Common Minerals and Rocks

Boston Society of Natural History

GUIDES FOR SCIENCE-TEACHING

No. XII

Common Minerals and Rocks

By WILLIAM O. CROSBY

D. C. HEATH & CO., PUBLISHERS

BOSTON NEW YORK CHICAGO

Copyright

By the Boston Society of Natural History

1881

I D 2

INTRODUCTION.

Minerals and rocks, or the inorganic portions of the earth, constitute the proper field or subject-matter of the science of Geology. Now the inorganic earth, like an animal or plant, may be and is studied in three quite distinct ways, giving rise to three great divisions of geology, which, as will be seen, correspond closely to the main divisions of Biology.

First, we may study the forces now operating upon and in the earth—the geological agencies—such as the ocean and atmosphere, rivers, rain and frosts, earthquakes, volcanoes, hot springs, etc., and observe the various effects which they produce. We are concerned here with the dynamics of the earth; and this is the great division of dynamical geology, corresponding to physiology among the biological sciences.

Or, second, instead of geological causes, we may study more particularly geological effects, observing the different kinds of rocks and of rock-structure produced by the geological agencies, not only at the present time, but also during past ages. This method of study gives us the important division of structural geology, corresponding to anatomy and morphology.

All phenomena present two distinct and opposite aspects or phases which we call cause and effect; and so in dynamical and structural geology we are really studying the opposite sides of essentially the same classes of phenomena. In the first division we study the causes now in operation and observe their effects; and then, guided by the light of the experience thus gained, we turn to the effects produced in the past and seek to refer them to their causes.

These two divisions together constitute what is properly known as physiography; and they are both subordinate to the third great division of geology,—historical geology,—which corresponds to embryology.

The great object of the geologist is, by studying the geological formations in regular order, from the oldest up to the newest, to work out, in their proper sequence, the events which constitute the earth’s history; and dynamical and structural geology are merely introductory chapters, the alphabet, as it were, which must be learned before we are prepared to read understandingly the grand story of the geological record.

Our work in this short course will be limited to the first two divisions,—i.e., to dynamical and structural geology. We will attempt, first, a general sketch of the forces now concerned in the formation of rocks and rock-structures; and after that we will study the composition and other characteristics of the common minerals and rocks.

The scope of this work, and its relations to the whole field of geology, are more clearly indicated by the following classification of the geological sciences:—

Many teachers will desire to fill in some of the details of the outline sketch presented in this Guide, and for this purpose the following works are especially recommended:—

Elements of Geology. By Prof. Joseph Le Conte. 1882. D. Appleton & Co., New York. Nearly 600 pages.

Manual of Geology. By Prof. J. D. Dana. Third edition. 1880. 800 pages.

Text-Book of Geology. By Prof. A. Geikie. 1882. Macmillan & Co., London. Nearly 1000 pages.

As a reference-book for mineralogy, the following treatise is unsurpassed:—

Text-Book of Mineralogy. By Edward S. Dana. 1883. John Wiley & Sons, New York.

And, as an introduction to the study of minerals, and, through these, to the study of rocks,—

First Lessons in Minerals. Science Guide No. XIII. By Mrs. E. H. Richards.

cannot be too highly recommended. Teachers will find this little primer of 46 pages invaluable with young children, and with all who have had no previous training in chemistry.

As an admirable continuation of the work begun in these pages, teachers are referred to Professor Shaler’s “First Book in Geology.” In this our brief sketch of the geological agencies is amplified and beautifully illustrated; and rarely have the wonderful stories of the river, ocean-beach, glacier, and volcano been told so effectively. In the chapter on the history of life on the globe the main outlines of historical geology are skillfully brought within the comprehension of beginners. The directions to teachers are fully in accord with the modern methods and ideas, and are a very valuable feature of the book.

DYNAMICAL GEOLOGY.

When we think of the ocean with its waves, tides, and currents, of the winds, and of the rain and snow, and the vast net-work of rivers to which they give rise, we realize that the energy or force manifested upon the earth’s surface resides chiefly in the air and water—in the earth’s fluid envelope and not in its solid crust. And it would be an easy matter to show that, with the exception of the tidal waves and currents, which of course are due chiefly to the attraction of the moon, nearly all this energy is merely the transformed heat of the sun. Now the air and water are two great geological agencies, and therefore the geological effects which they produce are traceable back to the sun.

Organic matter is another important geological agent; but all are familiar with the generalization that connects the energy exhibited by every form of life with the sun; and, besides, it is scarcely necessary to allude to the obvious fact that all animals and plants, so far at least as any display of energy is concerned, are merely differentiated portions of the earth’s fluid envelope. And so, if space permitted, it might be shown that, with the exception of the tides, nearly every form of force manifested upon the earth’s surface has its origin in the sun.

Of this trio of geological agencies operating upon the earth’s surface and vitalized by the sun—water, air, and organic matter—the water is by far the most important, and so it is common to call these collectively the aqueous agencies. Hence we have solar agencies and aqueous agencies as synonymous terms.

The aqueous agencies include, on one side, air and water, or inorganic agencies; and, on the other, animals and plants, or organic agencies.

Let us notice briefly the operation of these, beginning with the air and water.

I. AQUEOUS AGENCIES.

1. Air and Water, or Inorganic Agencies.

Chemical Erosion.—Attention is invited first to the specimens numbered 1, 2, 3, and 4. No. 1 is a sound, fresh piece of the rather common rock, diabase; and those who are acquainted with minerals will recognize that the light-colored grains in the rock are feldspar, and the dark, augite. This specimen came from a depth in the quarry, and has not been exposed to the action of the weather.

The second specimen differs from the first, apparently, as much as possible; and yet, except in being somewhat finer grained, it was originally of precisely similar composition and appearance. In fact, it is a portion of the same rock, but a weathered portion. In this we can no longer recognize the feldspar and augite as such, but both these minerals are very much changed, while in the place of a strong, hard rock we have an incoherent friable mass, which is, externally at least, easily crushed to powder; and with the next step in the weathering, as we may readily observe in the natural ledges, the rock is completely disintegrated, forming a loose earth or soil.

We have two examples of such natural powders in the specimens numbered 3 and 4; and by washing these (especially the finer one, No. 4) with water, we can prove that they consist of an impalpable substance which we may call clay, and angular grains which we may call sand. The sand-grains are really portions of the feldspar not yet entirely changed to clay.

Thus we learn that the result of the exposure of this hard rock to the weather is that it is reduced to the condition of sand and clay. What we mean especially by the weather are moisture and certain constituents of the air, particularly carbon dioxide.

The action of the weather on the rocks is almost entirely chemical. With a very few exceptions, the principal minerals of which rocks are composed, such as feldspar, hornblende, augite, and mica, are silicates, i.e., consist of silicic acid or silica combined with various bases, especially aluminum, magnesium, iron, calcium, potassium, and sodium.

Now the silica does not hold all these bases with equal strength; but carbon dioxide, in the presence of moisture, is able to take the sodium, potassium, calcium, and magnesium away from the silica in the form of carbonates, which, being soluble, are carried away by the rain-water.

The silicate of aluminum, with more or less iron, takes on water at the same time, and remains behind as a soft, impalpable powder, which is common clay.

In the case of our diabase, continued exposure to the weather would reduce the whole mass to clay. But other rocks contain grains of quartz, a hard mineral which cannot be decomposed, and it always forms sand. Certain classes of rocks, too, such as the limestones and some iron-ores, are completely dissolved by water holding carbon dioxide in solution, and nothing is left to form soil, except usually a small proportion of insoluble impurities like sand or clay.

Let us see next how these agents of decay get at the rocks. Neither water nor air can penetrate the solid rock or mineral to any considerable extent, so that practically the action is limited to surfaces, and whatever multiplies surfaces must favor decomposition.

First, we have the upper surface of the rock where it is bare, but more especially where it is covered with soil, for there it is always wet.

All rocks are naturally divided by joints into blocks, which are frequently more or less regular, and often of quite small size. Water and air penetrate into these cracks and decompose the surfaces of the blocks, and thus the field of their operations is enormously extended. These rock-blocks sometimes show very beautifully the progress of the decomposing agents from the outside inward by concentric layers or shells of rotten material, which, in the larger blocks, often envelop a nucleus of the unaltered rock.

It is interesting to observe, too, that these concentric lines of decay cut off the angles of the original blocks, so that the undecomposed nucleus, when it is found, is approximately spherical instead of cuboidal. Both these points are well illustrated by specimen No. 2; for although now nearly spherical, it was originally perfectly angular, and has become rounded by the peeling off, in concentric layers, of the decomposed material, and in most cases several of these layers are distinctly visible, like the coats of an onion. But by stripping these off we should discover, in all the larger balls at least, a solid, spheroidal nucleus, while in the smaller balls the decomposition has penetrated to the centre.

In the rocks also we find many imperfect joints and minute cracks. In cold countries these are extended and widened by the expansive power of freezing water, and thus the surfaces of decomposition become constantly greater.

Nearly all rocks suffer this chemical decomposition when exposed to the weather, but in some the decay goes on much faster than in others. Diabase is one of the rocks which decay most readily; while granite is, among common rocks, one of those that resist decay most effectually.

The caverns which are so large and numerous in most limestone countries are a splendid example of the solvent action of meteoric waters, being formed entirely by the dissolving out of the limestone by the water circulating through the joint cracks. The process must go on with extreme slowness at first, when the joints are narrow, and more rapidly as they are widened and more water is admitted. We get some idea, too, of the magnitude of the results accomplished by these silent and unobtrusive agencies when we reflect that almost all the loose earth and soil covering the solid rocks are simply the insoluble residue which carbon dioxide and water cannot remove. In low latitudes, where a warm climate accelerates the decay of the rocks, the soil is usually from 50 to 300 feet deep.

Mechanical Erosion.—On the edge of the land.—Let us trace next the mechanical action of water and air upon the land. First we will consider the edge of the land, where it is washed by the waves of the sea. Whoever has been on the shore must have noticed that the sand along the water’s edge is kept in constant motion by the ebb and flow of the surf.

Where the beach is composed of gravel or shingle the motion is evident to the ear as well as the eye; and when the surf is strong, the rattling and grinding of the pebbles as they are rolled up and down the beach develops into a roar.

The constant shifting of the grains of sand, pebbles, and stones is, of course, attended by innumerable collisions, which are the cause of the noise. Now it is practically impossible, as we may easily prove by experiment, to knock or rub two pieces of stone together, at least so as to produce much noise, without abrading their surfaces; small particles are detached, and sand and dust are formed.

That this abrasion actually occurs in the case of the moving sand is most beautifully shown by the sandblast. We are to conclude, then, that every time a pebble, large or small, is rolled up or down the beach it becomes smaller, and some sand and dust or clay are formed which are carried off by the water.

But what are the pebbles originally? This question is not difficult. A little observation on the beach shows us that the pebbles are not all equally round and smooth, but many are more or less angular. And we soon see that it is possible to select a series showing all gradations between the most perfectly rounded forms and angular fragments of rock that are only slightly abraded on the corners. The three principal members of such a series are shown in specimens 5, 6, and 7 from the beach on Marblehead Neck; but equally instructive specimens can be obtained at many other points on our coast. It is also observable that the well-rounded pebbles are much smaller on the average than the angular blocks.

From these facts we draw the legitimate inference that the pebbles were all originally angular, and that the same abrasion which diminishes their size makes them round and smooth.

