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Prince Dimitri Ivanovich Dolgorukov was a Russian career diplomat born into one of the most prominent families in Russia.

Prince Dimitri Ivanes dze Kipiani was a Georgian statesman, publicist, writer and translator. A leader of Georgia's liberal nobility, he was known for his work in support of the Georgian culture and society, a cause that led to his 1886 exile and murder at the hands of Russian Imperial authorities. In 2007 he was canonized by the Georgian Orthodox Church as a saint.

Dimitri Sergeevich Rozhdestvensky was a Russian physicist. He worked on spectroscopy, examining the dispersion of sodium lines. He drew up a proposal for the State Optical Institute which was established in 1918 in Petrograd.

Dimitri Konstantinovich Simes is a Russian-American author, editor, and political pundit. He is the former president and CEO of The Center for the National Interest, where he served from 1994 to 2022. Simes was selected to lead the Center by former President Richard Nixon, to whom he served as an informal foreign policy advisor and with whom he traveled regularly to Russia and other former Soviet states as well as Western and Central Europe.

Dimitri Uznadze was a Georgian psychologist and professor of psychology, co-founder of the Tbilisi State University (TSU) and of the Georgian Academy of Sciences (GAS).

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Dimitri Verhulst is a Belgian writer and poet. He is best known for his novels Problemski Hotel and The Misfortunates.

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Dimitrie Anghel (Romanian pronunciation: [diˈmitri.e ˈaŋɡel]; July 16, 1872 – November 13, 1914) was a Romanian poet.

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Dimitrie C. Ollănescu-Ascanio was a Wallachian, later Romanian poet, prose writer and playwright.

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Dimitrie or Demetrius Cantemir, also known by other spellings, was a Romanian prince, statesman, and man of letters, regarded as one of the most significant early Enlightenment figures. He twice served as voivode of Moldavia. During his second term he allied his state with Russia in a war against Moldavia's Ottoman overlords; Russia's defeat forced Cantemir's family into exile and the replacement of the native voivodes by Greek phanariots. Cantemir was also a prolific writer, variously a philosopher, historian, composer, musicologist, linguist, ethnographer, and geographer. His son Antioch, Russia's ambassador to Great Britain and France and a friend of Montesquieu and Voltaire, would become known as "the father of Russian poetry".

Dimitrie Sturdza was a Romanian statesman and author of the late 19th century, and president of the Romanian Academy between 1882 and 1884.