as they, protect the cross pieces and secure them against breakage in the middle. All the angles of the breakwater and all points of juncture of the pieces are protected with iron, and it is in order to counterbalance the weight of all this iron that the central float is used. Parallel with this first breakwater, there are two other and smaller ones, which are designed for reducing the effect of rolling as much as possible. Reduced to a single float, the breakwater might remain under the waves too long, but, owing to the two others, it rights itself, warps around, and always presents the spur of its sharp roof to the wave.
In order to prevent the breakwaters from clashing against each other, they are united end to end in a very simple and ingenious manner. From each of them there starts a deeply inserted iron bar which terminates in a journal that permits the breakwater to oscillate. Between these two bars there is a sort of swivel, whose pieces, in playing upon one another, give the breakwaters elasticity, while always holding them apart (Fig. 4). From each side of the swivel start the branches of a stirrup iron to which the anchorage chain is attached. This latter is of steel, without solderings, and it is so perfectly constructed that no breakage need be feared. To the other extremity of the chain is attached an anchor having two flukes, which both engage with the bottom.
Mr. Froideville proposes to set up two lines of these breakwaters, for a length of about 7½ kilometers, starting at the north from Cape Heve, taking in depths of 15 meters (the best that are found in the Little Roadstead), passing in front of the Eclat shoal and the heights, and ending opposite the entrance of the present port.
The first row is designed for breaking the force of the waves, and the second for lending its aid in times of high tempests, and stopping the surge that has escaped from the first.
The extreme simplicity of this project has permitted its promoter to affirm that in a few months, and with nine millions, he can inclose the Havre roadstead.
The Little Roadstead, being thenceforward protected, will become an excellent port of refuge in bad weather. In addition, a system of lighters, or, better, a few floats connected with the shore and forming a rock, will permit vessels to take on their cargoes with great rapidity.
Mr. Froideville's project presents the further advantage of rendering it easier to put the port of Havre quickly in defense. A certain number of floating batteries, anchored behind the breakwaters and protecting the advances of torpedo boats by means of their firing, would make a formidable defense. Not having to perform any evolutions, they might without danger be invested with armor plate thicker than that of ordinary ironclads. In order to complete the system, there might be erected upon the Eclat shoal an ironclad fort like that which defends the entrance of Portsmouth.
An English chronicler of the fourteenth century, in speaking of his country, places it above all others, and declares that men are handsomer, whiter, and purer blooded there than elsewhere, and he says that this is so "because it is so." We would not like to imitate his naive reasoning, and yet, for defending the very original system proposed by Mr. Froideville, we have only our conviction, which we share, moreover, with a large number of sea-faring men and engineers. Mathematics are powerless to predict to us with accuracy the manner in which the floating breakwaters will behave, but experiment remains. Let the promoter of the project, then, be given authority to inclose a few hundred meters, and if, as we suppose, the breakwaters shall remain immovable in a northwester, a maritime revolution will have been brought about.—La Nature.
IMPROVED CATCH BASIN.
In 1882, M. Bacle published in Le Génie Civil a study of the sewer systems in some of the large foreign cities. There may be found there a description of the Liernur system at Amsterdam, Leyden, and Dordrecht, in Holland, and in certain cities of Germany and the United States.
IMPROVED CATCH BASIN.
This system consists in the employment of two distinct systems of ducts, one for the discharges from water-closets and the other for household wastes, rain water, and the discharges from factories when sufficiently purified. This arrangement allows the employment of sewers of small section, provided that it shall be unnecessary to enter them for the purpose of cleansing them. It has been necessary, therefore, to provide inlets with a separating apparatus called "gully" or "catch basin," which retains as completely as possible all solid matter, mud, excrement, and debris of every kind which maybe floated in by street washing or by rain-water, and which may be capable of causing stoppages in the sewers, the choking up being followed by fermentation and the emanation of noxious vapors.
M.C. Pieper of Berlin suggests a device for a catch basin, which appears to meet the requirements. It is in the form of a cylindrical metal box, enlarged in its upper section to receive a filtering cylinder of perforated sheet iron, which occupies almost the upper half of the device and rests upon the smaller lower part. The entire apparatus is covered by a movable funnel, through which enter water and any rubbish which it may carry with it. From one side a tube allows the liquid to be discharged, while a siphon placed on the opposite side serves the same purpose under certain circumstances, as will be explained.