A little reflection, too, shows that the rounding of the angular fragments is a natural and necessary result of their mutual collisions; for the angles are at the same time their weakest and most exposed points, and must wear off faster than the flat or concave surfaces.

Having traced each pebble back to a larger angular rock-fragment, the question arises, Whence come these angular blocks?

Behind our gravel-beach, or at its end, we have usually a cliff of rocks. As we approach this it is distinctly observable that the angular pebbles are more numerous, larger, and more angular; and a little observation shows that these are simply the blocks produced by jointing, and that the cliff is entirely composed of them. In other words, our cliff is a mass of natural masonry, which chemical agencies, the frost, and the sea are gradually disintegrating and removing. As soon as the blocks are brought within reach of the surf their mutual collisions make them rounder and smaller; and small round pebbles, sand, and clay are the final result.

For a more complete account of the formation of pebbles, teachers are referred to the first or introductory number of this series of guides, by Prof. Hyatt, “About Pebbles.”

Where the waves can drive the shingle directly against the base of the cliff, this is gradually ground away in the same manner as the loose stones themselves, sometimes forming a cavern of considerable depth, but always leaving a smooth, hard surface, which is very characteristic, and contrasts strongly with the upper portion of the cliff, which is acted on only by the rain and frost. A good example of such a pebble-carved cliff may be seen behind the beach on the sea-ward side of Marblehead Neck.

The sea acts within very narrow limits vertically, a few feet or a few yards at most; but the coast-lines of the globe (including inland lakes and seas) have an aggregate length of more than 150,000 miles. Hence it is easy to see that the amount of solid rock ground to powder in the mill of the ocean-beach annually must be very considerable.

Mechanical Erosion.—On the surface of the land.—I next ask attention to the mechanical action of water upon the surface of the land.

It is a familiar fact that after heavy rains the roadside rills carry along much sand and clay (which we know have been produced by the previous action of chemical forces), and also frequently small pebbles or gravel. It is easy to show that in all important respects the rill differs in size only from brooks and rivers; and the former afford us fine models of the systems of valleys worn out during the lapse of ages by rivers. The turbidity of rivers is often very evident, and in shallow streams we can sometimes see the pebbles rolled along by the current.

Now here, just as on the beach, the collisions of rock-fragments are attended by mutual abrasion, sand and clay are formed, and the fragments become smaller and rounder. Our series of pebbles from the beach might be matched perfectly among the river-gravel. In mountain streams especially we may often observe that pebbles of a particular kind of rock become more numerous, larger, and more angular as we proceed up stream, until we reach the solid ledge from which they were derived, showing the same gradation as the beach pebbles when followed back to the parent cliff.

The pebbles, however, not only grind each other, but also the solid rocks which form the bed of the streams in many places, and these are gradually worn away. When the rocky bed is uneven and the water is swift, pebbles collect in hollows where eddies are formed, by which they are kept whirling and turning, and the hollow is deepened to a pot-hole, while the pebbles, the river’s tools, are worn out at the same time.

By these observations we learn not only that running water carries away sand and clay already formed, but that it also has great power of grinding down hard rocks to sand and clay. Of course the pulverized rock always moves in the same direction as the stream which carries it; and, in a certain sense, all streams run in one direction, viz., toward the sea. Therefore the constant tendency of the rain falling upon the land is to break up the rocks by chemical and mechanical action and transport the débris to the sea.

Rivers, as we all know, are continually uniting to form larger and larger streams; and thus the drainage of a wide area sometimes, as in the case of the Mississippi Valley, reaches the sea through a single mouth. By careful measurements made at the mouth of the Mississippi it has been shown that the 20,000,000,000,000 cubic feet of water discharged into the Gulf of Mexico annually carries with it no less than 7,500,000,000 cubic feet of sand, clay, and dissolved mineral matter; and this, spread over the whole Mississippi basin, would form a layer a little more than 1/5000 of a foot in thickness. So that we may conclude that the surface of the continent is being cut down on the average about one foot in five thousand years.

We can only allude in passing to the very important geological action of water in the solid state, as in glaciers and icebergs. The moisture precipitated from the atmosphere, and falling as rain, makes ordinary rivers; but falling in the form of snow in cold regions, where more snow falls than is melted, the excess accumulates and is gradually compacted to ice, which, like water, yields to the enormous pressure of its own mass and flows toward lower levels. When the ice-river reaches the sea it breaks off in huge blocks, which float away as icebergs. Moving ice, like moving water, is a powerful agent of erosion; and the glacial marks or scratches observable upon the ledges everywhere in the Northern States and Canada attest the magnitude of the ice-action at a comparatively recent period.

We have already noticed incidentally the powerful disintegrating action of water where it freezes in the joints and pores of the rocks; and it is probable that it thus facilitates the destruction of the rocks in cold countries nearly as much as the higher temperature and greater rain-fall do in warm countries.

Our observations up to this point show us that erosion, by which we mean the breaking up by chemical and mechanical action of the rocks of the land and the transportation of the débris into the sea, is one great result accomplished by the inorganic aqueous agencies.

Mechanical Deposition.—Next let us notice what becomes of all this vast amount of clay, sand, and gravel after it is washed into the ocean. By taking up a glass of turbid water from our roadside rill, and observing that as soon as the water is undisturbed the sand and clay begin to settle, we learn that the solid matter is held in suspension by the motion of the water. But it does not remain in suspension long after being washed into the sea, for otherwise the sea would, in the course of time, become turbid for long distances from shore; and it is a well-known fact that the sea-water is usually clear and free from sensible turbidity close along shore and even near the mouths of large rivers, while at a distance of only 50 or 100 miles we find the transparency of the central ocean.

Putting these facts together, we see that the ocean, nothwithstanding the ceaseless and often violent undulations of its surface, must be as a whole a vast body of still water; and to the reflecting mind the almost perfect tranquillity of the ocean is one of its most impressive features. For it is in striking contrast, in this respect, with the more mobile aerial ocean above it.

We have got hold, now, of two facts of great geological importance: (1) The débris washed off the land by waves and rivers into the still water of the ocean very soon settles to the bottom; and (2) it nearly all settles on that part of the ocean-floor near the land.

And now we have in view the second great office of the inorganic aqueous agencies,—deposition, the counterpart or complement of erosion.

The land is the great theatre of erosion and the sea of deposition; the rocks which are constantly wasting away on the former are as constantly renewed in the latter.

We will now observe the process of deposition a little more closely. Each of these two bottles contains the same amount of fine yellow clay, but in one the water is fresh, and in the other it is salt. At the beginning of the lesson, as you may have observed, I brought the clay in both bottles into suspension by violent agitation, and since then they have remained undisturbed. The main point is that the salt water has become quite clear, while the fresh water is still distinctly turbid, showing that the salt favors the rapid deposition of the clay. At the second lecture, a week later, these two bottles, yet undisturbed, were exhibited, and the fresh water seen to be still sensibly turbid. The fact is, the clay is not held in suspension wholly by the motion of the water; but, just as in the case of dust in the atmosphere, a small portion of the medium is condensed around or adheres to each solid particle, i.e., each clay particle in our experiment has an atmosphere of water which moves with it and buoys it up. Now the effect of the salt is to diminish the adhesion of the water to the particles, i.e., to diminish their atmospheres, and consequently their buoyancy. The diminished adhesion of the salt water is well shown by the smaller drops which it forms on a glass rod.

The geological importance of this principle is very great; for it is undoubtedly largely to the saltness of the sea that we owe its transparency, and the fact that the fine, clayey sediment from the land, like the coarse, is deposited near the shore.

This bottle of fresh water contains some fine gravel, coarse sand, fine sand, and clay. By agitating the water, all this material is brought into suspension. Now, suddenly placing the bottle in a state of rest, we observe that the gravel falls to the bottom almost instantly, followed quickly by the coarse sand, and very soon afterward by the fine sand; and then there appears to be a pause, the fine particles of clay all remain in suspension; but finally, when the water is quite motionless, they begin to settle; they fall very slowly, however, and the water will not be clear for hours.

This is a very instructive experiment. We learn from it:

First, that the power of the water to hold particles in suspension is inversely proportional to the size of the particles;

Second, that all materials deposited in water are assorted according to size;

Third, and this is one of the most important facts in geology, all water-deposited sediments are arranged in horizontal layers, i.e., are stratified. And we have now traced to its conclusion, though very briefly, the process of the formation of one great division of stratified rocks,—the mechanically-formed or fragmental rocks. These are so called because the clay, sand, and gravel are, in every instance, fragments of pre-existing rocks; and because the formation, transportation, and especially the deposition of these fragments, are the work chiefly or entirely of mechanical forces.

Chemical Deposition.—It is a well-known fact that the sea holds in solution vast amounts of common salt as well as many other substances; and analyses of river-waters show that dissolved minerals derived from the chemical decomposition of the rocks of the land are being constantly carried into the sea.

Portions of the sea which are cut off from the main body, and which are gradually drying up, like the Great Salt Lake, Dead Sea, and Caspian Sea, become saturated solutions of the various dissolved minerals, and these are slowly deposited. This process is very nicely illustrated along our shores in summer, where, during storms, salt-water spray is thrown above the reach of the tides, and, collecting in hollows in the rocks, gradually dries up, leaving behind a crust of salt.

When the sea lays down matter which it held in suspension, we call the process mechanical deposition, and the result is mechanically-formed rocks.

But when it lays down matter which it held in solution, we call the process chemical deposition, and the result is chemically-formed rocks.

The principal substances which the sea deposits chemically are common salt, forming beds of rock-salt; sulphate of calcium, forming beds of gypsum; carbonate of calcium, forming beds of limestone; and the double carbonate of calcium and magnesium, forming beds of dolomite.

Inorganic deposition, like inorganic erosion, is both chemical and mechanical.

2. Animals and Plants, or Organic Agencies.

We turn now to the consideration of the organic agencies. And I will merely allude in passing to the vast importance of the fossil organic remains found in the stratified rocks as marks by which to determine the relative ages of the formations.

As regards the destruction of rocks—erosion—plants and animals are almost powerless; but in the role of rock-makers they play a very important part, being very efficient agents of deposition.

Formation of Coals and Bitumens.—Specimen No. 8 is an example of peat from the vicinity of Boston; but just as good specimens may be obtained in thousands of places in this and other States.

The general physical conditions under which peat is formed are familiar facts. We require simply low, level land, covered with a thin sheet of water and abundant vegetation; in other words, a marsh or swamp. If plants decay on the dry land, the decomposition is complete; they are burned up by the oxygen of the air to carbon dioxide and water just as surely as if they had been thrown into a furnace, though less rapidly, and nothing is returned to the soil but what had been taken from it by the plants during their growth. But if the plants decay under water, as in a peat-marsh or bog, the decay is incomplete, and most of the carbon of the wood is left behind. Now, if this incomplete combustion of vegetable tissues takes place in a charcoal-pit, where the wood is out of contact with air from being covered with earth, we call the carbonaceous product charcoal; but if under the water of a marsh, in Nature’s laboratory, we call the product peat. Peat is simply a natural charcoal; and, just as in ordinary charcoal, its vegetable origin is always perfectly evident. But when the deposit becomes thicker, and especially when it is buried under thick formations of other rocks, like sand and clay, the great pressure consolidates the peat; it becomes gradually more mineralized and shining, shows the vegetable tissues less distinctly, becomes more nearly pure carbon, and we call it in succession lignite, bituminous coal, and anthracite.

