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Alexander Rumyantsev is a world-known pediatric hematologist, professor of the Russian Academy of Sciences, and a deputy of the 8th State Duma. In 1984, he was granted a Doctor of Sciences in Medicine degree.

Alexander Rypinski was a Belarusian and Polish poet, translator and folklorist, participant in the November Uprising.

Alexander Nikolayevich Saburov was one of the leaders of Soviet partisan movement in Ukraine and western Russia during World War II.

Alexander Andreevich Samarskii was a Soviet and Russian mathematician and academician, specializing in mathematical physics, applied mathematics, numerical analysis, mathematical modeling, finite difference methods.

Alexander Alexandrovich Samoylo was a commander in the Imperial Russian Army and Red Army during World War I and the Russian Civil War.

Alexander Nikolaevich Samoylovich was a Russian Orientalist-Turkologist who served as a member of the USSR Academy of Sciences (1929), Rector of the Leningrad Oriental Institute (1922–1925), academic secretary of the Humanities Branch of the USSR Academy of Sciences (1929–1933), and director of the Institute of Oriental Studies of the USSR Academy of Sciences (1934–1937). He was arrested by the NKVD in October 1937, and was executed on 13 February 1938.

Alexander Grigorievich Schlichter was a Ukrainian Bolshevik politician, Soviet statesman, political scientist and economist.

Alexander Dmitrievich Schmemann was an influential Orthodox priest, theologian, and author who spent most of his career in the United States.

Alexander Nikolayevich Scriabin was a Russian composer and virtuoso pianist. Before 1903, Scriabin was greatly influenced by the music of Frédéric Chopin and composed in a relatively tonal, late-Romantic idiom. Later, and independently of his influential contemporary Arnold Schoenberg, Scriabin developed a much more dissonant musical language that had transcended usual tonality but was not atonal, which accorded with his personal brand of metaphysics. Scriabin found significant appeal in the concept of Gesamtkunstwerk as well as synesthesia, and associated colours with the various harmonic tones of his scale, while his colour-coded circle of fifths was also inspired by theosophy. He is often considered the main Russian Symbolist composer and a major representative of the Russian Silver Age.

Alexander Gennadyevich Selin ; was a Russian writer, a scriptwriter, a stage director and a literary figure. He was an author of novels, stories, plays and screenplays.