Figure 1 represents the apparatus discharging under normal conditions. The heavy matter, sand, stones, etc., falls to the bottom into a receptacle which can be lifted out from time to time and emptied. The lighter buoyant matters, straw, vegetable debris, paper, etc., remain at the surface, and are retained by the filter; the water passing through the holes in the sheet iron rushes in a filtered condition through the annular space which exists in the upper part between the two cylinders, and escapes by the waste-pipe when the water reaches a proper level. If at a given moment the quantity of water flowing in is too much to be discharged through this waste-pipe, the level of the water mounts in the cylinder until it reaches the top of the siphon. Immediately the siphon comes into play and empties the upper part of the apparatus, and the filtered water contained in the annular space already mentioned quickly re-enters the cylinder through the perforated sheet iron, and in so doing cleans out the perforations with considerable energy. This second period is represented in the second figure.
The mouth of the siphon being placed above the movable basket, the heavy matters contained in the latter are not in the least disturbed, and the metallic screen placed over the mouth prevents the entrance of any floating matters. When siphonic action ceases, the water in the short arm of the siphon empties itself into the main receptacle, and by so doing cleanses the screen. During a rain or the washing of the streets, the siphon can work in concurrence with the ordinary discharge-pipe. It is evident of course that these two—pipes can be placed on the same side of the apparatus, if this prove the most convenient arrangement.
We will add that this apparatus can be applied not only to the Liernur system, but also can be used for preventing the entrance of obstructions into sewers of the ordinary type, where the grade is small or where the quantity of water is insufficient; and if we adopt the system of "everything to the sewer," can we not find in the employment of this apparatus an element for the realization of the famous formula, "Always in circulation, and never in stagnation?"—Le Génie Civil.
[Concluded from SUPPLEMENT No. 454, page 7249.]
WATER-POWER WITH HIGH PRESSURES AND WROUGHT-IRON WATER-PIPE.
By HAMILTON SMITH, JR., M. Am. Soc. C.E.
METHODS OF CONDUCTING WATER AND TRANSMITTING POWER.
A description of the mode of using water-power for driving the North Bloomfield tunnel in California, some years since, will give a good illustration of some of the advantages of the hurdy-gurdy. This tunnel was originally about 8,000 feet long, through a slate highly metamorphosed, with its general line passing under a good-sized stream, at a depth of about 190 feet. There were eight working-shafts, each about 200 feet deep, which, with the lower entrance or portal, gave sixteen working faces. Diamond drills were used at the lower heading requiring power; the other fifteen headings were driven by hand-work. It was uncertain how much water would be encountered; but from the location, it was evident that a large quantity might be struck in any shaft, and hence it became necessary to have ample power at hand at each opening, in readiness for such an emergency. A pipe main was laid along the general line of the tunnel, with its pen-stock 285 feet vertical above the surface at the upper shaft, and 549 feet above the lowest shaft. It was made of single riveted sheet-iron, of No. 14 (Birmingham) gauge, in lengths of 20 feet, put together stove-pipe fashion, with the joints made tight by cloth tarred strips and pine wedges. This pipe had a diameter of 15 inches at the pen-stock, diminishing from this to 13, 11, and 7 inches at its lower end. From it, short branches, 7 inches in diameter, were extended to the several shafts. It was in one place carried across the stream by a light suspension bridge, some 150 feet long, the trunk of a tree on each side forming a convenient tower. The aggregate length of the main and branches was 9,960 feet, with some 2,500 feet additional, for the branch to the diamond drills. The pipe was laid on the surface of the ground, its only protection being in places a couple of 1½-inch planks tacked together, and placed over it; the range of temperature was from 10 degrees to 107 degrees Fahr. (in the shade). It was inspected by the foreman of the tunnel-work as he daily walked over the line; besides the occasional driving of a few wedges and putting on a band or two, it gave no trouble from leakage, which probably for its entire length did not amount to more than an average of 3 or 4 cubic feet a minute; from time to time, a little sawdust was put into the pen-stock. Three stop-gates were placed on the main, and a separate stop-gate at each shaft, operated by a fine-threaded screw, so that the water could be cut off when desired.
FIG. 13.