This is, briefly, the way in which all varieties of coal, as well as the more solid kinds of bitumen, like asphaltum, are formed. But the lighter forms of bitumen, such as petroleum and naphtha, are derived mainly, if not entirely, from the partial decomposition of animal tissues. These, it is well known, decay much more readily than vegetable tissues; and the water of an ordinary marsh or lake contains sufficient oxygen for their complete and rapid decomposition. In the deeper parts of the ocean, however, the conditions are very different, for recent researches have shown, contrary to the old idea, that the deep sea holds an abundant fauna. All grades of animal life, from the highest to the lowest, have need of a constant supply of oxygen. On the land vegetation is constantly returning to the air the oxygen consumed by animals, but in the abysses of the ocean vegetable life is scarce or wanting; and hence it must result that over these greater than continental areas countless myriads of animals are living habitually on short rations of oxygen, and in water well charged with carbon dioxide, the product of animal respiration. As a consequence, when these animals die their tissues do not find the oxygen essential for their perfect decomposition, and in the course of time become buried, in a half-decayed state, in the ever-increasing sediments of the ocean-floor.

It is important to observe that an abundance of organic matter decaying under water is not the only condition essential to the formation of beds of coal and bitumen; for this condition is realized in the luxuriant growth of sea-weeds fringing the coast in every quarter of the globe; and yet coals and bitumens are rarely of sea-shore origin. These organic products, even under the most favorable circumstances, accumulate with extreme slowness; far more slowly, as a rule, than the ordinary mechanical sediments, like sand and clay, with which they are mixed, and in which they are often completely lost. Consequently, although the deposition of the carbonized remains of plants and animals is taking place in nearly all seas, lakes, and marshes, it is only in those places where there is little or no mechanical sediment that they can predominate so as to build up beds pure enough to be called coal or bitumen. In all other cases we get merely more or less carbonaceous sand or clay. Now these especially favorable localities will manifestly not be often found along the seashore, where we have strewn the sand and clay brought down by rivers or washed off the land directly by the ever-active surf; but they must exist in the central portions of the ocean, where there is almost no mechanical sediment and yet an abundance of life, and in swamps and marshes, where there is scarcely sufficient water to cover the vegetation, and no waves or currents to wash down the soil from the surrounding hills.

Formation of Iron-ores.—The iron-ores are another class of rocks which are formed only through the agency of organic matter. Iron is an abundant and wide-spread element in the earth’s crust, and, but for the intervention of life, we might say that, while there is iron everywhere, there is not much of it in any one place, since it is originally very thinly diffused. All rocks and soils contain iron, but it is mainly in the form of the peroxide, in which state it is entirely insoluble, and hence cannot be soaked out of the soil by the rain-water and concentrated by the evaporation of the water at lower levels in ponds and marshes, as a soluble substance like salt would be. If carried off with the sand and clay, by the mechanical action of water, it remains uniformly mixed with them, and there is no tendency to its separation and concentration so as to form a true iron-ore.

But what water cannot do alone is accomplished very readily when the water is aided by decaying organic matter, which is always hungry for oxygen, being, in the language of the chemist, a powerful reducing agent. The soil, in most places, has a superficial stratum of vegetable mould or half-decayed vegetation. The rainwater percolates through this and dissolves more or less of the organic matter, which is thus carried down into the sand and clay beneath and brought in contact with the ferric oxide, from which it takes a certain proportion of oxygen, reducing the ferric to the ferrous oxide. At the same time the vegetation is burned up by the oxygen thus obtained, forming carbon dioxide, which immediately combines with the ferrous oxide, forming carbonate of iron, which, being soluble under these conditions, is carried along by the water as it gradually finds its way by subterranean drainage to the bottom of the valley and emerges in a swamp or marsh.

Here one of two things will happen: If the marsh contains little or no decaying vegetation, then as soon as the ferrous carbonate brought down from the hills is exposed to the air it is decomposed, the carbon dioxide escapes, and the iron, taking on oxygen from the air, returns to its original ferric condition; and being then quite insoluble, it is deposited as a loose, porous, earthy mass, commonly known as bog-iron-ore, which becomes gradually more solid and finally even crystalline through the subsequent action of heat and pressure. When first deposited, the ferric oxide is combined with water or hydrated, and is then known as limonite (specimen No. 12); at a later period the water is expelled, and we call the ore hematite (specimen No. 13); and at a still later age it loses part of its oxygen, becomes magnetic and more crystalline, and is then known as magnetite (specimen No. 14). Thus it is seen that the iron-ores, as we pass from bog-limonite to magnetite, form a natural series similar to and parallel with that afforded by the coals as we pass from peat to graphite.

If the drainage from the hills is into a marsh containing an abundance of decaying vegetation, i.e., if peat is forming there, the ferrous carbonate, in the presence of the more greedy organic matter, will be unable to obtain oxygen from the air; and as the evaporation of the water goes on, it will sooner or later become saturated with this salt, and the latter will be deposited. Here we find an explanation of a fact often observed by geologists, viz., that the carbonate iron-ores are usually associated with beds of coal.

The formation of the iron-ores, like that of the coals and bitumens, is a slow process; and the ores, like the coals, etc., will be pure only where there is a complete absence of mechanical sediment, a condition that is realized most nearly in marshes.

Formation of Limestone, Diatomaceous Earth, etc.—Marine animals take from the sea-water certain mineral substances, especially silica and carbonate of calcium, to form their skeletons. Silica is used only by the lowest organisms, such as Radiolaria, Sponges, and the minute unicellular plants, Diatoms. The principal animals secreting carbonate of calcium are Corals and Mollusks. These hard parts of the organisms remain undissolved after death; and over portions of the ocean-floor where there is but little of other kinds of sediment they form the main part of the deposits, and in the course of ages build up very extensive formations which we call diatomaceous earth or tripolite, if the organisms are siliceous, or limestone if they are calcareous. A very satisfactory account of the formation of limestone on a stupendous scale by the polyps in coral reefs and islands is contained in No. IV. of this series of guides.

The rocks here considered may be, and, as we have already seen, sometimes are, deposited in a purely chemical way, without the aid of life; and it is important to observe that in no case do the organisms make the silica and carbonate of calcium of their skeletons, but they simply appropriate and reduce to the solid state what exists ready made in solution in the sea-water. These minerals, and others, as we know, are produced by the decomposition of the rocks of the land, and are being constantly carried into the sea by rivers; and, if there were no animals in the sea, these processes would still go on until the sea-water became saturated with these substances, when their precipitation as limestone, etc., would necessarily follow. Hence it is clear that all the animals do is to effect the precipitation of certain minerals somewhat sooner than it would otherwise occur; so that from a geological standpoint the differences between chemical and organic deposition are not great.

This section of our subject may be summarized as follows: Animals and plants contribute to the formation of rocks in three distinct ways:—

1. During their growth they deoxidize carbon dioxide and water, and reduce to the solid state in their tissues carbon and the permanent gases oxygen, hydrogen, and nitrogen; and after death, through the accumulation of the half-decayed tissues in favorable localities,—marshes, etc.,—these elements are added to the solid crust of the earth in the form of coal and bitumen.

2. During the decomposition, i.e., oxidation, of the organic tissues, the iron existing everywhere in the soil is partially deoxidized, and, being thus rendered soluble, is removed by rain-water and concentrated in low places, forming beds of iron-ore.

3. Through the agency of marine organisms, certain mineral substances are being constantly removed from the sea-water and deposited upon the ocean floor, forming various calcareous and siliceous rocks.

I now bring our study of the aqueous or superficial agencies to a conclusion by noting once more that the great geological results accomplished by air, water, and organic matter or life are: (1) Erosion, or the wearing away of the surface of the land; and (2) Deposition, or the formation from the débris of the eroded land of two great classes of stratified rocks,—the mechanically formed or fragmental rocks, and the chemically and organically formed rocks.

II. IGNEOUS AGENCIES.

We pass next to a very brief consideration of operations that originate below the earth’s surface. The records of deep mines and artesian wells show that the temperature of the ground always increases downwards from the surface; and the much higher temperatures of hot springs and volcanoes show that the heat continues to increase to a great depth, and is not a merely superficial phenomenon. The observed rate of increase is not uniform, but it seldom varies far from the average, which is about 1° Fahr. per 53 feet of vertical descent, or, in round numbers, 100° per mile. This rate, if continued, would give a very high temperature at points only a few miles below the surface; and until within a few years the idea was generally accepted by geologists that the increase of temperature is sensibly uniform for an indefinite distance downward; that in the central regions of the earth the temperature is far higher than anything we can conceive, and that everywhere below a depth of 20 to 40 miles the temperature is above the fusing-point of all rocks; and hence that the earth is an incandescent liquid globe covered by a thin shell or crust of cold, solid rock.

Our limited space will not permit us to enter into a discussion of the condition of the earth’s interior, and I will merely point out in a few sentences the position occupied by geologists at the present time. The reasoning of Thompson has shown that the temperature cannot increase downward at a uniform rate, but at a constantly and rapidly diminishing rate; and that everywhere below a depth of 300 miles the temperature is probably sensibly the same, and nowhere, probably, above 8000° to 10,000° Fahr.

Unlike water, all rocks contract on solidifying and expand on melting, and consequently the high pressures to which they are subjected in the earth’s interior—10,000,000 to 20,000,000 pounds per square inch—must raise their fusing-points enormously, and the probabilities are that they are solid, in spite of the high temperature. But Thompson and Darwin have shown us farther that the phenomena of the oceanic tides could not be what they are known to be if the earth were any less rigid than a globe of solid steel; while Hopkins has proved that the astronomical phenomena of precession and nutation could not be what they are if the earth’s crust were less than 800 or 1000 miles thick. Putting these considerations together, geologists are almost universally agreed that, while the earth has an incandescent interior, it is still continuously solid from centre to circumference, with the exception of a thin plastic stratum at a depth not exceeding 40 or 50 miles, which forms the seat of volcanic action.

The earth is not only a very hot body, but it is rotating through almost absolutely cold space, and therefore must be a cooling body. But, except at the very beginning of the cooling, the loss of heat has gone on almost entirely from the interior; and since cooling means contraction, the heated interior must be constantly tending to shrink away from the cold external crust.

Of course no actual separation between the crust and interior or nucleus can take place, but there is no doubt that the crust is left unsupported to a certain extent, and it must then behave like an arch with a radius of 4000 miles, and the result is an enormous horizontal or tangential pressure.

This lateral pressure in the earth’s crust is one of the most important and most generally accepted facts in geology, and lies at the bottom of many geological theories. According to what seems to me to be the most probable theory of the origin of continents and ocean-basins, they are broad upward and downward bendings or arches into which the crust is thrown by the tangential pressure. Finally, the strain becomes great enough to crush the crust along those lines where it is weakest. When the crust is thus mashed up by horizontal pressure, a mountain range is formed, the crust becomes enormously thicker, and a weak place becomes a strong one.

During the formation of mountains the stratified rocks, which were originally horizontal, are thrown into folds or arches, and tipped up at all possible angles; they are fractured and faults produced; and by the immense pressure the structure known as slaty cleavage is developed. In fact, a vast amount and variety of structures are produced during the growth of a mountain range.

These great earth-movements are not always perfectly smooth and steady, but they are accompanied by slipping or crushing now and then; and, as a result of the shock thus produced, a swift vibratory movement or jar, which we know as an earthquake, runs through the earth’s crust.

Extensive fissures are also formed, opening down to the regions where the rocks are liquid or plastic, and through these the melted rocks flow up to or toward the surface. That portion which flows out on the surface builds up a volcanic cone, while that which cools and solidifies below the surface, in the fissures, forms dikes. Thus among the igneous or eruptive rocks we have two great classes,—the dike rocks and the volcanic rocks.

It is important to observe that all these subterranean operations—the formation of continents, of mountain-ranges with all their attendant phenomena of folds, faults and cleavage, and every form and phase of earthquake and volcanic activity—depend upon or originate in the interior heat of the earth. And over against the superficial or aqueous agencies, originating in the solar heat and producing the stratified or sedimentary rocks, we set the subterranean or igneous agencies originating in the central heat, and producing the unstratified or eruptive rocks.

STRUCTURAL GEOLOGY.

In geology, just as in biology, there are two ways of studying structure,—the small way and the large way. In the case of an organism, we may select a single part or organ, and, disregarding its external form and relations to other parts, observe its composition and minute structure, the various forms and arrangements of the cells, etc. This is histology, and it is the complement of that larger method of studying structure which is ordinarily understood by anatomy.

The divisions of structural geology corresponding to histology and anatomy are lithology and petrology. Lithology is an in-door science; we use the microscope largely, and work with hand specimens or thin sections of the rocks, observing the composition and those small structural features which go under the general name of texture.

In petrology, on the other hand, we consider the larger kinds of rock-structure, such as stratification, jointing, folds, faults, cleavage, etc.; and it is essentially an out-door science, since to study it to the best advantage we must have, not hand specimens, but ledges, cliffs, railway-cuttings, gorges, and mountains.

LITHOLOGY.

A rock is any mineral, or mixture of minerals, occurring in masses of considerable size. This distinction of size is the only one that can be made between rocks and minerals, and that is very indefinite. A rock, whether composed of one mineral or several, is always an aggregate; and therefore no single crystal or mineral-grain can properly be called a rock.

Before proceeding to study particularly the various kinds of rocks, a little more preliminary work should be done. As already intimated, the more important characteristics of rocks may be grouped under two general heads,—composition and texture.

Composition of Rocks.

Rocks are properly defined as large masses or aggregates of mineral matter, consisting in some cases of one and in other cases of several mineral species. Hence it is clear that the composition of rocks is of two kinds: chemical and mineralogical; for the various chemical elements are first combined to form minerals, and then the minerals are combined to form rocks.

Of course those minerals and elements which can be described as principal or important rock-constituents must be the common minerals and elements. Now it is a very important and convenient fact that although chemists recognize about sixty-five elementary substances, and these are combined to form nearly one thousand mineral species, yet both the common elements and the common minerals are few in number.

So that, although it is very desirable and even necessary for the student of lithology to know something of chemistry and mineralogy, it by no means follows that he or she must be master of those sciences. A knowledge of the chemical and physical characteristics of a few common minerals is all that is absolutely essential, though it may be added that an excess of wisdom in these directions is no disadvantage.

Chemical Composition of Rocks.

The elementary substances of which rocks are chiefly composed, which make up the main mass of the earth so far as we are acquainted with it, number only fourteen:—

Non-Metallic or Acidic Elements.—Oxygen, silicon, carbon, sulphur, chlorine, phosphorus, and fluorine.

Metallic or Basic Elements.—Aluminum, magnesium, calcium, iron, sodium, potassium, and hydrogen.

The elements are named in each group in about the order of their relative abundance; and to give some idea of the enormous differences in this respect it may be stated that two of the elements—oxygen and silicon—form more than half of the earth’s crust.

Silicon, calcium, and fluorine, although exceedingly abundant, are also very difficult to obtain in the free or uncombined state, and specimens large enough to exhibit to a class would be very expensive. With these exceptions, however, examples of these common rock-forming elements are easily obtained.

My purpose in calling attention to this point is simply to suggest that the proper way to begin the study of minerals and rocks with children is to first familiarize them with the elements of which they are composed. The most important thing to be known about any mineral is its chemical composition; and when a child is told that a mineral—corundum, for example—is composed of oxygen and aluminum, he should have a distinct conception of the properties of each of those elements, for otherwise corundum is for him a mere compound of names.

It is very important, too, if the pupil has not already studied chemistry, that he should be led to some comprehension of the nature of chemical union and of the difference between a chemical compound and a mechanical mixture. For this purpose a few simple experiments (the details of which would be out of place here) with the more common and familiar elements will be sufficient. Mrs. Richard’s “First Lessons in Minerals” should be introduced here.

Mineralogical Composition of Rocks.

The fourteen elements named above are combined to form about fifty minerals with which the student of geology should be acquainted; but not more than one-half of these are of the first importance. It is desired to lay especial emphasis upon the importance of a perfect familiarity with these few common minerals. There is nothing else in the whole range of geology so easily acquired which is at the same time so valuable; for it is entirely impossible to comprehend the definitions of rocks, or to recognize rocks certainly and scientifically, unless we are acquainted with their constituent minerals.

With one or two exceptions, these common rock-forming minerals may be easily distinguished by their physical characters alone, so that their certain recognition is a matter of the simplest observation, and entirely within the capacity of young children. Furthermore, being common, specimens of these minerals are very easily obtained, so that there is no reason why teachers should not here adopt the best method and place a specimen of each mineral in the hands of each pupil. Typical examples, large enough to show the characteristics well, ought not to cost, on the average, over two cents apiece.

A MINERAL is an inorganic body having theoretically a definite chemical composition, and usually a regular geometric form.

The Principal Characteristics of Minerals.—These may be grouped under the following general heads:—

(1) Composition, (2) Crystalline form, (3) Hardness, (4) Specific gravity, (5) Lustre, (6) Color and Streak.

1. Composition.—This, according to the definition of a mineral, ought to be definite, and expressible by a chemical formula. When it is not so, we usually consider that the mineral is partially decomposed, or that we are dealing with a mixture of minerals. It is well to impress upon the mind of the pupil the important fact that the more fundamental properties of the elements, such as specific gravity and lustre, are not lost when they combine, but may be traced in the compounds. In other words, the properties of minerals are, in a very large degree, the average of the properties of the elements of which they are composed; minerals in which heavy metallic elements predominate being heavy and metallic, and vice versa.

To fully appreciate this point it is only necessary to compare a mineral like galenite—a common ore of lead, and containing nearly 87 per cent. of that heavy metal; or hematite (specimen 13), containing 70 per cent. of another heavy metal, iron—with quartz (specimen 15), which is composed in nearly equal parts of oxygen and silicon, two typical non-metallic elements. Many minerals contain water, i.e., are hydrated. Now water, whether we consider the liquid or solid state, is one of the lightest and softest of mineral constituents; and it is a very important fact that hydrated minerals are invariably lighter and usually softer than anhydrous species of otherwise similar composition. Other striking illustrations of this principle will be pointed out in the descriptions of the minerals which follow.

2. Crystalline form.—A crystal is bounded by plane surfaces symmetrically arranged with reference to certain imaginary lines passing through its centre and called axes. Crystals of the same species are always constant in the angles between like planes, while similar angles usually vary in different species; so that each species has its own peculiar form.

“Besides external symmetry of form, crystallization produces also regularity of internal structure, and often of fracture. This regularity of fracture, or tendency to break or cleave along certain planes, is called cleavage. The surface afforded by cleavage is often smooth and brilliant (see specimens 17, 18, and 21), and is always parallel with some external plane of the crystal. It should be understood that the cleavage lamellæ are not in any sense present before they are made to appear by fracture.”—(Dana.)

Crystals are arranged in six systems, based upon the number and relations of the axes, as follows:—

Isometric System.—Three equal axes crossing at right angles. Example, cube.

Tetragonal System.—Two axes equal, third unequal, all crossing at right angles. Example, square prism.

Orthorhombic System.—Three unequal axes, but intersections all at right angles. Example, rhombic prism.

Monoclinic System.—Three unequal axes, one intersection oblique. Example, oblique rhombic prism.

Triclinic System.—Three unequal axes, all crossing obliquely. Example, oblique rhomboidal prism.

Hexagonal System.—Three equal axes lying in one plane and intersecting at angles of 60°, and a fourth axis crossing each of these at right angles and longer or shorter. Example, hexagonal prism.

By the truncation and bevelment of the angles and edges of these fundamental forms a vast variety of secondary forms are produced. The limits of the guide will not permit us to follow this topic farther; but it may be added that for the proper elucidation of even the simpler crystalline forms the teacher should be provided with a set of wooden crystal models and Dana’s “Text-Book of Mineralogy.”

The crystallization of a mineral may be manifested in two ways: first, by the regularity of its internal structure or molecular arrangement, as shown by cleavage and the polarization of transmitted light; and, second, by the regularity of external form which follows, under favorable conditions, as a necessary consequence of symmetry in the arrangement of the molecules.

When a mineral is entirely devoid of crystalline structure, both externally and internally, it is said to be amorphous.

Perfect and distinct crystals are the rare exception, most mineral specimens being simply aggregates of imperfect crystals. In such cases, and when the mineral is amorphous, the structure of the mass may be:—

Columnar or fibrous.

Lamellar, foliaceous, or micaceous.

Granular.—When the grains or crystalline particles are invisible to the naked eye the mineral is called impalpable, compact, or massive.

And the external form of the mass may be:—

Botryoidal, having grape-like surfaces.

Stalactitic, forming stalactites or pendant columns.

Amygdaloidal or Concretionary, forming separate globular masses in the enclosing rock.

Dendritic, branching or arborescent.

3. Hardness.—By the hardness of a mineral we mean the resistance which it offers to abrasion. But hardness is a purely relative term, calcite, for example, being hard compared with talc, but very soft compared with quartz. Hence mineralogists have found it necessary to select certain minerals to be used as a standard of comparison for all others, and known as the scale of hardness. These are arranged at nearly equal intervals all the way from the softest mineral to the hardest, as follows:—

Scale of Hardness.

(1) Talc.

(2) Gypsum.

(3) Calcite.

(4) Fluorite.

(5) Apatite.

(6) Orthoclase.

(7) Quartz.

(8) Topaz or Beryl.

(9) Corundum.

(10) Diamond.

If a mineral scratches calcite and is scratched by fluorite, we say its hardness is between 3 and 4, perhaps 3.5; if it neither scratches nor is scratched by orthoclase, its hardness is 6; and so on. There are very few minerals harder than quartz, and hence the first seven members of the scale are sufficient for all ordinary purposes; and these are all included in the series of specimens accompanying this Guide.

Although it is desirable to be acquainted with the scale of hardness, and to understand how to use it, still the student will learn, after a little practice, that almost as good results may be obtained much more conveniently by the use of his thumb-nail and a good knife-blade or file. Talc and gypsum are easily scratched with the nail; calcite and fluorite yield easily to the knife or file, apatite with more difficulty; while orthoclase is near the limit of the hardness of ordinary steel, and quartz is entirely beyond it.