Fig. 13 shows the arrangement of the machinery for hoisting and pumping, which was identical at the several shafts, except that the hurdy-gurdies varied from 16½ feet in diameter at the upper shaft to 21 feet at the lowest shaft. The water-wheel moved only in one direction; the pinion on the wheel-shaft drove the spur-wheel, to which the pitman of the pump-bob was attached. On the spur-wheel shaft was a friction-gear, driving the hoisting-reel; this reel was mounted on sliding blocks, so that hoisting was done by putting it in gear, the empty load being dropped by a friction-band. Changing the size of the water-wheel as the pressure increased permitted the use of the same pattern of machinery at the different shafts. The water was brought to the wheel by a discharge-pipe, some nine feet long, having a vertical movement by ball-and-socket joint, so that at pleasure, by dropping the pipe, the machinery could be run at various speeds, or entirely stopped. At the end of this discharge-pipe was a cast tapered nozzle, about 3½ inches in diameter, in which was inserted a ring of saw-plate steel having the desired diameter, and which was held in place by an annular screw-cap. By changing the ring, which only required a few moments' time, any desired amount of water, up to 3 or 4 cubic feet a second, could be discharged against the wheel. The stop-gate was left wide open while the machinery was running. The pumping was done by eighteen pumps, of Cornish pattern; the largest amount of water pumped from any one shaft was something over 30 cubic feet a minute; the power at hand, however, was ample to pump more than twice that quantity. It was rather curious at, this shaft to see more water coming from the pumps than was used on the wheel. The two diamond drills were driven by a small hurdy-gurdy set on the rear of the drill carriage. This, but at another tunnel, was afterward modified by placing a separate hurdy-gurdy on a sleeve on each drill-rod; the advance movement of the drill being given by hydrostatic pressure on an annular piston, thus doing away with all gearing. These eight sets of machinery were run for nearly 2½ years' time; the only break being that of a spur-wheel, doubtless caused by the careless dropping of a steel bar between it and its pinion. Aside from this accident, practically not a dollar was spent for repairs, and the machinery, including the pipe, was in about as good order when the tunnel was finished as when it was first erected. One man, on a twelve hour shift, operated the machinery at each shaft, besides dumping the cars; two men kept the 18 pumps on the line in order, the principal work being in keeping the suction-pipes for the down-grade headings tight; thus a force of 18 men was only required for the eight shafts. The cost of the pipe, gates, etc., when put in place, was $14,631, and of the machinery about $60,000.
FIG. 14.
At the Idaho gold quartz mine, situated near Grass Valley, California, water-power has been introduced during the past year (1883), taking the place of steam. The supply main is of wrought-iron, 22 inches in diameter, 8,764 feet long, buried in the ground below frost-line. The joints, as a rule, are riveted together, with occasional lead joints to admit of slight movements in the pipe.[[4]] The pipe was coated by placing each joint in a bath of boiling tar and asphaltum; to insure the most thorough coating, it is necessary to keep the pipe for ten or fifteen minutes in the boiling mixture. A cast-iron stop-gate is placed at the lower end of the main, and also one at each of the branches. Cast-iron man-holes are attached to the main, which, although they have given no trouble in this particular case, are very objectionable for high pressures, as it is difficult to avoid ruptures with cast and wrought-iron combined, owing to the great difference in the elasticity of the two metals. The long seams of this pipe are double-riveted, and the round seams single riveted; at the lower end, iron of No. 6 gauge is used. From the end of the main, the water is led to the several wheels by branches of smaller diameter.
The water is delivered at the hoisting-wheel with a total head of 542.6 feet. For power and for mill uses, etc., the required supply is about 8 cubic feet a second; this draught reduces the effective head to say 523 feet.
The work done consists in driving the following described machinery:
A large air-compressor—2 cylinders, double acting, air compressed to 75 pounds—requiring about 140 horse-power.
A line of Cornish pumps, forcing the water from a depth of 1,450 feet vertical; 12-inch plungers for upper 800 feet, 6-inch plungers for lower 650 feet, with 6-foot stroke, requiring from 55 to 70 horse-power.
Hoisting from a double-compartment shaft—two connected winding reels, moving separate cages—requiring 35 horse-power, or more.
A few small machine-tools and smithy forges, requiring 3 or 4 horse-power.
A 35-stamp mill, with concentrating apparatus, etc., requiring about 70 horse-power.
The total amount of power required being say 320 horse-power, for which seven Pelton hurdy-gurdy wheels are employed.
The power in all cases is transmitted by systems of Manila rope belting; the rope is 2 inches in diameter; the grooves in the sheaves or pulleys are slightly oval, so that the rope does not go quite to the bottom; the ropes are horizontal, and run very slack (no tighteners), with no appreciable slip; the splices are made very long, to obtain uniformity in diameter.