4. Specific Gravity.—The specific gravity of a mineral, by which we mean its weight as compared with the weight of an equal volume of water, is determined by weighing it first in air and then in water, and dividing the weight in air by the difference of the two weights. Minerals exhibit a wide range in specific gravity; from petroleum, which floats on water, to gold, which is nearly twenty times heavier than water. Although this is one of the most important properties of minerals, yet, being more difficult to measure than hardness, it is less valuable as an aid in distinguishing species. One can with practice, however, estimate the density of a mineral pretty closely by lifting it in the hand.

5. Lustre.—Of all the properties of minerals depending on their relations to light the most important is lustre, by which we mean the quality of the light reflected by a mineral as determined by the character or minute structure of its surface. Two kinds of lustre, the metallic and vitreous, are of especial importance; in fact all other kinds are merely varieties of these.

The metallic lustre is the lustre of all true metals, as copper and tin, and characterizes nearly all minerals in which metallic elements predominate. The vitreous lustre is best exemplified in glass, but belongs to most minerals composed chiefly of non-metallic elements. Metallic minerals are always opaque, but vitreous minerals are often transparent.

Other kinds of lustre are the adamantine (the lustre of diamond), resinous, pearly, and silky. When a mineral has no lustre, like chalk, it is said to be dull.

It should be made clear to children that lustre and color are entirely distinct and independent. Thus, iron, copper, gold, silver, and lead are all metallic; while white or colorless quartz, black tourmaline, green beryl, red garnet, etc., are all vitreous. Generally speaking, any color may occur with any lustre.

6. Color and Streak.—The colors of minerals are of two kinds,—essential and non-essential. By the essential color in any case we mean the color of the mineral itself in its purest state. The non-essential colors, on the other hand, are chiefly the colors of the impurities contained in the minerals.

Metallic minerals, which are always opaque, usually have essential colors; but vitreous minerals, which are always more or less transparent, often have non-essential colors. The explanation is this: In opaque minerals we can only see the impurities immediately on the surface, and these are, as a rule, not enough to affect its color; but in diaphanous minerals we look into the specimen and see impurities below the surface, and thus bring into view, in many cases, sufficient impurity so that its color drowns that of the mineral.

To prove this we have only to take any mineral (serpentine is a good example in our series) having a non-essential color, and make it opaque by pulverizing it or abrading its surface, when the non-essential color, the color of the impurity, immediately disappears; just as water, yellow with suspended clay, becomes white when whipped into foam, and thus made opaque.

What we understand by the streak of a mineral is its essential color, the color of its powder; and it is so called because the powder is most readily observed by scratching the surface of the mineral, and thereby pulverizing a minute portion of it. The streak and hardness are thus determined at the same time. The streak of soft minerals is easily determined by rubbing them on any white surface of suitable hardness, as paper, porcelain, or Arkansas stone.

Essential and Accessory Minerals.—Lithologists, regarding minerals as constituents of rocks, divide them into two great classes: the essential and the accessory. The essential constituents of a rock are those minerals which are essential to the definition of the rock. For example, we cannot properly define granite without naming quartz and orthoclase; hence these are essential constituents of granite; and if either of these minerals were removed from granite it would not be granite any longer, but some other rock. But other minerals, like tourmaline and garnet, may be indifferently present or absent; it is granite still; hence they are merely accidental or accessory constituents. They determine the different varieties of granite, while the essential minerals make the species.

This classification, of course, is not absolute, for in many cases the same mineral forms an essential constituent of one rock and an accessory constituent of another. Thus, quartz is essential in granite, but accessory in diorite.

Principal Minerals constituting Rocks.—Having studied in a general way the more important characteristics of minerals, brief descriptions of the chief rock-forming species are next in order. We will notice first and principally those minerals occurring chiefly as essential constituents of rocks.

1. Graphite.—Essentially pure carbon, though often mixed with a little iron oxide. Crystallizes in hexagonal system, but usually foliated, granular, or massive. Hardness, 1-2, being easily scratched with the nail. Sp. gr., 2.1-2.3. Lustre, metallic; an exception to the rule that acidic elements have non-metallic or vitreous lustres. Streak, black and shining (see pencil-mark on white paper). Color, iron-black. Slippery or greasy feel. Every black-lead pencil is a specimen of graphite. Specimen 9.

The different kinds of mineral coal are, geologically, as we have seen, closely related to graphite, but they are such familiar substances that they need not be described here.

2. Halite (common salt).—Chloride of sodium: chlorine, 60.7; sodium, 39.3; = 100. Isometric system, usually forming cubes. Hardness, 2.5, a little harder than the nail. Sp. gr., 2.1-2.6. Lustre, vitreous. Streak and color both white, and hence color is essential. Often transparent. Soluble; taste, purely saline. In specific gravity and lustre it is a good example of a mineral in which an acidic element predominates. Specimen 11.

3. Limonite.—Hydrous sesquioxide of iron: oxygen, 25; iron, 60; water, 15; = 100. Usually amorphous; occurring in stalactitic and botryoidal forms, having a fibrous structure; and also concretionary, massive, and earthy (yellow ochre). Hardness, 5-5.5. Sp. gr., 3.6-4. Lustre, vitreous or silky, inclining to metallic, and sometimes dull. Color, various shades of black, brown, and yellow. Streak, ochre-yellow; hence color partly non-essential. Specimen 12.

4. Hematite.—Sesquioxide of iron: oxygen, 30; iron, 70; = 100. Hexagonal system, in distinct crystals, but usually lamellar, granular, or compact,—columnar, botryoidal, and stalactitic forms being common. Hardness, 5.5-6.5; good crystals are harder than steel. Sp. gr., 4.5-5.3. Lustre, metallic, sometimes dull. Color, iron-black, but red when earthy or pulverized (red ochre). Streak, red, and color, therefore, mainly non-essential; sometimes attracted by the magnet. Specimen 13.

Hematite has the same composition as limonite, minus the water; and by comparing the hardness and specific gravity of these two minerals we see that they are a good illustration of the principle that hydrous minerals are softer and lighter than anhydrous minerals of analogous composition. Limonite and hematite are two great natural coloring agents, and almost all yellow, brown, and red colors in rocks and soils are due to their presence.

5. Magnetite.—Protoxide and sesquioxide of iron: oxygen, 27.6; iron, 72.4; = 100. Isometric system, usually in octahedrons or dodecahedrons. Most abundant variety is coarsely to finely granular, sometimes dendritic. Hardness, 5.5-6.5, same as hematite. Sp. gr., 4.9-5.2. Lustre, metallic. Color and streak, iron-black, and hence color essential. Strongly magnetic; some specimens have distinct polarity, and are called loadstones. Specimen 14.

The three iron-oxides just described—limonite, hematite, and magnetite—are all important ores of iron, and form a well-marked natural series. Thus limonite is never, hematite is usually, and magnetite is always, crystalline. Again, limonite with 60 per cent. of iron is never magnetic, hematite with 70 per cent. is sometimes magnetic, while magnetite with 72.4 per cent. is always magnetic. As the iron increases so does the magnetism. We have here an excellent illustration of the principle that the properties of the elements can be traced in those minerals in which they predominate. Iron is the only strongly magnetic element: magnetite contains more iron than any other mineral, and it is the only strongly magnetic mineral.

These three iron-ores are easily distinguished from each other by the color of their powders or streak,—limonite yellow, hematite red, and magnetite black,—and from all other common minerals by their high specific gravity.

6. Quartz.—Oxide of silicon or silica: oxygen, 53.33; silicon, 46.67; = 100. Hexagonal system. The most common form is a hexagonal prism terminated by a hexagonal pyramid. Also coarsely and finely granular to perfectly compact, like flint; the compact or cryptocrystalline varieties often assuming botryoidal, stalactitic, and concretionary forms. It has no cleavage, but usually breaks with an irregular, conchoidal fracture like glass. Hardness, 7, being No. 7 of the scale; scratches glass easily. Sp. gr., 2.5-2.8. Lustre, vitreous. Pure quartz is colorless or white, but by admixture of impurities it may be of almost any color. Streak always white or light colored. Quartz is usually, as in specimen 15, transparent and glassy, but may be translucent or opaque. It is almost absolutely infusible and insoluble.

The varieties of quartz are very numerous, but they may be arranged in two great groups:—

1. Phenocrystalline or vitreous varieties, including rock-crystal, amethyst, rose quartz, yellow quartz, smoky quartz, milky quartz, ferruginous quartz, etc.

2. Cryptocrystalline or compact varieties, including chalcedony, carnelian, agate, onyx, jasper, flint, chert, etc. Only three varieties, however, are of any great geological importance; these are: common glassy quartz (spec. 15), flint (spec. 16), and chert.

Quartz is one of the most important constituents of the earth’s crust, and it is also the hardest and most durable of all common minerals. We have already observed (p. 12) that it is entirely unaltered by exposure to the weather; i.e., it cannot be decomposed; and, being very hard, the same mechanical wear which, assisted by more or less chemical decomposition, reduces softer minerals to an impalpable powder or clay, must leave the quartz chiefly in the form of sand and gravel. This agrees with our observation that sand (spec. 30), especially, is usually merely pulverized quartz.

Opal is a mineral closely allied to quartz, and may be mentioned in this connection. It is of similar composition, but contains from 5 to 20 per cent. of water, and is decidedly softer and lighter. Hardness, 5.5-6.5; sp. gr., 1.9-2.3.

7. Gypsum.—Hydrous sulphate of calcium: sulphur trioxide (SO₃), 46.5; lime (CaO), 32.6; water (H₂O), 20.9; = 100. Monoclinic system. Often in distinct rhombic crystals; also foliated, fibrous, and finely granular. Hardness, 1.5-2; the hardest varieties being No. 2 of the scale of hardness. Sp. gr., 2.3. Lustre, pearly, vitreous, or dull. Color and streak usually white or gray. The principal varieties of gypsum are (a) selenite, which includes all distinctly crystallized or transparent gypsum; (b) fibrous gypsum or satin-spar; (c) alabaster, fine-grained, light-colored, and translucent. Gypsum is easily distinguished from all common minerals resembling it by its softness and the fact that it is not affected by acids. Specimen 17.

8. Calcite.—Carbonate of calcium: carbon dioxide (CO₂), 44; lime (CaO), 56; = 100. Hexagonal system, usually in rhombohedrons, scalenohedrons, or hexagonal prisms. Cleavage rhombohedral and highly perfect (specimen 18). Also fibrous and compact to coarsely granular, in stalactitic, concretionary, and other forms. Hardness, 2.5-3.5, usually 3 (see scale of hardness). Sp. gr., 2.5-2.75. Lustre, vitreous. Color and streak usually white. Transparent crystallized calcite is known as Iceland-spar, and is remarkable for its strong double refraction. When finely fibrous it makes a satin-spar similar to gypsum. Geologically speaking, calcite is a mineral of the first importance, being the sole essential constituent of all limestones. It is readily distinguished from allied species by its perfect rhombohedral cleavage; by its softness, being easily scratched with a knife; and above all by its lively effervescence with acids, for it is the only common mineral effervescing freely with cold dilute acid. To apply this test it is only necessary to touch the specimen with a drop of dilute chlorohydric acid. The effervescence, of course, is due to the escape of the carbon dioxide in a gaseous form. Specimen 18.

9. Dolomite.—Carbonate of calcium and magnesium: carbonate of calcium (CaCO₃), 54.35; carbonate of magnesium (MgCO₃), 45.65; = 100. Hexagonal system, being nearly isomorphous with calcite. Rhombohedral cleavage perfect. Hardness, 3.5-4; sp. gr., 2.8-2.9, being harder and heavier than calcite. Lustre, color, and streak same as for calcite, from which it is most easily distinguished by its non-effervescence or only feeble effervescence with cold dilute acid, though effervescing freely with strong or hot acid. Spec. 19.

10. Siderite.—Carbonate of iron: carbon dioxide (CO₂), 37.9; protoxide of iron (FeO), 62.1; = 100. Crystallization and cleavage essentially the same as for calcite and dolomite. Hardness, 3.5-4.5, and sp. gr., 3.7-3.9. Lustre, vitreous. Color, white, gray, and brown. Streak, white. With acid, siderite behaves like dolomite. It is distinguished from both calcite and dolomite by its high specific gravity, which is easily explained by the fact that it is largely composed of the heavy element, iron.

With one exception, the fifteen minerals which we have yet to study belong to the class of silicates, which includes more than one-fourth of the known species of minerals, and, omitting quartz and calcite, all of the really important rock-constituents. The silicate minerals may be very conveniently divided into two great groups, the basic and acidic. This is not a sharp division; on the contrary, there is a perfectly gradual passage from one group to the other; and yet this is, for geological purposes at least, a very natural classification. The dividing line falls in the neighborhood of 60 per cent. of silica; i.e., all species containing this proportion of silica or less are classed as basic, since in them the basic elements predominate; while those containing more than 60 per cent. of silica are classed as acidic, because their characteristics are determined chiefly by the acid element or silica. The principal bases occurring in the silicates, named in the order of their relative importance, are aluminum, magnesium, calcium, iron, sodium, and potassium; and of these, magnesium, calcium, iron, and usually sodium, are especially characteristic of basic species.

Iron is the heaviest base; but all the bases, except sodium and potassium, are heavier than the acid—silica; consequently basic minerals must be, as a rule, heavier than acidic minerals. And since basic minerals contain more iron than acidic, they must be darker colored. In general, we say, dark, heavy silicates are basic, and vice versa. All this is of especial importance because in the rocks nature keeps these two classes separate in a great degree.

11. Amphibole.—Silicate of aluminum, magnesium, calcium, iron, and sodium. The bases occur in very various proportions, forming many varieties; but the only variety of especial geological interest is hornblende, the average percentage composition of which is as follows: silica (SiO₂), 50; alumina (Al₂O₃), 10; magnesia (MgO), 18; lime (CaO), 12; iron oxide (FeO and Fe₂O₃), 8; and soda (Na₂O), 2; = 100. Monoclinic system: usually in rhombic or six-sided prisms which may be short and thick, but are more often acicular or bladed. Hardness, 5-6; sp. gr., 2.9-3.4. Lustre, vitreous; color, black and greenish black; and streak similar to color, but much paler. Compare with quartz, and observe the strong contrast in color possible with minerals having the same lustre. Specimen 20.

12. Pyroxene.—Like amphibole, this species embraces many varieties, and these exhibit a wide range in composition; but of these augite alone is an important rock-constituent. Hence in lithology we practically substitute for amphibole and pyroxene, hornblende, and augite respectively.

Augite is very similar in composition to hornblende, but contains usually more lime and less alumina and alkali. Physically, too, these minerals are almost identical, crystallizing in the same system and in very similar forms, and agreeing in hardness, color, lustre, and streak. Augite is heavier than hornblende, sp. gr., 3.2-3.5. A certain prismatic angle, which in augite is 87°5´, is 124°30´ in hornblende. Slender, bladed crystals are more common with hornblende than augite. When examined in thin sections with the polarizer, augite does not afford the phenomenon of dichroism, which is strongly marked in hornblende. However, as these minerals commonly occur in the rocks, in small and imperfect crystals, these distinctions can only be observed in thin sections under the microscope; so that, as regards the naked eye, they are practically indistinguishable.

It might appear at first that the distinction of minerals so nearly identical is not an important matter; but nature has decreed otherwise. Augite and hornblende are typical examples of basic minerals; but augite is, both in its composition and associations, the more basic of the two. In proof of this we need only to know that it very rarely occurs in the same rock with quartz, while hornblende is found very commonly in that association. Quartz in a rock means an excess of acid or silica, and almost necessarily implies the absence of highly basic minerals. In other words, hornblende is often, and augite very rarely, found in connection with acidic minerals; and it is this difference of association chiefly that makes their distinction essential to the proper recognition of rocks; while at the same time it affords an easy, though of course not absolutely certain, means of determining whether the black constituent of any particular rock is hornblende or augite.

Mica Family.—Mica is not the name of a single mineral, but of a whole family of minerals, including some half-dozen species. Only two, however,—muscovite and biotite,—are sufficiently abundant to engage our attention. These are complex, basic silicates of aluminum, magnesium, iron, potassium, and sodium. The crystallization of biotite is hexagonal, and of muscovite monoclinic; but both occur commonly in flat six-sided forms. Undoubtedly the most important and striking characteristic of the whole mica family is the remarkably perfect cleavage parallel with the basal planes of the crystals, and the wonderful thinness, and above all the elasticity, of the cleavage lamellæ. The cleavage contrasts the micas with all other common minerals, and makes their certain identification one of the easiest things in lithology. The micas are soft minerals, the hardness ranging from 2 to 3, and being usually easily scratched with the nail. Sp. gr. varies from 2.7-3.1. Lustre, pearly; and streak, white or uncolored.

The distinguishing features of muscovite and biotite are as follows:—

13. Muscovite.—Contains 47 per cent. of silica, 3 per cent. of sesquioxide of iron, and 10 per cent. of alkalies, chiefly potash; and the characteristic colors are white, gray, and, more rarely, brown and yellow. Non-dichroic. Usually found in association with acidic minerals. The mica used in the arts is muscovite. Specimen 21.

14. Biotite.—Contains only 36 per cent. of silica, 20 per cent. of oxide of iron, and 17 per cent. of magnesia; colors, deep black to green. Strongly dichroic. Commonly occurs with other basic minerals. Compare color with per cent. of iron.

These differences are tabulated below:—

Feldspar Family.—Like mica, feldspar is the name of a family of minerals; and these are, geologically, the most important of all minerals. They are, above all others, the minerals of which rocks are made, and their abundance is well expressed in the name,—feldspar being simply the German for field-spar, implying that it is the common spar or mineral of the fields.

Chemically, the feldspars are silicates of aluminum and potassium, sodium or calcium. They crystallize in the monoclinic and triclinic systems; and all possess easy cleavage in two directions at right angles to each other, or nearly so. The general physical characters, including the cleavage, are well exhibited in the common species, orthoclase (specimen 22).

In hardness the feldspars range from 5 to 7, being usually near 6, and almost always distinctly softer than quartz. Sp. gr. varies from 2.5-2.75; lustre, from vitreous to pearly; color, from white and gray to red, brown, green, etc., but usually light. Streak, always white; rarely transparent. By exposure to the weather, feldspars gradually lose their alkalies and lime, become hydrated, and are changed to kaolin or common clay. A similar change takes place with the micas, augite, and hornblende; but these species, being usually rich in iron, make clays which are much darker colored than those derived from feldspars. The fact that the feldspars contain little or no iron undoubtedly explains their low specific gravity and light colors, as compared with the other minerals just named. The only common minerals for which the feldspars are liable to be mistaken are quartz and the carbonates. From the latter they are easily distinguished by their superior hardness and non-effervescence with acids; and from the former, by possessing distinct cleavage, by being rarely transparent, by being somewhat softer, and by changing to clay on exposure to the weather.

The feldspars of greatest geological interest are five in number, and may be classified chemically as follows:—

This appears like a complex arrangement, but it can be simplified. Orthoclase crystallizes in the monoclinic system, and all the other feldspars in the triclinic system. With the exception of albite, which is a comparatively rare species, the triclinic feldspars all contain less silica than orthoclase; i.e., are more basic. This is shown by the subjoined table giving the average composition of each of the feldspars:—

As we should naturally expect, the triclinic feldspars occur usually with other basic minerals, while the monoclinic species, orthoclase, is acidic in its associations; furthermore, the triclinic feldspars are often intimately associated with each other, but are rarely important constituents of rocks containing much orthoclase. In other words, the distinction of orthoclase from the basic or triclinic feldspars is important and comparatively easy, while the distinction of the different basic feldspars from each other is both unimportant and difficult. Hence, in lithology, we find it best to put all these basic feldspars together, as if they were one species, under the name plagioclase, which refers to the oblique cleavage of all these feldspars, and contrasts with orthoclase, which refers to the right-angled cleavage of that species.

This statement of the relations of the feldspars is, of course, beyond the comprehension of many children, and yet it should be understood by the teacher who would lead the children to any but the most superficial views.

15. Orthoclase.—This is the common feldspar, and the most abundant of all minerals, being the principal constituent of granite, gneiss, and many other important rocks. The most characteristic colors are white, gray, pinkish, and flesh-red. Specimen 22.

16. Plagioclase.—Like orthoclase, these species may be of almost any color; yet these two great divisions of the feldspars are usually contrasted in this respect. Thus, bluish and grayish colors are most common with plagioclase, and white or reddish colors with orthoclase. Specimen 23 is labradorite, and, in every respect, a typical example of plagioclase. On certain faces and cleavage-surfaces of the plagioclase crystals we may often observe a series of straight parallel lines or bands which are often very fine,—fifty to a hundred in a single crystal. These striæ are due to the mode of twinning, and are of especial importance, since, while they are very characteristic of plagioclase, they never occur in orthoclase. As stated, these twinning striæ in plagioclase are often visible to the naked eye; and when they are not, they may usually be revealed by examining a thin section under the microscope with polarized light. Plagioclase decays much more rapidly when exposed to the weather than orthoclase. This point becomes perfectly clear when we compare weathered ledges of diabase (or any trap-rock, see specimen 2) and granite; for plagioclase is the principal constituent of the former rock, and orthoclase of the latter.

Hydrous Silicates.—Many silicates contain water, and some of these are of great geological importance. What has been stated on a preceding page concerning the softness and lightness of hydrated minerals is especially applicable here; for all the geologically important hydrous silicates are distinctly softer and lighter than anhydrous minerals of otherwise similar composition. Furthermore, they usually have an unctuous or slippery feel; and, with one exception (kaolin), are of a green or greenish color.

17. Kaolinite (Kaolin).—Hydrous silicate of aluminum: silica (SiO₂), 46; alumina (Al₂O₃), 40; and water (H₂O), 14; = 100. Orthorhombic system, in rhombic or hexagonal scales or plates, but usually earthy or clay-like. Hardness, 1-2.5; sp. gr., 2.4-2.65. The pure mineral is white; but it is usually colored by impurities, the principal of which are iron oxides and carbonaceous matter. Kaolin is the most abundant of all the hydrous silicates, and it is the basis and often the sole constituent of common clay,—a very common mineral, but rarely pure. We have already (p. 11) noticed the mode of origin of kaolin or clay. It results from the decomposition of various aluminous silicate minerals, especially the feldspars. Under the combined influence of carbon dioxide and moisture, feldspars give up their potassium, sodium, and calcium, and take on water, and the result is kaolin. This mineral is believed to be always a decomposition product. Perhaps the best, or at least the most convenient, test for kaolin is the argillaceous odor, the odor of moistened clay. Specimen 24.

18. Talc.—Hydrous silicate of magnesium: silica (SiO₂), 63 (acidic); magnesia (MgO), 32; water (H₂O), 5; = 100. Orthorhombic system, but rarely in distinct crystals. Cleavage in one direction very perfect; the cleavage lamellæ are flexible, but not elastic, as in mica. Hardness, 1; see scale. Sp. gr., 2.55-2.8. Lustre, pearly. Color, apple-green to white; and streak, white. The feel is very smooth and greasy; and, in connection with the color and foliation, affords the best means of distinguishing talc from allied minerals. Talc sometimes results from the alteration of augite, hornblende, and other minerals, but it is not always nor usually an alteration product.

19. Serpentine.—Hydrous silicate of magnesium: silica (SiO₂), 44 (basic); magnesia (MgO), 44; water (H₂O), 12; = 100. Essentially amorphous. Hardness, 2.5-4; sp. gr., 2.5-2.65. Lustre, greasy, waxy, or earthy. Color, various shades of green and usually darker than talc, but streak always white. Feel, smooth, sometimes greasy. Distinguished from talc by its hardness, compactness, and darker green. Sometimes results from the alteration of olivine and other magnesian minerals, but usually we are to regard it as an original mineral. Specimen 25.

20. Chlorite.—This is, properly, the name of a group of highly basic minerals of very variable composition, but they are all essentially hydrous silicates of aluminum, magnesium, and iron; and the average composition of the most abundant species, prochlorite, is as follows: silica (SiO₂), 30; alumina (Al₂O₃), 18; magnesia (MgO), 15; protoxide of iron (FeO), 26; and water (H₂O), 11; = 100. The chlorites crystallize in several different systems, but in all there is a highly perfect cleavage in one direction, giving, as in talc, a foliated structure with flexible but inelastic laminæ. The cleavage scales, however, are sometimes minute, and the structure massive or granular. Hardness of prochlorite, 1-2; between talc and serpentine. Sp. gr., 2.78-2.96. All the chlorites have a pearly to vitreous lustre. Color usually some shade of green; in prochlorite a dark or blackish green, darker than serpentine, as that is darker than talc. Streak, a lighter, whitish green. Less unctuous than talc, but more so than serpentine. The chlorites are produced very commonly, but not generally, by the alteration of basic anhydrous silicates, like augite and hornblende. Specimen 26.

21. Hydro-mica.—This, too, is properly the name of a group of minerals; but for geological purposes they may be regarded as one species. Taking a general view of the composition, these are simply the anhydrous or ordinary micas, which we have already studied, with from 5 to 10 per cent. of water added. In crystallization and structure they are essentially mica-like. Although not distinctly softer than the common micas, they are lighter, always more unctuous and slippery, and usually of a greenish color. The micaceous structure with elastic laminæ serves to distinguish the hydro-micas from other hydrous silicates.

22. Glauconite.—Hydrous silicate of aluminum, iron, and potassium: silica (SiO₂), 50; alumina (Al₂O₃), protoxide of iron (FeO), and potash (K₂O), together, 41; and water (H₂O), 9; = 100. Amorphous, forming rounded and generally loose grains, which often have a microscopic organic nucleus. It is dull and earthy, like chalk, and always soft, green, and light, but not particularly unctuous. Glauconite is the principal, often the sole, constituent of the rock greensand, which occurs abundantly in the newer geological formations, and is now forming in the deep water of the Gulf of Mexico and along our Atlantic sea-board. Specimen 27.

This completes our list of minerals occurring chiefly as essential constituents of rocks; and following are three of the more common and important minerals occurring chiefly as accessory, rarely as essential, rock-constituents.

23. Chrysolite (Olivine).—Silicate of magnesium and iron: silica (SiO₂), 41; magnesia (MgO), 51; protoxide of iron (Fe₂O₃), 8; = 100. Orthorhombic system; but usually in irregular glassy grains. Hardness, 6-7. Sp. gr., 3.3-3.5. Lustre, vitreous; color, usually some shade of green; and streak, white. Chrysolite sometimes closely resembles quartz, but its green color usually suffices to distinguish it. It is a common constituent of basalt and allied rocks. By absorption of water it is changed into serpentine and talc. See examples in specimen.

24. Garnet.—The composition of this mineral is extremely variable; but the most important variety is a basic silicate of aluminum and iron: silica (SiO₂), 37; alumina (Al₂O₃), 20; and protoxide of iron (FeO), 43; = 100. Isometric system, usually in distinct crystals, twelve-sided (dodecahedrons) and twenty-four-sided (trapezohedrons) forms being most common. Hardness, 6.5-7.5; average as hard as quartz. Sp. gr., 3.15-4.3; compare with the high percentage of iron. Lustre, vitreous; colors, various, usually some shade of red or brown; and streak, white. Some varieties contain iron enough to make them magnetic. Garnet is easily distinguished by its form, color, and hardness from all other minerals. It is a common but not an abundant mineral, occurring most frequently in gneiss, mica schist, and other stratified crystalline rocks. See examples in specimen.

25. Pyrite.—Sulphide of iron: sulphur, 53.3; iron, 46.7; = 100. Isometric system, occurring usually in distinct crystals, the cube and the twelve-sided form known as the pyritohedron being the most common. Hardness, 6-6.5, striking fire with steel. Sp. gr., 4.8-5.2; heavy because rich in iron. Lustre, metallic and splendent. Color, pale, brass-yellow, and streak, greenish or brownish. Pyrite is sometimes mistaken for gold, but it is not malleable; while its color, hardness, and specific gravity, combined, easily distinguish it from all common minerals. As an accessory rock-constituent, pyrite occurs usually in isolated cubes or pyritohedrons. Specimen 10.

Textures of Rocks.

Texture is a general name for those smaller structural features of rocks which can be studied in hand specimens, and which depend upon the forms and sizes of the constituent particles of the rocks, and the ways in which these are united.

By “constituent particles” we mean, not the atoms or molecules of matter composing the rocks, but the pebbles in conglomerate, grains of sand in sandstone, crystals of quartz, feldspar, and mica in granite, etc. The four most important textures are:—

(1) Fragmental texture.—The rock is composed of mere irregular, angular, or rounded, but visible, fragments. Examples: sand, sandstone, gravel, conglomerate, etc. Specimens 30, 31, 28, 29.

(2) Crystalline texture.—The constituent particles are chiefly, at least, distinctly crystalline, as shown either by external form, or cleavage, or both. Examples: granite, diabase, gneiss, etc. Specimens 45, 1, 41.

(3) Compact texture.—The constituent particles are indistinguishable by the naked eye, but become visible under the microscope, appearing as separate crystalline grains or as irregular fragments. In other words, if, in the case of either the granular or crystalline textures, we conceive the particles to become microscopically small, then we have the compact texture. Examples: clay, slate, many limestones, basalt, etc. Specimens 34, 35, 39.

(4) Vitreous texture.—The texture of glass, in which the constituent particles are absolutely invisible even with the highest powers of the microscope, and may be nothing more than the molecules of the substance, which thus, so far as our powers of observation are concerned, presents a perfectly continuous surface. Examples: obsidian, glassy quartz, and some kinds of coal. Specimens 47, 15.

These four textures, which, it will be observed, are determined by the forms and sizes of the constituent particles, may be called the primary textures, because every rock must possess one of them. We cannot conceive of a rock which is neither fragmental, crystalline, compact, nor vitreous. But in addition to one of the primary textures, a rock may or may not have one or more of what may be called secondary textures. These are determined by the way in which the particles are united, the mode or pattern of the arrangement, etc. Following are definitions of the principal secondary textures:—

(1) Laminated texture.—This exists where the particles are arranged in thin, parallel layers, which may be marked simply by planes of division, or the alternate layers may be composed of particles differing in composition, form, size, or color, etc. Among the laminated textures we thus distinguish: (a) the banded texture, where the layers are contrasted in color, texture, or composition, but cohere, so that there is no cleavage or easy splitting parallel with the stratification; and (b) the schistose or shaly texture, where such fissility or stratification-cleavage exists. If a fragmental, compact, or vitreous rock is fissile, we use the term shaly; but a fissile, crystalline rock is described as schistose. The banded texture may occur with the fragmental,—banded sandstones, etc.; with the crystalline,—many gneisses, etc. (specimen 41); with the compact,—many slates, limestones, felsites, etc. (specimens 34, 42); with the vitreous,—banded obsidian, furnace slags, and some coal. The schistose texture may occur with the crystalline,—mica schist, etc. (specimen 43); and the shaly texture with the compact and fragmental, but rarely with the vitreous.

(2) Porphyritic texture.—We have this texture when separate and distinct crystals of any mineral, but most commonly of feldspar, are enclosed in a relatively fine-grained base or matrix, which may be either crystalline, compact, or vitreous, but rarely fragmental. Specimens 5, 6, 7 are examples of the porphyritic compact texture.

(3) Concretionary texture.—When one or more constituents of a rock have the form, in whole or in part, not of distinct angular crystals, but of rounded concretions, the texture is described as concretionary, the concretions taking the place in this texture of the isolated crystals in the porphyritic texture. This texture occurs in connection with all the primary textures, but the most familiar example is oölitic limestone.

(4) Vesicular texture.—A rock has this texture when it contains numerous small cavities or vesicles. These are most commonly produced by the expansion of steam and other vapors when the rock is in a plastic state; and hence the vesicular texture is found chiefly in volcanic rocks. Except rarely, it is associated only with the compact texture,—ordinary stony lavas (specimen 49); and with the vitreous texture,—pumice (specimen 48).

(5) Amygdaloidal texture.—In the course of time the vesicles of common lava are often filled with various minerals deposited by infiltrating waters, giving rise to the amygdaloidal texture, from the Latin amygdalum, an almond, in allusion to a common form of the vesicles, or amygdules, as they are called, after being filled. The amygdaloidal texture is thus necessarily preceded by the vesicular, and is limited to the same classes of rocks. Specimen 50.

Besides the foregoing, there are many minor secondary textures. The rocks known as tufas have what may be called the tufaceous texture. Then we have kinds of texture depending on the strength of the union of the particles, as strong, weak, friable, earthy, etc.

Classification of Rocks.

Having finished our preliminary observations on the characteristics of rocks, we are now about ready to begin a systematic study of the rocks themselves; but it is needful first to say a few words about the classification of rocks, since upon this depends not only the order in which we shall take the rocks up, but also the ideas that will be imparted concerning their relations and affinities. The classifications which have been proposed at different times are almost as numerous as the rocks themselves. Some of these are confessedly, and even designedly, artificial, as when we classify stones according to their uses in the arts, etc. But we want something more scientific, a natural classification; that is, one based upon the natural and permanent characteristics of rocks. Rocks have been classified according to chemical composition, mineralogical composition, texture, color, density, hardness, etc.; but these arrangements, taken singly or all combined, are inadequate.

A natural classification may be defined as a concise and systematic statement of the natural relations existing among the objects classified. Now the most important relations existing among rocks are those due to their different origins. We must not forget that lithology is a branch of geology, and that geology is first of all a dynamical science. The most important question that can be asked about any rock is, not What is it made of? but How was it made? What were the general forces or agencies concerned in its formation? Rocks are the material in which the earth’s history is written, and what we want to know first concerning any rock is what it can tell us of the condition of that part of the earth at the time it was made and subsequently.

Classification of Rocks.

The geological agencies, as we have already learned, may be arranged in two great classes: first, the aqueous or superficial agencies originating in the solar heat, and producing the sedimentary or stratified rocks; and, second, the igneous or subterranean agencies originating in the central or interior heat, and producing the eruptive or unstratified rocks. Hence, we want to know first of any rock whether it is of aqueous or igneous origin. Then, if it is a sedimentary rock, whether it has been formed by the action chiefly of mechanical forces, or of chemical and organic forces. And, if it is an eruptive rock, whether it has cooled and solidified below the earth’s surface in a fissure, and is a dike or trappean rock, or has flowed out on the surface and cooled in contact with the air, and thus become an ordinary lava or volcanic rock.

Here we have the outlines of our classification, and it will be observed that we have simply reached the conclusion, in a somewhat roundabout manner, that there should always be a general correspondence between the classification of rocks and the classification of the forces that produce them. The general plan of the preceding scheme of the classification must now be clear, and the details will be explained as we go along.

Descriptions of Rocks.

1.—Sedimentary or Stratified Rocks.

1. Mechanically formed or Fragmental Rocks.—These consist of materials deposited from suspension in water, and the process of their formation is throughout chiefly mechanical. The materials deposited are mere fragments of older rocks; and, if the fragments are large, we call the newly deposited sediment gravel; if finer, sand; and, if impalpably fine, clay. These fragmental rocks cannot be classified chemically, since the same handful of gravel, for instance, may contain pebbles of many different kinds of rocks, and thus be of almost any and very variable composition. Such chemical distinctions as can be established are only partial, and the classification, like the origin, must be mechanical. Accordingly, as just shown, we recognize three principal groups based upon the size of the fragments; viz.:—

(1) Conglomerate group.

(2) Arenaceous group.

(3) Argillaceous group.

This mode of division is possible and natural, simply because, as we observed in an early experiment, materials arranged by the mechanical action of water are always assorted according to size. When first deposited, the gravel, sand, and clay are, of course, perfectly loose and unconsolidated; but in the course of time they may, under the influence of pressure, heat, and chemical action, attain almost any degree of consolidation, becoming conglomerate, sandstone, and slate, respectively. The pressure may be vertical where it is due to the weight of newer deposits, or horizontal where it results from the cooling and shrinking of the earth’s interior. The heat may result from mechanical movements, or contact with eruptive rocks; or it may be due simply to the burial of the sediments, which, it will be seen, must virtually bring them nearer the great source of heat in the earth’s interior, on the same principle that the temperature of a man’s coat, on a cold day, is raised by putting on an overcoat. The effect of the heat, ordinarily, is simply drying, coöperating with the pressure to expel the water from the sediments; but, if the temperature is high, it may bake or vitrify them, just as in brick-making. Sediments are consolidated by chemical action when mineral substances, especially calcium carbonate, the iron oxides, and silica are deposited between the particles by infiltrating waters, cementing the particles together. This principle is easily demonstrated experimentally by taking some loose sand and wetting it repeatedly with a saturated solution of some soluble mineral, like salt or alum, allowing the water to evaporate each time before making a fresh application. The interstices between the grains are gradually filled up, and the sand soon becomes a firm rock. But the student should clearly understand that, in geology, gravel, sand, and clay are just as truly rocks before their consolidation as after. It is plain then that in each of the principal groups of fragmental rocks we must recognize an unconsolidated division and a consolidated division.

(1) Conglomerate group.—The rocks belonging in this group we know before consolidation as gravel, and after consolidation as conglomerate.

Gravel.—The pebbles, as we have already seen, are usually, though not always, well rounded or water-worn; and they may be of any size from coarse grains of sand to boulders. As a rule, however, the larger pebbles, especially, are of approximately uniform size in the same bed or layer of gravel, with, of course, sufficient fine material to fill the interstices. Although the same limited mass of gravel may show the widest possible range in chemical and mineralogical composition, yet hard rocks are evidently more likely than soft rocks to form pebbles; and hence quartz and quartz-bearing rocks usually predominate in gravels. Specimen 28.

Conglomerate.—Consolidated gravel. Children should be led to an appreciation of this point by a careful comparison of the forms of the pebbles in the gravel and conglomerate. The conglomerate seems to contain a larger proportion of fine material than ordinary gravel. But this is because the gravel is usually, as with our specimen, taken from the surface of the beach, where, of course, the pebbles are clean and separate; but if it had remained there to be covered by a subsequently deposited layer, enough fine stuff would have been sifted into the holes to fill them. And in the finished gravel, just as in the conglomerate, the pebbles are usually closely packed, with just sufficient sand and clay, or paste, as the material in which the pebbles are imbedded is called, to fill the interstices. The paste is usually similar in composition to the pebbles, with this difference: hard materials predominate in the pebbles and soft in the paste.

Stratified rocks generally show the stratification in parallel lines or bands differing in color, composition, etc.; but nothing like this can be detected in our specimens of conglomerate; and the question might be asked, How do we know that this is a stratified rock? In answer, it can be said that our hand-specimens appear unstratified simply because the rock is so coarse; but when we look at large masses, and especially when we see it in place in the quarry, that parallel arrangement of the material which we call stratification is usually very evident; and we often see precisely the same thing in gravel banks. It is, however, wholly unnecessary that we should see the stratification in order to know certainly that this is a stratified or aqueous rock, because the forms of the pebbles show very plainly that they have been fashioned and deposited by moving water; and we have in the smallest specimen proof positive that our conglomerate is a consolidated sea-beach.

Conglomerate shows the same variations in composition and texture as gravel; it may be composed of almost any kind of material in pebbles of almost any size. We recognize two principal varieties of conglomerate based on the forms of the pebbles; if, as is usual, these are well rounded and water-worn, the rock is true pudding-stone (specimen 29); but, if they are angular, or show but little wear, it is called breccia.

(2) Arenaceous Group.—The conglomerate group passes insensibly into the arenaceous group; for, from the coarsest gravel to the finest sand, the gradation is unbroken, and every sandstone is merely a conglomerate on a small scale.

Sand.—Like gravel, sand may be of almost any composition, but as a rule it is quartzose; quartz, on account of its hardness and the absence of cleavage, being better adapted than any other common mineral to form sand. Where the composition of a sand is not specified, a quartzose sand is always understood. By examining a typical sand with a lens, and noting the glassy appearance of the grains, and then testing their hardness on a piece of glass, which they will scratch as easily as quartz, the pupil is readily convinced that each grain is simply an angular fragment of quartz. Specimen 30.

Sandstone.—Consolidated sand. In proving this, children will notice first the granular or sandy appearance of the sandstone; and then, with the lens, that the grains in the sandstone have the same forms as the sand-grains. The stratification cannot be seen very distinctly in our hand-specimens, but in larger masses it is usually very plain, as may be observed in the blocks used for building, and still better in the quarries. However, even if the stratification were not visible to the eye, we could have no doubt that sandstone is a mechanically formed stratified rock; because the form of the grains, just as in the conglomerate, tells us that. Many sandstones, too, contain the fossil remains of plants and animals, and these are always regarded as affording positive proof that the rocks containing them belong to the aqueous or stratified series.

There are many varieties of sandstone depending upon differences in composition, texture, etc., but we have not space to notice them in detail. In sandstone, just as in sand, quartz is the predominant constituent, although we sometimes find varieties composed largely or entirely of feldspar, mica, calcite, or other minerals. Specimen 31 is an example of the architectural variety known as freestone, which is merely a fine-grained, light-colored, uniform sandstone, not very hard, and breaking with about equal freedom in all directions. The consolidation of sandstones is due chiefly to chemical action. The cementing materials are commonly either: ferruginous (iron oxides), giving red or brown sandstones; calcareous, forming soft sandstones, which effervesce with acid if the cement is abundant; or siliceous, making very strong, light-colored sandstones. Ferruginous sandstones are the most valuable for architectural purposes; for, while not excessively hard, they have a very durable cement. Siliceous sandstones are too hard; and the calcareous varieties crumble when exposed to the weather because the cement is soluble in water containing carbon dioxide, as all rain-water does. Specimen 32 is a good example of a ferruginous sandstone, and it is coarse enough so that we can see that each grain of quartz is coated with the red oxide of iron. The mica scales visible here and there in this specimen are interesting as showing that the grains are not necessarily all quartz; and it is important to observe that the mica was not made in the sandstone, but, like the quartz, has come from some older rock.

Quartzite.—This rock is simply an unusually hard sandstone. Now the hardness of any rock depends upon two things: (1) the hardness of the individual grains or particles; and (2) the firmness with which they are united one to another. Therefore, the hardest sandstones must be those in which grains of quartz are combined with an abundant siliceous cement; and that is precisely what we have in a typical quartzite, such as specimen 33. Quartzite is distinguished, in the hand-specimen, from ordinary quartz by its granular texture (compare specimens 15 and 33); and of course in large masses the stratification is an important distinguishing feature.

3. Argillaceous group.—Just as the conglomerate group shades off gradually into the arenaceous group, so we find it difficult to draw any sharp line of division between the arenaceous group and the argillaceous, but we pass from the largest pebble to the most minute clay-particle by an insensible gradation. For the sake of convenience, however, we draw the line at the limit of visibility, and say that in the true clay and slate the individual particles are invisible to the naked eye; in other words, these rocks have a perfectly compact texture, while the two preceding groups are characterized by a granular texture. Although clay, like sand and gravel, may be of almost any composition, yet it usually consists chiefly, often entirely, of the mineral kaolin. The reason for this is easily found. Quartz resists both mechanical and chemical forces, and is rarely reduced to an impalpable fineness; but all the other common minerals, such as feldspar, hornblende, mica, and calcite, on account of their cleavage and inferior hardness, are easily pulverized; but it is practically impossible that this should happen without their being broken up chemically at the same time. Decomposition follows disintegration; and, while calcite is completely dissolved and carried away, the other minerals are reduced, as we have seen, to impalpable hydrous silicates of aluminum, i.e., to kaolin. Hence, we find that the fragmental rocks are composed principally of two minerals, quartz and kaolin,—the former predominating in the conglomerate and arenaceous groups, and the latter in the argillaceous group.

Clay.—That kaolin is the basis of common clay is proved by the argillaceous odor, which is so characteristic of moist clay. Pure kaolin clay is white and impalpable, like China clay; but pure clays are the exception. They often become coarse and gritty by admixture with sand, forming loam; and they also usually contain more or less carbonaceous matter, which makes black clays; or more or less ferrous oxide, which makes blue clays; or more or less ferric oxide, which makes red, brown, and yellow clays. By mixing these coloring materials in various proportions, almost any tint may be explained. Clays are sometimes calcareous, from the presence of shells and shell-fragments or of pulverized limestone. These usually effervesce with acid, and are commonly known as marl. It is the calcareous material in a pulverulent and easily soluble condition that makes the marls valuable as soils.

Slate.—Consolidated clay. The compact texture and argillaceous odor are usually sufficient to prove this. To get the odor we need simply to breathe upon the specimen, and then smell of it. We find all degrees of induration in clay. It sometimes, as every one knows, becomes very hard by simple drying; but this is not slate, and no amount of mere drying will change clay into slate; for, when moistened with water, the dried clay is easily brought back to the plastic state. To make a good slate, the induration must be the result of pressure, aided probably to some extent by heat. True slate, then, is a permanently indurated clay which will not soak up and become soft when wet.